3,385 research outputs found
Thermoelectric Properties of Intermetallic Semiconducting RuIn3 and Metallic IrIn3
Low temperature (<400 K) thermoelectric properties of semiconducting RuIn3
and metallic IrIn3 are reported. RuIn3 is a narrow band gap semiconductor with
a large n-type Seebeck coefficient at room temperature (S(290K)~400 {\mu}V/K),
but the thermoelectric Figure of merit (ZT(290K) = 0.007) is small because of
high electrical resistivity and thermal conductivity ({\kappa}(290 K) ~ 2.0 W/m
K). IrIn3 is a metal with low thermopower at room temperature (S(290K)~20
{\mu}V/K) . Iridium substitution on the ruthenium site has a dramatic effect on
transport properties, which leads to a large improvement in the power factor
and corresponding Figure of merit (ZT(380 K) = 0.053), improving the efficiency
of the material by an over of magnitude.Comment: Submitted to JA
Field-induced Conductance Switching by Charge-state Alternation in Organometallic Single-Molecule Junctions
Charge transport through single molecules can be influenced by the charge and
spin states of redox-active metal centres placed in the transport pathway.
These molecular intrinsic properties are usually addressed by varying the
molecules electrochemical and magnetic environment, a procedure that requires
complex setups with multiple terminals. Here we show that oxidation and
reduction of organometallic compounds containing either Fe, Ru or Mo centres
can solely be triggered by the electric field applied to a two-terminal
molecular junction. Whereas all compounds exhibit bias-dependent hysteresis,
the Mo-containing compound additionally shows an abrupt voltage-induced
conductance switching, yielding high to low current ratios exceeding 1000 at
voltage stimuli of less than 1.0 V. DFT calculations identify a localized,
redox active molecular orbital that is weakly coupled to the electrodes and
closely aligned with the Fermi energy of the leads because of the
spin-polarised ground state unique to the Mo centre. This situation opens an
additional slow and incoherent hopping channel for transport, triggering a
transient charging effect of the entire molecule and a strong hysteresis with
unprecedented high low-to-high current ratios.Comment: 9 pages, 4 figure
Modularity and Optimality in Social Choice
Marengo and the second author have developed in the last years a geometric
model of social choice when this takes place among bundles of interdependent
elements, showing that by bundling and unbundling the same set of constituent
elements an authority has the power of determining the social outcome. In this
paper we will tie the model above to tournament theory, solving some of the
mathematical problems arising in their work and opening new questions which are
interesting not only from a mathematical and a social choice point of view, but
also from an economic and a genetic one. In particular, we will introduce the
notion of u-local optima and we will study it from both a theoretical and a
numerical/probabilistic point of view; we will also describe an algorithm that
computes the universal basin of attraction of a social outcome in O(M^3 logM)
time (where M is the number of social outcomes).Comment: 42 pages, 4 figures, 8 tables, 1 algorithm
Microstructural white matter alterations in the corpus callosum of girls with conduct disorder
Objective Diffusion tensor imaging (DTI) studies in adolescent conduct disorder (CD) have demonstrated white matter alterations of tracts connecting functionally distinct fronto-limbic regions, but only in boys or mixed-gender samples. So far, no study has investigated white matter integrity in girls with CD on a whole-brain level. Therefore, our aim was to investigate white matter alterations in adolescent girls with CD. Method We collected high-resolution DTI data from 24 girls with CD and 20 typically developing control girls using a 3T magnetic resonance imaging system. Fractional anisotropy (FA) and mean diffusivity (MD) were analyzed for whole-brain as well as a priori−defined regions of interest, while controlling for age and intelligence, using a voxel-based analysis and an age-appropriate customized template. Results Whole-brain findings revealed white matter alterations (i.e., increased FA) in girls with CD bilaterally within the body of the corpus callosum, expanding toward the right cingulum and left corona radiata. The FA and MD results in a priori−defined regions of interest were more widespread and included changes in the cingulum, corona radiata, fornix, and uncinate fasciculus. These results were not driven by age, intelligence, or attention-deficit/hyperactivity disorder comorbidity. Conclusion This report provides the first evidence of white matter alterations in female adolescents with CD as indicated through white matter reductions in callosal tracts. This finding enhances current knowledge about the neuropathological basis of female CD. An increased understanding of gender-specific neuronal characteristics in CD may influence diagnosis, early detection, and successful intervention strategies
Evidence of Martensitic Phase Transitions in Magnetic Ni-Mn-In Thin Films
Ni 50Mn35In15 Heusler alloy thin films (with thicknesses of about 10 nm) have been grown on single crystal MgO and SrTiO3 (STO) (100) substrates using a laser-assisted molecular beam epitaxy method. Films of mixed austenitic and martensitic phases and of pure martensitic phase have been detected for those grown on MgO and STO substrates, respectively. Thermomagnetic curves were measured using a SQUID magnetometer and are consistent with those of off-stoichiometric In-based bulk Heusler alloys, including a martensitic transition at T = 315 K for films grown on MgO. The differences in the properties of the films grown on MgO and STO are discussed
Gauging the three-nucleon spectator equation
We derive relativistic three-dimensional integral equations describing the
interaction of the three-nucleon system with an external electromagnetic field.
Our equations are unitary, gauge invariant, and they conserve charge. This has
been achieved by applying the recently introduced gauging of equations method
to the three-nucleon spectator equations where spectator nucleons are always on
mass shell. As a result, the external photon is attached to all possible places
in the strong interaction model, so that current and charge conservation are
implemented in the theoretically correct fashion. Explicit expressions are
given for the three-nucleon bound state electromagnetic current, as well as the
transition currents for the scattering processes
\gamma He3 -> NNN, Nd -> \gamma Nd, and \gamma He3 -> Nd. As a result, a
unified covariant three-dimensional description of the NNN-\gamma NNN system is
achieved.Comment: 23 pages, REVTeX, epsf, 4 Postscript figure
Convexity deficit of benzenoids
In 2012, a family of benzenoids was introduced by Cruz, Gutman, and Rada, which they called convex benzenoids. In this paper we introduce the convexity deficit, a new topological index intended for benzenoids and, more generally, fusenes. This index measures by how much a given fusene departs from convexity. It is defined in terms of the boundary-edges code. In particular, convex benzenoids are exactly the benzenoids having convexity deficit equal to 0. Quasi-convex benzenoids form the family of non-convex benzenoids that are closest to convex, i.e., they have convexity deficit equal to 1. Finally, we investigate convexity deficit of several important families of benzenoids
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