Influence of water absorption in flexible epoxy resins on the space charge behaviour

The aim of the current work is to achieve a better understanding of the influence of water uptake in flexible epoxy resins on the space charge dynamics at high electric fields. The space charge behaviour was studied using pulsed electroacoustic (PEA) technique. The samples were prepared from Araldite CY1311, which is a bisphenol-A epoxy resin. This particular resin was chosen because its glass transition is 0°C and hence it is in a flexible state at room temperature. All samples were conditioned in containers with saturated salt solutions or de-ionised water so that various water uptake levels were obtained. It was found that the space charge dynamics was correlated with the amount of absorbed water in the samples and this is consistent with the dielectric measurements made on the same material where ion transport was identified as the main charge transport process from the observed QDC behaviour

Limitations of Kramers-Kronig transform for calculation of the DC conductance magnitude from dielectric measurements

The Kramers-Kronig (K-K) transform relates the real and imaginary parts of the complex susceptibility as a consequence of the principle of causality. It is a special case of the Hilbert transform and it is often used for estimation of the DC conductance from dielectric measurements. In this work, the practical limitations of a numerical implementation of the Kramers-Kronig transform was investigated in the case of materials that exhibit both DC conductance and quasi-DC (QDC) charge transport processes such as epoxy resins. The characteristic feature of a QDC process is that the real and imaginary parts of susceptibility (permittivity) follow fractional power law dependences with frequency with the low frequency exponent approaching -1. Dipolar relaxation in solids on the other hand has a lower frequency exponent <1. The computational procedure proposed by Jonscher for calculation of the K-K transform involves extrapolation and truncation of the data to low frequencies so that convergence of the integrals is ensured. The validity of the analysis is demonstrated by performing K-K transformation on real experimental data and on theoretical data generated using the Dissado-Hill function. It has been found that the algorithm works well for dielectric relaxation responses but it is apparent that it does not work in the case of a low frequency power law in which the low frequency exponent approaches -1, i.e. in the case of QDC responses. In this case convergence can only be guaranteed by extrapolating the low frequency power law over many decades towards zero frequency

Statistical Analysis of Partial Discharges from Electrical Trees Grown in a Flexible Epoxy Resin

Electrical treeing is a long-term degradation mechanism in polymeric insulation, which can lead to electrical failure of HV insulation systems. The rate at which trees grow across the insulation depends on the PD activity occurring within them and hence the detection of the onset of electrical treeing could be established by PD monitoring. In this paper, a statistical analysis of the partial discharges detected during the growth of trees in an epoxy resin will be reported. The aim of this work was to provide additional insight into the physical mechanisms that lead to the observed fluctuations in the partial discharge activity. The results demonstrate interesting correlations between a number of statistical parameters, such as average discharge magnitude and standard deviation in the partial discharge amplitudes. These correlations could also be related to physical parameters such as the applied voltage magnitude and the measured power dissipation due to the partial discharges occurring during tree growth. The implications of this work for deterministic methodologies for the simulation of tree growth as well as for condition monitoring using feature recognition strategies for the early detection of tree growth will be discussed

Influence of the temperature on the dielectric properties of epoxy resins

Electrical degradation processes in epoxy resins, such as electrical treeing, were found to be dependent on the temperature at which the experiments were carried out. Therefore, it is of considerable research interest to study the influence of temperature on the dielectric properties of the polymers and to relate the effect of temperature on these properties to the possible electrical degradation mechanisms. In this work, the dielectric properties of two different epoxy resin systems have been characterized via dielectric spectroscopy. The epoxy resins used were bisphenol-A epoxy resins Araldite CY1301 and Araldite CY1311, the later being a modified version of the former with added plasticizer. The CY1301 samples were tested below and above their glass transition temperature, while the CY1311 were tested well above it. Both epoxy systems possess similar behaviour above the glass transition temperature, e.g. in a flexible state, which can be characterized as a low frequency dispersion (LFD). On the other hand, it was found that below the glass transition temperature CY1301 samples have almost “flat” dielectric response in the frequency range considered. The influence of possible interfacial features on the measured results is discussed

Electron spin resonance study of changes during the development of a mouse myeloid leukaemia. I. Paramagnetic metal ions.

The blood, spleen and liver of mice were examined by means of electron spin resonance (e.s.r.), throughout the course of myeloid leukaemia induced by intravenous injection of leukaemic spleen cells. In blood, marked increases in the concentrations of iron transferrin and ceruloplasmin occurred within the first 3 days after injection. In the spleen, changes in the concentrations of paramagnetic copper and iron complexes were detectable by about the 5th day, before any measurable splenic enlargement, whilst in the liver changes were detectable by about the 8th day. The changes occurring in blood, spleen and liver during the development of leukaemia appear to be related and they are discussed in terms of iron transport

Nonlinear Band Gap Transmission in Optical Waveguide Arrays

The effect of nonlinear transmission in coupled optical waveguide arrays is theoretically investigated via numerical simulations on the corresponding model equations. The realistic experimental setup is suggested injecting the beam in a single boundary waveguide, linear refractive index of which ($n_0$) is larger than one ($n$) of other identical waveguides in the array. Particularly, the effect holds if $\omega(n_0-n)/c>2Q$, where $Q$ is a linear coupling constant between array waveguides, $\omega$ is a carrier wave frequency and $c$ is a light velocity. Making numerical experiments in case of discrete nonlinear Schr\"odinger equation it is shown that the energy transfers from the boundary waveguide to the waveguide array above certain threshold intensity of the injected beam. This effect is explained by means of the creation and propagation of gap solitons in full analogy with the similar phenomenon of nonlinear supratransmission [F. Geniet, J. Leon, PRL, {\bf 89}, 134102, (2002)] in case of discrete sine-Gordon lattice.Comment: 4 pages, 6 figures. Phys. Rev. Lett. (in press

Influence of absorbed moisture on the dielectric properties of epoxy resins

The dielectric response of two bisphenol-A epoxy resin systems Araldite CY1301 (Tg ~ 50°C) and Araldite CY1311 (Tg ~0°C) was studied at different levels of absorbed moisture. The dielectric measurements were carried out over the frequency range 1 mHz to 100 kHz and the results were characterised in terms of dc bulk electrical conduction and dielectric processes. The characteristic parameters (frequency and magnitude) of all processes have been found to be moisture dependent. In both resins above the glass transition temperature, absorbed moisture was found to be implicated in the formation of a bulk quasi-dc dielectric response consistent with cluster formation of the absorbed water molecules

An idealised study for the evolution of a shoreface nourishment

We develop an idealised one dimensional (cross-shore) morphodynamic model that couples wave, tide and sediment dynamics to study the effect and evolution of a shoreface nourishment. Sediment fluxes driven by wave skewness, wave asymmetry (both onshore) and return flow (offshore) are considered. With the aid of new analytical expressions for the skewness and standard deviation of wave velocity and acceleration, sediment fluxes are calculated. Nourishment is viewed as a perturbation to the system in equilibrium that is subject to the divergence of the perturbed sediment flux and a gravity driven diffusion term. Depending on the location, a nourishment may provide a feeder or lee effect. In moderate and mild wave conditions, the evolution of a nourishment primarily depends on the relative location of nourishment and break point. Placed well offshore of the break point, the nourishment induces an overall positive perturbation in sediment flux, resulting in onshore migration (feeder effect). Located closer to the break point, the nourishment induces an earlier wave breaking, which dissipates part of the wave energy (lee effect), leading to a negative sediment flux perturbation around this break point and a positive sediment flux perturbation around the break point of the un-nourished beach. Depending on the intensity of the earlier breaking, the nourishment either migrates onshore (weak break) or splits into onshore and offshore moving parts (strong break). The relative importance of the diffusion term and the divergence of perturbed sediment flux may lead to a primarily migrating or decaying evolution of nourishment. In storm wave conditions, the nourishment tends to move offshore due to the predominance of return flow driven sediment flux. The sensitivity to wave period and tide are also studied. Model results are consistent with observations, as well as prevailing theory on cross-shore sediment transport