733 research outputs found
Self Replication and Signalling
It is known that if one could clone an arbitrary quantum state one could send
signal faster than the speed of light. However it remains interesting to see
that if one can perfectly self replicate an arbitrary quantum state, does it
violate the no signalling principle? Here we see that perfect self replication
would also lead to superluminal signalling.Comment: Modified version of quant-ph/0510221, Accepted in International
Journal of Theoretical Physic
The measurement of homonegative reactions with physiological and subjective reports
A proposal to present a paper on the physiological measurement of homonegativit
A model-theoretic interpretation of environmentally-induced superselection
Environmentally-induced superselection or "einselection" has been proposed as
an observer-independent mechanism by which apparently classical systems
"emerge" from physical interactions between degrees of freedom described
completely quantum-mechanically. It is shown that einselection can only
generate classical systems if the "environment" is assumed \textit{a priori} to
be classical; einselection therefore does not provide an observer-independent
mechanism by which classicality can emerge from quantum dynamics. Einselection
is then reformulated in terms of positive operator-valued measures (POVMs)
acting on a global quantum state. It is shown that this re-formulation enables
a natural interpretation of apparently-classical systems as virtual machines
that requires no assumptions beyond those of classical computer science.Comment: 15 pages, 1 figure; minor correction
Crystal structures of the carborane dianions, [1,4-(PhCB10H10C)2C6H4]2- and [1,4-(PhCB10H10C)2C6F4]2-, and the stabilizing role of the para-phenylene unit on unusual 2n+3 SE clusters
While carboranes with 2 n+2 and 2 n+4 (n=number of skeletal atoms) skeletal electrons (SE) are widely known, little has been reported on carboranes with odd SE numbers. Electrochemical measurements on two-cage assemblies, where two C-phenyl-ortho-carboranyl groups are linked by a para-phenylene or a para-tetrafluorophenylene bridge, revealed two well separated and reversible two-electron reduction waves indicating formation of stable dianions and tetraanions. The salts of the dianions were isolated by reduction with sodium metal and their unusual structures were determined by X-ray crystallography. The diamagnetic dianions contain two 2 n+3 SE clusters where each cluster has a notably long carborane C–carborane C distance of ca 2.4 Å. The π conjugation within the phenylene bridge plays an important role in the stabilization of these carboranes with odd SE counts
Entanglement of a Single Spin-1 Object: An Example of Ubiquitous Entanglement
Using a single spin-1 object as an example, we discuss a recent approach to
quantum entanglement. The key idea of the approach consists in presetting of
basic observables in the very definition of quantum system. Specification of
basic observables defines the dynamic symmetry of the system. Entangled states
of the system are then interpreted as states with maximal amount of uncertainty
of all basic observables. The approach gives purely physical picture of
entanglement. In particular, it separates principle physical properties of
entanglement from inessential. Within the model example under consideration, we
show relativity of entanglement with respect to dynamic symmetry and argue
existence of single-particle entanglement. A number of physical examples are
considered.Comment: 12 pages, 2 figure : title has been changed, paper is re-organized,
new section "Violation of Bell-type condition by single spin-1" is adde
On the ambiguity of 1,3,2-benzodiazaboroles as donor/acceptor functionalities in luminescent molecules
A series of 1,3-bis(perfluoroaryl)-2-(hetero)aryl-1,3,2-benzodiazaboroles, 1,3-FAr2-2-Ar-1,3,2-N2BC6H4 (Ar = Ph, FAr = C6F5 5; Ar = Ph, FAr = 4-C5F4N 6; Ar = Ph, FAr = 4-NCC6F4 7; Ar = 2-C4H3S, FAr = C6F5 8; Ar = 2-C4H3S, FAr = 4-C5F4N 9; Ar = 2-C4H3S, FAr = 4-NCC6F4 10), were synthesised by cyclocondensation of the adducts PhBBr2·PPh3 or 2-thienylBBr2·PPh3 with N,N′-bis(perfluoroaryl)-o-phenylenediamines in the presence of 2,2,6,6-tetramethylpiperidine. Similar treatments of the PPh3 adducts of 4-(1′,3′-diethyl-1′,3′,2′-benzodiazaborolyl)-phenyldibromoborane with the corresponding diamines gave rise to the push–pull compounds, C6H4(NEt)2B-1,4-C6H4-B(NFAr)2C6H4 (FAr = C6F5 11; 4-C5F4N 12) and C6H4(NEt)2B-2,5-C4H2S-B(NFAr)2C6H4 (FAr = C6F5 13; 4-C5F4N 14). The X-ray structures of 8, 11, 12 and 13 were determined. Electronic structure calculations reveal that the LUMOs are located at the perfluoroaryl groups in 5–14; thus the fluorinated benzodiazaborolyl groups are considered as electron-withdrawing moieties. These moieties differ from alkylated benzodiazaborolyl groups which are regarded as donors. The emission spectra for 5–14 show charge transfer bands with significant solvatochromism and large Stokes shifts (6100–12500 cm−1 in cyclohexane and 8900–15900 cm−1 in CH2Cl2). The emissions of the benzodiazaboroles, 5–10, arise from a different charge transfer (CT) process to the local charge transfer (LCT) process typically found in many fluorescent benzodiazaboroles. This novel remote charge transfer (RCT) process involving the perfluoroaryl groups is supported by CAM-B3LYP computations. The push–pull systems 11–14 here give fluorescent emissions with moderate to high fluorescence quantum yields (65–97%) that arise from the usual LCT process only
The significance of work allocation in the professional apprenticeship of solicitors
It is a peculiarity of the solicitors’ profession that it has historically relied on methods of pre-qualification ‘training’ by way of apprenticeship and that an entirely respectable non-graduate route into the profession remains. In a political context, however, where the profession is called upon positively to demonstrate its standards of performance, the professional regulator seeks to attach a competence framework to the existing model; shifting the focus from how the trainee learns to what the trainee learns. This paper will explore the period of traineeship from the perspective of the trainees themselves, drawing on two small qualitative studies, focussing on the fundamental context factor of the allocation and structuring of their work. In the first study the context for this evaluation is the set of outcomes being tested by the professional regulator and in the second, the perceptions of qualified individuals looking back at their apprenticeship, The paper concludes that there remains work for the profession to do not only in fostering supportive and expansive apprenticeships, but in attending, however, supportive the surrounding environment, to the work being carried out by trainees and its relationship with the work carried out by newly qualified solicitors
Tverberg-type theorems for intersecting by rays
In this paper we consider some results on intersection between rays and a
given family of convex, compact sets. These results are similar to the center
point theorem, and Tverberg's theorem on partitions of a point set
The quantum structure of spacetime at the Planck scale and quantum fields
We propose uncertainty relations for the different coordinates of spacetime
events, motivated by Heisenberg's principle and by Einstein's theory of
classical gravity. A model of Quantum Spacetime is then discussed where the
commutation relations exactly implement our uncertainty relations.
We outline the definition of free fields and interactions over QST and take
the first steps to adapting the usual perturbation theory. The quantum nature
of the underlying spacetime replaces a local interaction by a specific nonlocal
effective interaction in the ordinary Minkowski space. A detailed study of
interacting QFT and of the smoothing of ultraviolet divergences is deferred to
a subsequent paper.
In the classical limit where the Planck length goes to zero, our Quantum
Spacetime reduces to the ordinary Minkowski space times a two component space
whose components are homeomorphic to the tangent bundle TS^2 of the 2-sphere.
The relations with Connes' theory of the standard model will be studied
elsewhere.Comment: TeX, 37 pages. Since recent and forthcoming articles (hep-th/0105251,
hep-th/0201222, hep-th/0301100) are based on this paper, we thought it would
be convenient for the readers to have it available on the we
Motion of influential players can support cooperation in Prisoner's Dilemma
We study a spatial Prisoner's dilemma game with two types (A and B) of
players located on a square lattice. Players following either cooperator or
defector strategies play Prisoner's Dilemma games with their 24 nearest
neighbors. The players are allowed to adopt one of their neighbor's strategy
with a probability dependent on the payoff difference and type of the given
neighbor. Players A and B have different efficiency in the transfer of their
own strategy therefore the strategy adoption probability is reduced by a
multiplicative factor (w < 1) from the players of type B. We report that the
motion of the influential payers (type A) can improve remarkably the
maintenance of cooperation even for their low densities.Comment: 7 pages, 7 figure
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