25,330 research outputs found
Liquid-gas coexistence and critical point shifts in size-disperse fluids
Specialized Monte Carlo simulations and the moment free energy (MFE) method
are employed to study liquid-gas phase equilibria in size-disperse fluids. The
investigation is made subject to the constraint of fixed polydispersity, i.e.
the form of the `parent' density distribution of the particle
diameters , is prescribed. This is the experimentally realistic
scenario for e.g. colloidal dispersions. The simulations are used to obtain the
cloud and shadow curve properties of a Lennard-Jones fluid having diameters
distributed according to a Schulz form with a large (40%) degree of
polydispersity. Good qualitative accord is found with the results from a MFE
method study of a corresponding van der Waals model that incorporates
size-dispersity both in the hard core reference and the attractive parts of the
free energy. The results show that polydispersity engenders considerable
broadening of the coexistence region between the cloud curves. The principal
effect of fractionation in this region is a common overall scaling of the
particle sizes and typical inter-particle distances, and we discuss why this
effect is rather specific to systems with Schulz diameter distributions. Next,
by studying a family of such systems with distributions of various widths, we
estimate the dependence of the critical point parameters on . In
contrast to a previous theoretical prediction, size-dispersity is found to
raise the critical temperature above its monodisperse value. Unusually for a
polydisperse system, the critical point is found to lie at or very close to the
extremum of the coexistence region in all cases. We outline an argument showing
that such behaviour will occur whenever size polydispersity affects only the
range, rather than the strength of the inter-particle interactions.Comment: 14 pages, 12 figure
Enhanced transmission of slit arrays in an extremely thin metallic film
Horizontal resonances of slit arrays are studied. They can lead to an
enhanced transmission that cannot be explained using the single-mode
approximation. A new type of cavity resonance is found when the slits are
narrow for a wavelength very close to the period. It can be excited for very
low thicknesses. Optimization shows these structures could constitute
interesting monochromatic filters
Nuclear shape dependence of Gamow-Teller distributions in neutron-deficient Pb isotopes
We study Gamow-Teller strength distributions in the neutron-deficient even
isotopes (184-194)Pb in a search for signatures of deformation. The microscopic
formalism used is based on a deformed quasiparticle random phase approximation
(QRPA) approach, which involves a self-consistent quasiparticle deformed Skyrme
Hartree-Fock (HF) basis and residual spin-isospin forces in both the
particle-hole and particle-particle channels. By analyzing the sensitivity of
the Gamow-Teller strength distributions to the various ingredients in the
formalism, we conclude that the beta-decay of these isotopes could be a useful
tool to look for fingerprints of nuclear deformation.Comment: 20 pages, 11 figures. To be published in Physical Review
Equilibrium phase behavior of polydisperse hard spheres
We calculate the phase behavior of hard spheres with size polydispersity,
using accurate free energy expressions for the fluid and solid phases. Cloud
and shadow curves, which determine the onset of phase coexistence, are found
exactly by the moment free energy method, but we also compute the complete
phase diagram, taking full account of fractionation effects. In contrast to
earlier, simplified treatments we find no point of equal concentration between
fluid and solid or re-entrant melting at higher densities. Rather, the fluid
cloud curve continues to the largest polydispersity that we study (14%); from
the equilibrium phase behavior a terminal polydispersity can thus only be
defined for the solid, where we find it to be around 7%. At sufficiently large
polydispersity, fractionation into several solid phases can occur, consistent
with previous approximate calculations; we find in addition that coexistence of
several solids with a fluid phase is also possible
Fractionation effects in phase equilibria of polydisperse hard sphere colloids
The equilibrium phase behaviour of hard spheres with size polydispersity is
studied theoretically. We solve numerically the exact phase equilibrium
equations that result from accurate free energy expressions for the fluid and
solid phases, while accounting fully for size fractionation between coexisting
phases. Fluids up to the largest polydispersities that we can study (around
14%) can phase separate by splitting off a solid with a much narrower size
distribution. This shows that experimentally observed terminal polydispersities
above which phase separation no longer occurs must be due to non-equilibrium
effects. We find no evidence of re-entrant melting; instead, sufficiently
compressed solids phase separate into two or more solid phases. Under
appropriate conditions, coexistence of multiple solids with a fluid phase is
also predicted. The solids have smaller polydispersities than the parent phase
as expected, while the reverse is true for the fluid phase, which contains
predominantly smaller particles but also residual amounts of the larger ones.
The properties of the coexisting phases are studied in detail; mean diameter,
polydispersity and volume fraction of the phases all reveal marked
fractionation. We also propose a method for constructing quantities that
optimally distinguish between the coexisting phases, using Principal Component
Analysis in the space of density distributions. We conclude by comparing our
predictions to perturbative theories for near-monodisperse systems and to Monte
Carlo simulations at imposed chemical potential distribution, and find
excellent agreement.Comment: 21 pages, 23 figures, 2 table
Mobile particles in an immobile environment: Molecular Dynamics simulation of a binary Yukawa mixture
Molecular dynamics computer simulations are used to investigate thedynamics
of a binary mixture of charged (Yukawa) particles with a size-ratio of 1:5. We
find that the system undergoes a phase transition where the large particles
crystallize while the small particles remain in a fluid-like (delocalized)
phase. Upon decreasing temperature below the transition, the small particles
become increasingly localized on intermediate time scales. This is reflected in
the incoherent intermediate scattering functions by the appearance of a plateau
with a growing height. At long times, the small particles show a diffusive
hopping motion. We find that these transport properties are related to
structural correlations and the single-particle potential energy distribution
of the small particles.Comment: 7 pages, 5 figure
Maude: specification and programming in rewriting logic
Maude is a high-level language and a high-performance system supporting executable specification and declarative programming in rewriting logic. Since rewriting logic contains equational logic, Maude also supports equational specification and programming in its sublanguage of functional modules and theories. The underlying equational logic chosen for Maude is membership equational logic, that has sorts, subsorts, operator overloading, and partiality definable by membership and equality conditions. Rewriting logic is reflective, in the sense of being able to express its own metalevel at the object level. Reflection is systematically exploited in Maude endowing the language with powerful metaprogramming capabilities, including both user-definable module operations and declarative strategies to guide the deduction process. This paper explains and illustrates with examples the main concepts of Maude's language design, including its underlying logic, functional, system and object-oriented modules, as well as parameterized modules, theories, and views. We also explain how Maude supports reflection, metaprogramming and internal strategies. The paper outlines the principles underlying the Maude system implementation, including its semicompilation techniques. We conclude with some remarks about applications, work on a formal environment for Maude, and a mobile language extension of Maude
Millimetre continuum observations of comet C/2009 P1 (Garradd)
Little is known about the physical properties of the nuclei of Oort cloud
comets. Measuring the thermal emission of a nucleus is one of the few means for
deriving its size and constraining some of its thermal properties. We attempted
to measure the nucleus size of the Oort cloud comet C/2009 P1 (Garradd). We
used the Plateau de Bure Interferometer to measure the millimetric thermal
emission of this comet at 157 GHz (1.9 mm) and 266 GHz (1.1 mm). Whereas the
observations at 266 GHz were not usable due to bad atmospheric conditions, we
derived a 3-sigma upper limit on the comet continuum emission of 0.41 mJy at
157 GHz. Using a thermal model for a spherical nucleus with standard thermal
parameters, we found an upper limit of 5.6 km for the radius. The dust
contribution to our signal is estimated to be negligible. Given the water
production rates measured for this comet and our upper limit, we estimated that
Garradd was very active, with an active fraction of its nucleus larger than
50%.Comment: Accepted for publication in Astronomy & Astrophysics. 5 pages, 2
figure
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