863 research outputs found
Structure analysis of the Ga-stabilized GaAs(001)-c(8x2) surface at high temperatures
Structure of the Ga-stabilized GaAs(001)-c(8x2) surface has been studied
using rocking-curve analysis of reflection high-energy electron diffraction
(RHEED). The c(8x2) structure emerges at temperatures higher than 600C, but is
unstable with respect to the change to the (2x6)/(3x6) structure at lower
temperatures. Our RHEED rocking-curve analysis at high temperatures revealed
that the c(8x2) surface has the structure which is basically the same as that
recently proposed by Kumpf et al. [Phys. Rev. Lett. 86, 3586 (2001)]. We found
that the surface atomic configurations are locally fluctuated at high
temperatures without disturbing the c(8x2) periodicity.Comment: 14 pages, 4 figures, 1 tabl
Electronic structure of the MO oxides (M=Mg, Ca, Ti, V) in the GW approximation
The quasiparticle band structures of nonmagnetic monoxides, MO (M=Mg, Ca, Ti,
and V), are calculated by the GW approximation. The band gap and the width of
occupied oxygen 2p states in insulating MgO and CaO agree with experimental
observation. In metallic TiO and VO, conduction bands originated from metal 3d
states become narrower. Then the partial densities of transition metal e_g and
t_2g states show an enhanced dip between the two. The effects of static
screening and dynamical correlation are discussed in detail in comparison with
the results of the Hartree-Fock approximation and the static Coulomb hole plus
screened exchange approximation. The d-d Coulomb interaction is shown to be
very much reduced by on-site and off-site d-electron screening in TiO and VO.
The dielectric function and the energy loss spectrum are also presented and
discussed in detail.Comment: 10 pages, 5 figure
Electronic Structure of Dangling Bonds in Amorphous Silicon Studied via a Density-Matrix Functional Method
A structural model of hydrogenated amorphous silicon containing an isolated
dangling bond is used to investigate the effects of electron interactions on
the electronic level splittings, localization of charge and spin, and
fluctuations in charge and spin. These properties are calculated with a
recently developed density-matrix correlation-energy functional applied to a
generalized Anderson Hamiltonian, consisting of tight-binding one-electron
terms parametrizing hydrogenated amorphous silicon plus a local interaction
term. The energy level splittings approach an asymptotic value for large values
of the electron-interaction parameter U, and for physically relevant values of
U are in the range 0.3-0.5 eV. The electron spin is highly localized on the
central orbital of the dangling bond while the charge is spread over a larger
region surrounding the dangling bond site. These results are consistent with
known experimental data and previous density-functional calculations. The spin
fluctuations are quite different from those obtained with unrestricted
Hartree-Fock theory.Comment: 6 pages, 6 figures, 1 tabl
Ab initio optical properties of Si(100)
We compute the linear optical properties of different reconstructions of the
clean and hydrogenated Si(100) surface within DFT-LDA, using norm-conserving
pseudopotentials. The equilibrium atomic geometries of the surfaces, determined
from self-consistent total energy calculations within the Car-Parrinello
scheme, strongly influence Reflectance Anisotropy Spectra (RAS), showing
differences between the p(2x2) and c(4x2)reconstructions. The Differential
Reflectivity spectrum for the c(4x2) reconstruction shows a positive peak at
energies < 1 eV, in agreement with experimental results.Comment: fig. 2 correcte
Spectra and total energies from self-consistent many-body perturbation theory
With the aim of identifying universal trends, we compare fully self-consistent electronic spectra and total energies obtained from the GW approximation with those from an extended GW Gamma scheme that includes a nontrivial vertex function and the fundamentally distinct Bethe-Goldstone approach based on the T matrix. The self-consistent Green's function G, as derived from Dyson's equation, is used not only in the self-energy but also to construct the screened interaction W for a model system. For all approximations we observe a similar deterioration of the spectrum, which is not removed by vertex corrections. In particular, satellite peaks are systematically broadened and move closer to the chemical potential. The corresponding total energies are universally raised, independent of the system parameters. Our results, therefore, suggest that any improvement in total energy due to self-consistency, such as for the electron gas in the GW approximation, may be fortuitous. [S0163-1829 (98)05040-1]
Theoretical study of the (3x2) reconstruction of beta-SiC(001)
By means of ab initio molecular dynamics and band structure calculations, as
well as using calculated STM images, we have singled out one structural model
for the (3x2) reconstruction of the Si-terminated (001) surface of cubic SiC,
amongst several proposed in the literature. This is an alternate dimer-row
model, with an excess Si coverage of 1/3, yielding STM images in good accord
with recent measurements [F.Semond et al. Phys. Rev. Lett. 77, 2013 (1996)].Comment: To be published in PRB Rapid. Com
Anisotropic optical response of the diamond (111)-2x1 surface
The optical properties of the 21 reconstruction of the diamond (111)
surface are investigated. The electronic structure and optical properties of
the surface are studied using a microscopic tight-binding approach. We
calculate the dielectric response describing the surface region and investigate
the origin of the electronic transitions involving surface and bulk states. A
large anisotropy in the surface dielectric response appears as a consequence of
the asymmetric reconstruction on the surface plane, which gives rise to the
zigzag Pandey chains. The results are presented in terms of the reflectance
anisotropy and electron energy loss spectra. While our results are in good
agreement with available experimental data, additional experiments are proposed
in order to unambiguously determine the surface electronic structure of this
interesting surface.Comment: REVTEX manuscript with 6 postscript figures, all included in uu file.
Also available at http://www.phy.ohiou.edu/~ulloa/ulloa.html Submitted to
Phys. Rev.
Towards the fabrication of phosphorus qubits for a silicon quantum computer
The quest to build a quantum computer has been inspired by the recognition of
the formidable computational power such a device could offer. In particular
silicon-based proposals, using the nuclear or electron spin of dopants as
qubits, are attractive due to the long spin relaxation times involved, their
scalability, and the ease of integration with existing silicon technology.
Fabrication of such devices however requires atomic scale manipulation - an
immense technological challenge. We demonstrate that it is possible to
fabricate an atomically-precise linear array of single phosphorus bearing
molecules on a silicon surface with the required dimensions for the fabrication
of a silicon-based quantum computer. We also discuss strategies for the
encapsulation of these phosphorus atoms by subsequent silicon crystal growth.Comment: To Appear in Phys. Rev. B Rapid Comm. 5 pages, 5 color figure
Study of a Nonlocal Density scheme for electronic--structure calculations
An exchange-correlation energy functional beyond the local density
approximation, based on the exchange-correlation kernel of the homogeneous
electron gas and originally introduced by Kohn and Sham, is considered for
electronic structure calculations of semiconductors and atoms. Calculations are
carried out for diamond, silicon, silicon carbide and gallium arsenide. The
lattice constants and gaps show a small improvement with respect to the LDA
results.
However, the corresponding corrections to the total energy of the isolated
atoms are not large enough to yield a substantial improvement for the cohesive
energy of solids, which remains hence overestimated as in the LDA.Comment: 4 postscript figure
The role of electronic correlation in the Si(100) reconstruction: a quantum Monte Carlo study
Recent low-temperature scanning tunneling experiments have challenged the
generally accepted picture of buckled silicon dimers as the ground state
reconstruction of the Si(100) surface. Together with the symmetric dimer model
of the surface suggested by quantum chemistry calculations on small clusters,
these findings question our general understanding of electronic correlations at
surfaces and its proper description within density functional theory. We
present quantum Monte Carlo calculations on large cluster models of the
symmetric and buckled surface, and conclude that buckling remains energetically
more favorable even when the present-day best treatment of electronic
correlation is employed.Comment: 5 pages, Revtex, 10 figure
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