Note on the Preparation of Ethyl Cyclohexylidene-Cyanoacetate

Ethyl cyclohexylidene-cyanoacetate has been prepared by the condensation of ethyl cyanoacetate and cyclohexanone under pressure and in the presence of various catalysts i. e. sodium ethoxide, piperidirne pyridine , piperazine , acid amides, soluble salts of amines or quarternary ammonium bases with an organic acid, acetamide, and ammonium acetate and acetic acid

2-Dimethylaminopropyl Esters of Some Substituted Acetic Acids

2-dimethylaminopropyl esters of folowing acids were prepared: benzoic, phenylacetic, diphenylacetic, B, B -diphenylrpropionic, a- phenylbutyric, acetylmandelic and benzilic

2-Dimethylaminopropyl Esters of Some Substituted Acetic Acids

2-dimethylaminopropyl esters of folowing acids were prepared: benzoic, phenylacetic, diphenylacetic, B, B -diphenylrpropionic, a- phenylbutyric, acetylmandelic and benzilic

Phenomenological description of the nonlocal magnetization relaxation in magnonics, spintronics, and domain-wall dynamics

A phenomenological equation called Landau-Lifshitz-Baryakhtar (LLBar) equation, which could be viewed as the combination of Landau-Lifshitz (LL) equation and an extra "exchange damping" term, was derived by Baryakhtar using Onsager's relations. We interpret the origin of this "exchange damping" as nonlocal damping by linking it to the spin current pumping. The LLBar equation is investigated numerically and analytically for the spin wave decay and domain wall motion. Our results show that the lifetime and propagation length of short-wavelength magnons in the presence of nonlocal damping could be much smaller than those given by LL equation. Furthermore, we find that both the domain wall mobility and the Walker breakdown field are strongly influenced by the nonlocal damping.Comment: 10 pages, 6 figure

Termination Reaction in the Anionic Polymerization of Methacrylonitrile

The anionic polymerization of methacrylonitrile initiated by triethylphosphine in dimethylformamide was studied. Experimental evidence for two mechanisms of termination reaction was obtained. By addition of water or alcohol in polymerizing system the rate of polymerization and molecular weight of polymethacrylon1itrile decrease, which proves the termination reaction to be bimolecular and proceed by interaction of the active carbanion with water or alcohol. The rate constant for termination of free anions with water was determined, k~,0 = 2.2 x 102 dm3 moP s-1• The termination reaction could not be excluded by purification and prolonged drying of all components of the system, which indicates that the second mechanism of termination is operative as well. Conductivity measurements gave evidence for a monomolecular spontaneous reaction leading to deactivation of the anion

Photometric selection and redshifts for quasars in the Kilo-Degree Survey Data Release 4

We present a catalog of quasars and corresponding redshifts in the Kilo-Degree Survey (KiDS) Data Release 4. We trained machine learning (ML) models, using optical ugri and near-infrared ZYJHK_s bands, on objects known from Sloan Digital Sky Survey (SDSS) spectroscopy. We define inference subsets from the 45 million objects of the KiDS photometric data limited to 9-band detections. We show that projections of the high-dimensional feature space can be successfully used to investigate the estimations. The model creation employs two test subsets: randomly selected and the faintest objects, which allows to fit the bias versus variance trade-off. We tested three ML models: random forest (RF), XGBoost (XGB), and artificial neural network (ANN). We find that XGB is the most robust model for classification, while ANN performs the best for combined classification and redshift. The inference results are tested using number counts, Gaia parallaxes, and other quasar catalogs. Based on these tests, we derived the minimum classification probability which provides the best purity versus completeness trade-off: p(QSO_cand) > 0.9 for r < 22 and p(QSO_cand) > 0.98 for 22 < r < 23.5. We find 158,000 quasar candidates in the safe inference subset (r < 22) and an additional 185,000 candidates in the reliable extrapolation regime (22 < r < 23.5). Test-data purity equals 97% and completeness is 94%; the latter drops by 3% in the extrapolation to data fainter by one magnitude than the training set. The photometric redshifts were modeled with Gaussian uncertainties. The redshift error (mean and scatter) equals 0.01 +/- 0.1 in the safe subset and -0.0004 +/- 0.2 in the extrapolation, in a redshift range of 0.14 < z < 3.63. Our success of the extrapolation challenges the way that models are optimized and applied at the faint data end. The catalog is ready for cosmology and active galactic nucleus (AGN) studies.Comment: We publicly release the catalog at kids.strw.leidenuniv.nl/DR4/quasarcatalog.php , and the code at github.com/snakoneczny/kids-quasar

KiDS+GAMA:The weak lensing calibrated stellar-to-halo mass relation of central and satellite galaxies

We simultaneously present constraints on the stellar-to-halo mass relation for central and satellite galaxies through a weak lensing analysis of spectroscopically classified galaxies. Using overlapping data from the fourth data release of the Kilo-Degree Survey (KiDS), and the Galaxy And Mass Assembly survey (GAMA), we find that satellite galaxies are hosted by halo masses that are $0.53 \pm 0.39$ dex (68\% confidence, $3\sigma$ detection) smaller than those of central galaxies of the same stellar mass (for a stellar mass of $\log(M_{\star}/M_{\odot}) = 10.6$). This is consistent with galaxy formation models, whereby infalling satellite galaxies are preferentially stripped of their dark matter. We find consistent results with similar uncertainties when comparing constraints from a standard azimuthally averaged galaxy-galaxy lensing analysis and a two-dimensional likelihood analysis of the full shear field. As the latter approach is somewhat biased due to the lens incompleteness and as it does not provide any improvement to the precision when applied to actual data, we conclude that stacked tangential shear measurements are best-suited for studies of the galaxy-halo connection.Comment: 12 pages, 10 figures, accepted for publication in A&