Exact Finite-Size-Scaling Corrections to the Critical Two-Dimensional Ising Model on a Torus

We analyze the finite-size corrections to the energy and specific heat of the critical two-dimensional spin-1/2 Ising model on a torus. We extend the analysis of Ferdinand and Fisher to compute the correction of order L^{-3} to the energy and the corrections of order L^{-2} and L^{-3} to the specific heat. We also obtain general results on the form of the finite-size corrections to these quantities: only integer powers of L^{-1} occur, unmodified by logarithms (except of course for the leading $\log L$ term in the specific heat); and the energy expansion contains only odd powers of L^{-1}. In the specific-heat expansion any power of L^{-1} can appear, but the coefficients of the odd powers are proportional to the corresponding coefficients of the energy expansion.Comment: 26 pages (LaTeX). Self-unpacking file containing the tex file and three macros (indent.sty, eqsection.sty, subeqnarray.sty). Added discussions on the results and new references. Version to be published in J. Phys.

On the quantum stress tensor for extreme 2D Reissner-Nordstrom black holes

Contrary to previous claims, it is shown that the expectation values of the quantum stress tensor for a massless scalar field propagating on a two-dimensional extreme Reissner-Nordstrom black hole are indeed regular on the horizon.Comment: 5 pages, revtex, 1 figur

C_xN_y : new carbon nitride organic photocatalysts

The search for metal-free and visible light-responsive materials for photocatalytic applications has attracted the interest of not only academics but also the industry in the last decades. Since graphitic carbon nitride (g-C3N4) was first reported as a metal-free photocatalyst, this has been widely investigated in different light-driven reactions. However, the high recombination rate, low electrical conductivity, and lack of photoresponse in most of the visible range have elicited the search for alternatives. In this regard, a broad family of carbon nitride (CxNy) materials was anticipated several decades ago. However, the attention of the researchers in these materials has just been awakened in the last years due to the recent success in the syntheses of some of these materials (i.e., C3N3, C2N, C3N, and C3N5, among others), together with theoretical simulations pointing at the excellent physico-chemical properties (i.e., crystalline structure and chemical morphology, electronic configuration and semiconducting nature, or high refractive index and hardness, among others) and optoelectronic applications of these materials. The performance of CxNy, beyond C3N4, has been barely evaluated in real applications, including energy conversion, storage, and adsorption technologies, and further work must be carried out, especially experimentally, in order to confirm the high expectations raised by simulations and theoretical calculations. Herein, we have summarized the scarce literature related to recent results reporting the synthetic routes, structures, and performance of these materials as photocatalysts. Moreover, the challenges and perspectives at the forefront of this field using CxNy materials are disclosed. We aim to stimulate the research of this new generation of CxNy-based photocatalysts, beyond C3N4, with improved photocatalytic efficiencies by harnessing the striking structural, electronic, and optical properties of this new family of materials

Carbonaceous materials : the beauty of simplicity

The current mandates of a sustainable society and circular economy lead to the request that materials chemistry, but also chemistry as such, has to become significantly redesigned. Changes include commonplaces as the glassware we use, the minimization of wastes and side products or replacement strategies in the materials choice, among others. In this context, “carbons” are very versatile and already have found their place in a myriad of applications for a “carbon-neutral” society. They already take key enabling positions for sensors and biomaterials preparation, as energy conversion and storage electrode, or as effluent remediation sorbents. Herein, we describe how carbon chemistry can be again re-designed to outperform benchmark materials in a number of fields, especially in energy storage, (electro)catalysis, as sorbent, but also in a new chemistry of the confined state

Participatory varietal selection of potato using the mother & baby trial design: A gender-responsive trainer’s guide.

This guide aims to provide step-by-step guidance on facilitating and documenting the PVS dynamics using the MBT design to select, and eventually release, potato varieties preferred by end-users that suit male and female farmers ’different needs, diverse agro-systems, and management practices, as well as traders ’and consumers’ preferences

Test of nuclear level density inputs for Hauser-Feshbach model calculations

The energy spectra of neutrons, protons, and alpha-particles have been measured from the d+59Co and 3He+58Fe reactions leading to the same compound nucleus, 61$Ni. The experimental cross sections have been compared to Hauser-Feshbach model calculations using different input level density models. None of them have been found to agree with experiment. It manifests the serious problem with available level density parameterizations especially those based on neutron resonance spacings and density of discrete levels. New level densities and corresponding Fermi-gas parameters have been obtained for reaction product nuclei such as 60Ni,60Co, and 57Fe