Novel magnetic properties of graphene: Presence of both ferromagnetic and antiferromagnetic features and other aspects

Investigations of the magnetic properties of graphenes prepared by different methods reveal that dominant ferromagnetic interactions coexist along with antiferromagnetic interactions in all the samples. Thus, all the graphene samples exhibit room-temperature magnetic hysteresis. The magnetic properties depend on the number of layers and the sample area, small values of both favoring larger magnetization. Molecular charge-transfer affects the magnetic properties of graphene, interaction with a donor molecule such as tetrathiafulvalene having greater effect than an electron-withdrawing molecule such as tetracyanoethyleneComment: 16 pges, 5 figure

Quenching of fluorescence of aromatic molecules by graphene due to electron transfer

Investigations on the fluorescence quenching of graphene have been carried out with two organic donor molecules, pyrene butanaoic acid succinimidyl ester (PyBS, I) and oligo(p-phenylenevinylene) methyl ester (OPV-ester, II). Absorption and photoluminescence spectra of I and II recorded in mixture with increasing the concentrations of graphene showed no change in the former, but remarkable quenching of fluorescence. The property of graphene to quench fluorescence of these aromatic molecules is shown to be associated with photo-induced electron transfer, on the basis of fluorescence decay and time-resolved transient absorption spectroscopic measurements.Comment: 18 pages, 6 figure

Coastal windstorms create unsteady, unpredictable storm surges in a fluvial Maine estuary

Storm surges create coastal flooding that can be damaging to life and property. In estuaries with significant river influence (fluvial), it is possible for tides, storm surge, and river discharge to interact and enhance surges relative to the immediate coast. These tide-surge-river interactions were previously identified in a fluvial Maine estuary as higher frequency (\u3efour cycles per day) oscillations to storm surge which were proposed to be incited by enhanced friction and resonance during certain windstorm events (Spicer et al. 2019). The relative contributions to tide-surge-river interaction from atmospheric forcing variables (wind, barometric pressure, and externally generated surge) remains unclear. This work seeks to decompose and analyze a recent windstorm surge event to better isolate the effects of atmospheric forcing on tidesurge-river interaction. Results show total storm surges in the fluvial estuary to be two times larger than at the estuary mouth because of tide-surge-river interaction. Analysis indicated at least 50% of the magnitude of tide-surge-river interactions are created by non-tidal forcing, in the form of wind, enhancing frictional energy in the estuary. The remaining tide-surge-river interaction is likely a result of changes in tidal wave propagation speed due to surge deepening the mean estuary water level

Synthetic Aspects and Selected Properties of Graphene

Graphene has generated great sensation owing to its fascinating properties with possible potential applications. This two‐dimensional material exhibits half‐ integer quantum Hall effect and an ambipolar electric field effect, along with ballistic conduction of charge carriers. In this article, we provide a overview on some aspects of graphene devoting the special attention to synthesis, functionalization, self‐assembly, surface properties, gas adsorption and fluorescence quenching ability of graphene. Graphenes with varying number of layers can be synthesized by using different strategies. Graphene can be functionalized by different means in order to disperse it in various solvents. We also present the self‐assembly of graphene at the liquid‐liquid interface besides its surface properties including adsorption of hydrogen, carbon dioxide and methane. The remarkable property of graphene of quenching fluorescence of aromatic molecules is shown to be associated with photo‐induced electron transfe

Line Defects in Molybdenum Disulfide Layers

Layered molecular materials and especially MoS2 are already accepted as promising candidates for nanoelectronics. In contrast to the bulk material, the observed electron mobility in single-layer MoS2 is unexpectedly low. Here we reveal the occurrence of intrinsic defects in MoS2 layers, known as inversion domains, where the layer changes its direction through a line defect. The line defects are observed experimentally by atomic resolution TEM. The structures were modeled and the stability and electronic properties of the defects were calculated using quantum-mechanical calculations based on the Density-Functional Tight-Binding method. The results of these calculations indicate the occurrence of new states within the band gap of the semiconducting MoS2. The most stable non-stoichiometric defect structures are observed experimentally, one of which contains metallic Mo-Mo bonds and another one bridging S atoms

Theorems on shear-free perfect fluids with their Newtonian analogues

In this paper we provide fully covariant proofs of some theorems on shear-free perfect fluids. In particular, we explicitly show that any shear-free perfect fluid with the acceleration proportional to the vorticity vector (including the simpler case of vanishing acceleration) must be either non-expanding or non-rotating. We also show that these results are not necessarily true in the Newtonian case, and present an explicit comparison of shear-free dust in Newtonian and relativistic theories in order to see where and why the differences appear.Comment: 23 pages, LaTeX. Submitted to GR

Gravito-electromagnetism

We develop and apply a fully covariant 1+3 electromagnetic analogy for gravity. The free gravitational field is covariantly characterized by the Weyl gravito-electric and gravito-magnetic spatial tensor fields, whose dynamical equations are the Bianchi identities. Using a covariant generalization of spatial vector algebra and calculus to spatial tensor fields, we exhibit the covariant analogy between the tensor Bianchi equations and the vector Maxwell equations. We identify gravitational source terms, couplings and potentials with and without electromagnetic analogues. The nonlinear vacuum Bianchi equations are shown to be invariant under covariant spatial duality rotation of the gravito-electric and gravito-magnetic tensor fields. We construct the super-energy density and super-Poynting vector of the gravitational field as natural U(1) group invariants, and derive their super-energy conservation equation. A covariant approach to gravito-electric/magnetic monopoles is also presented.Comment: 14 pages. Version to appear in Class. Quant. Gra

Human iPSC-hepatocyte modeling of alpha-1 antitrypsin heterozygosity reveals metabolic dysregulation and cellular heterogeneity

Individuals homozygous for the “Z” mutation in alpha-1 antitrypsin deficiency are known to be at increased risk for liver disease. It has also become clear that some degree of risk is similarly conferred by the heterozygous state. A lack of model systems that recapitulate heterozygosity in human hepatocytes has limited the ability to study the impact of a single Z alpha-1 antitrypsin (ZAAT) allele on hepatocyte biology. Here, we describe the derivation of syngeneic induced pluripotent stem cells (iPSCs) engineered to determine the effects of ZAAT heterozygosity in iPSC-hepatocytes (iHeps). We find that heterozygous MZ iHeps exhibit an intermediate disease phenotype and share with ZZ iHeps alterations in AAT protein processing and downstream perturbations including altered endoplasmic reticulum (ER) and mitochondrial morphology, reduced mitochondrial respiration, and branch-specific activation of the unfolded protein response in cell subpopulations. Our model of MZ heterozygosity thus provides evidence that a single Z allele is sufficient to disrupt hepatocyte homeostatic function.This work was supported by an Alpha-1 Foundation John W. Walsh Translational Research Award (to J.E.K.); a CJ Martin Early Career Fellowship from the Australian National Health and Medical Research Council (to R.B.W.); NIH grant R01HL095993 (to D.N.K.); and NIH grants R01DK101501 (to A.A.W.) and R01DK117940 (to A.N.H. and A.A.W.). iPSC distribution and disease modeling is supported by NIH grants U01TR001810 (to D.N.K. and A.A.W.) and N0175N92020C00005 (to D.N.K.); and by The Alpha-1 Project (TAP), a wholly owned subsidiary of the Alpha-1 Foundation (to D.N.K. and A.A.W.)

Mucopolysaccharidoses in northern Brazil: Targeted mutation screening and urinary glycosaminoglycan excretion in patients undergoing enzyme replacement therapy

Mucopolysaccharidoses (MPS) are rare lysosomal disorders caused by the deficiency of specific lysosomal enzymes responsible for glycosaminoglycan (GAG) degradation. Enzyme Replacement Therapy (ERT) has been shown to reduce accumulation and urinary excretion of GAG, and to improve some of the patients’ clinical signs. We studied biochemical and molecular characteristics of nine MPS patients (two MPS I, four MPS II and three MPS VI) undergoing ERT in northern Brazil. The responsiveness of ERT was evaluated through urinary GAG excretion measurements. Patients were screened for eight common MPS mutations, using PCR, restriction enzyme tests and direct sequencing. Two MPS I patients had the previously reported mutation p.P533R. In the MPS II patients, mutation analysis identified the mutation p.R468W, and in the MPS VI patients, polymorphisms p.V358M and p.V376M were also found. After 48 weeks of ERT, biochemical analysis showed a significantly decreased total urinary GAG excretion in patients with MPS I (p < 0.01) and MPS VI (p < 0.01). Our findings demonstrate the effect of ERT on urinary GAG excretion and suggest the adoption of a screening strategy for genotyping MPS patients living far from the main reference centers