Formation and structure of calcium carbonate thin films and nanofibers precipitated in the presence of poly(allylamine hydrochloride) and magnesium ions

That the cationic polyelectrolyte poly(allylamine hydrochloride) (PAH) exerts a significant influence on CaCO₃ precipitation challenges the idea that only anionic additives have this effect. Here, we show that in common with anionic polyelectrolytes such as poly(aspartic acid), PAH supports the growth of calcite thin films and abundant nanofibers. While investigating the formation of these structures, we also perform the first detailed structural analysis of the nanofibers by transmission electron microscopy (TEM) and selected area electron diffraction. The nanofibers are shown to be principally single crystal, with isolated domains of polycrystallinity, and the single crystal structure is even preserved in regions where the nanofibers dramatically change direction. The formation mechanism of the fibers, which are often hundreds of micrometers long, has been the subject of intense speculation. Our results suggest that they form by aggregation of amorphous particles, which are incorporated into the fibers uniquely at their tips, before crystallizing. Extrusion of polymer during crystallization may inhibit particle addition at the fiber walls and result in local variations in the fiber nanostructure. Finally, we investigate the influence of Mg²+ on CaCO₃ precipitation in the presence of PAH, which gives thinner and smoother films, together with fibers with more polycrystalline, granular structures

Acoustic emission monitoring of a soil slope: comparisons with continuous deformation measurements

Acoustic emission (AE) has become an established approach to monitor the stability of soil slopes. However, the challenge has been to develop strategies to interpret and quantify deformation behaviour from the measured AE. This paper presents the first comparison of continuous AE (measured using an active waveguide) and continuous subsurface deformation measurements. The active waveguide is installed in a borehole through a slope and comprises a metal waveguide rod or tube with a granular backfill surround. When the host slope deforms, the column of granular backfill also deforms, generating AE that can propagate along the waveguide. This paper presents results from a field trial at a reactivated soil slope in North Yorkshire, UK. The measurements confirm that AE rates generated are directly proportional to the velocity of slope movement (e.g. the AE rate versus velocity relationship determined for a series of slope movement events produced an R 2 value of 0·8) and demonstrate the performance of AE monitoring of active waveguides to provide continuous information on slope displacements and displacement rates with high temporal resolution

Probing Molecular Dynamics with Hyperpolarized Ultrafast Laplace NMR Using a Low-field, Single-sided Magnet

Laplace NMR (LNMR) offers deep insights on diffusional and rotational motion of molecules. The so-called “ultrafast” approach, based on spatial data encoding, enables one to carry out a multidimensional LNMR experiment in a single scan, providing from 10 to 1000-fold acceleration of the experiment. Here, we demonstrate the feasibility of ultrafast diffusion–T2 relaxation correlation (D–T2) measurements with a mobile, low-field, relatively low-cost, single-sided NMR magnet. We show that the method can probe a broad range of diffusion coefficients (at least from 10−8 to 10−12 m2 s−1) and reveal multiple components of fluids in heterogeneous materials. The single-scan approach is demonstrably compatible with nuclear spin hyperpolarization techniques because the time-consuming hyperpolarization process does not need to be repeated. Using dynamic nuclear polarization (DNP), we improved the NMR sensitivity of water molecules by a factor of 105 relative to non-hyperpolarized NMR in the 0.3 T field of the single-sided magnet. This enabled us to acquire a D–T2 map in a single, 22 ms scan, despite the low field and relatively low mole fraction (0.003) of hyperpolarized water. Consequently, low-field, hyperpolarized ultrafast LNMR offers significant prospects for advanced, mobile, low-cost and high-sensitivity chemical and medical analysis

Value chain analysis of Chaya (Mayan Spinach) in Guatemala

Chaya is a highly nutritious perennial leafy vegetable native to Mesoamerica. This drought-resistant crop has low production and consumption levels in Guatemala, but has the potential to help agriculture and food systems be more nutritious and resilient. This study analyzed the value chain of chaya in Guatemala, and identified bottlenecks and opportunities for its use-enhancement. This research, the first of its kind applied to this crop in Guatemala, combined Rapid Market Appraisal tools. Small-scale chaya production, consumption, and marketing were observed in three focal sites (Guatemala City, Petén, and Dry Corridor). It was observed that producers are not motivated to produce chaya commercially and vendors are unwilling to sell it because of low demand and profitability. One Guatemalan company identified produces nutraceutical chaya products with few sales points in the country and occasionally abroad. Low demand is a primary bottleneck in the value chain due to lack of consumer awareness, changing eating habits, limited recipes, and availability in home-gardens. There is also a reluctance to grow, consume, or sell a crop perceived as a “food of the poor.” Low prices and profitability were other constraints registered. The findings can inform future interventions for enhancing the use of this crop to fight malnutrition

Characterising sand and gravel deposits using electrical resistivity tomography (ERT) : case histories from England and Wales

Electrical Resistivity Tomography (ERT) is a rapidly developing geophysical imaging technique that is now widely used to visualise subsurface geological structure, groundwater and lithological variations. It is being increasingly used in environmental and engineering site investigations, but despite its suitability and potential benefits, ERT has yet to be routinely applied by the minerals industry to sand and gravel deposit assessment and quarry planning. The principal advantages of ERT for this application are that it is a cost-effective non-invasive method, which can provide 2D or 3D spatial models of the subsurface throughout the full region of interest. This complements intrusive sampling methods, which typically provide information only at discrete locations. Provided that suitable resistivity contrasts are present, ERT has the potential to reveal mineral and overburden thickness and quality variations within the body of the deposit. Here we present a number of case studies from the UK illustrating the use of 2D and 3D ERT for sand and gravel deposit investigation in a variety of geological settings. We use these case studies to evaluate the performance of ERT, and to illustrate good practice in the application of ERT to deposit investigation. We propose an integrated approach to site investigation and quarry planning incorporating both conventional intrusive methods and ERT

Intra-tester and inter-tester reliability of the MicroFET 3 hand-held dynamometer.

Background: The reliability of the MicroFET 3 has not previously been reported in the literature. The aim of this study was to evaluate intra-tester and inter-tester reliability of the MicroFET3 hand-held dynamometer (HHD) in three lower limb muscle groups. Methods: Maximum voluntary isometric contraction (MVIC) of hip extension, knee extension and ankle plantar-flexion were measured in 38 healthy participants (males=18, females= 20) by two testers on separate days using the MicroFET3 HHD. The reliability analysis was carried out using intra-class correlation coefficients (ICCs) to measure association and Band and Altman plots to demonstrate agreement. Results: The results showed that intra-tester reliability was moderate to excellent; with associations ranging from ICC 0.56 - 0.92 and higher agreement for knee and ankle than hip measurements was shown. Inter-tester reliability was lower, with hip and knee associations ranging from ICC 0.60 - 0.66. Ankle measurements intertester associations were particularly low (ICC 0.23 and 0.15). These values would not be considered acceptable for clinical use. Bland and Altman plots used to demonstrate agreement between testers displayed a considerable lack of agreement with discrepancies of up to 150N noted in measurements. Conclusion: The results suggest that the MicroFET3 HHD displayed moderate to excellent intra-tester reliability and poor to moderate inter-tester reliability and agreement with discrepancies noted between muscle groups. While use of this instrument can be recommended when consistently used by a single tester, further reliability analysis should be carried out before this instrument could be recommended for use by different testers in the clinical setting

A Reproducible Approach to the Assembly of Microcapillaries for Double Emulsion Production

Double emulsions attract considerable interest for their potential utility in applications as diverse as drug delivery, contrast agents, and compartmentalizing analytes for fluorescence-activated cell sorting (FACS). Microfluidic platforms provide a particularly elegant approach to generating these structures, but the construction of devices to provide reproducible and stable production of double emulsions remains challenging. PDMS-based systems require specialized surface treatments that are difficult to implement and lack long-term stability, and current glass microcapillary systems, while offering some advantages, lack flexible and reproducible methods for capillary alignment. This article describes a microcapillary-based approach that addresses these key challenges. Our approach utilizes translational stage elements and alignment end caps that are fixed in place once configured, rather than tightly fitting capillaries. This new approach enables alignment to within ± 10 µm and allows greater flexibility in choosing the dimensions of the capillary, which contributes to the size and stability of formation of the double emulsion. Importantly, it also allows the user to compensate for the deviations from ideal shape that occur in pulled glass capillaries, which has been a source of failure with previous methods. A detailed description of the critical design and operational parameters that affect double emulsion generation in these capillary microfluidic devices is provided

Resumen de investigación: Cadena de valor y potencial de mercado de la chaya para fortalecer la resiliencia climática, seguridad nutricional e ingresos en Guatemala

El análisis de la cadena de valor de la chaya fue realizado por Nadezda Amaya como parte del programa internacional Integrando cadenas de valor agro-biodiversas, cambio climático y nutrición: empoderando a los pobres para manejar mejor el riesgo" respaldado por el Fondo Internacional de Desarrollo Agrícola (FIDA), la Unión Europea (UE) y Programas de investigación del CGIAR sobre Cambio Climático, Agricultura y Seguridad Alimentaria (CCAFS) y Agricultura para la Nutrición y la Salud (A4NH)

Research brief: Value chain and market potential of Chaya to strengthen climate resilience, nutrition security and incomes in Guatemala

Chaya (Cnidoscolus aconitifolius) is a perennial vegetable native to Guatemala, which has potential to make significant nutritional and health contributions in vulnerable communities due to its high nutritional value and capacity to produce leaves yield year-round. Chaya can be considered as a ‘superfood’ and as a viable option for an economic food supply for the Guatemalan population. Yet, paradoxically, its production, consumption and marketing have been poorly studied and promoted insofar. In 2017, a value chain assessment was carried out by Bioversity International and the Universidad del Valle de Guatemala (UVG) to contribute to fill this gap in knowledge, and identify opportunities and constraints for developing the market of chaya in Guatemala. This study deployed a Rapid Market Appraisal methodology to collect qualitative data through semi-structured interviews of different stakeholders engaged in the chaya value chain, including producers, vendors, consumers, indirect actors and other informed participants. This brief presents some key results of this research