The use of zooplankton metrics to determine the trophic status and ecological potential: An approach in a large Mediterranean watershed.

In the European Water Framework Directive, zooplankton was not included as a Biological Quality Element despite its important place in the aquatic trophic web. In the present study on zooplankton abundances and biomasses, we used several metrics to test their ability to detect differences among trophic statuses and ecological potential levels, and collected a large sum of data in more than 60 reservoirs at Ebro watershed, on more than 300 sampling occasions over 10 years. Our results indicate that most zooplankton metrics are correlated to environmental variables that determine reservoirs' trophic states, especially chlorophyll a and total phosphorus. The metrics with better sensitivity to differentiate trophic states and ecological potential levels were ZOO (total zooplankton), LZOO (large zooplankton), CLAD (cladocerans), and ZOO:CHLA (zooplankton:chlorophyll a ratio). Microcrustacean metrics such as DAPHN (Daphnia), COP (copepods), CYCLO (cyclopoids), and CALA (calanoids) were good at differentiating between high and low water quality in trophic status (oligotrophic-eutrophic) and ecological potential (good or superior-moderate). Thus, zooplankton can be used as a valuable tool to determine water quality; we believe that zooplankton should be considered a Biological Quality Element withinWater Framework Directive monitoring programs for inland waters

Facile mechanochemical modification of g-C3N4 for selective photo-oxidation of benzyl alcohol

Graphitic carbon nitride enriched with ZnO or Fe2O3 were synthesized using a simple one-pot mechanochemical method. By using this method, composite samples were synthetized without the production of any potentially hazardous waste. The synthesized materials were used as catalysts during the selective photo-oxidation of benzyl alcohol. Both composite materials displayed an enhancement of the activity and benzaldehyde selectivity with respect to the pure g-C3N4. The most active catalyst was Fe2O3/g-C3N4. The conversion and benzaldehyde selectivity of this sample were 20 and 70 %, respectively. It showed a considerable increase of the benzaldehyde selectivity compared to the pure g-C3N4 and TiO2 P25 commercial reference. A complete structural and electronic characterization using Scanning Electron Microscopy-Energy Dispersive (SEM-EDX), BET measurements, X-ray diffraction (XRD), X-ray Photoelectron (XPS), and UV–visible spectroscopies was carried out. The characterization analysis pointed out the leading role of the crystallinity and surface concentration over the activity and benzaldehyde selectivity of the reactio

Dependence of Induced Biological Damage on the Energy Distribution and Intensity of Clinical Intra-Operative Radiotherapy Electron Beams

The survival fraction of epithelial HaCaT cells was analysed to assess the biological damage caused by intraoperative radiotherapy electron beams with varying energy spectra and intensities. These conditions were achieved by irradiating the cells at different depths in water using nominal 6 MeV electron beams while consistently delivering a dose of 5 Gy to the cell layer. Furthermore, a Monte Carlo simulation of the entire irradiation procedure was performed to evaluate the molecular damage in terms of molecular dissociations induced by the radiation. A significant agreement was found between the molecular damage predicted by the simulation and the damage derived from the analysis of the survival fraction. In both cases, a linear relationship was evident, indicating a clear tendency for increased damage as the averaged incident electron energy and intensity decreased for a constant absorbed dose, lowering the dose rate. This trend suggests that the radiation may have a more pronounced impact on surrounding healthy tissues than initially anticipated. However, it is crucial to conduct additional experiments with different target geometries to confirm this tendency and quantify the extent of this effect

Electron transport in furfural: dependence of the electron ranges on the cross sections and the energy loss distribution functions

GEC 2016 ; 69th Annual Gaseous Electronics Conference ; Bochum, Germany, Monday–Friday, October 10–14Recent theoretical and experimental studies have provided a complete set of differential and integral electron scattering cross section data from furfural over a broad energy range1, 2. The energy loss distribution functions have been determined in this study by averaging electron energy loss spectra for different incident energies and scattering angles. All these data have been used as input parameters for an event by event Monte Carlo simulation procedure to obtain the electron energy deposition patterns and electron ranges in liquid furfural. The dependence of these results on the input cross sections is then analysed to determine the uncertainty of the simulated values.Peer Reviewe

Thermo-Photocatalysis: Environmental and Energy Applications

Catalysis is an integral part of a majority of chemical operations focused on the generation of value-added chemicals or fuels. Similarly, the extensive use of fossil-derived fuels and chemicals has led to deterioration of the environment. Catalysis currently plays a key role in mitigating such effects. Thermal catalysis and photocatalysis are two well-known catalytic approaches that were applied in both energy and environmental fields. Thermo-photocatalysis can be understood as a synergistic effect of the two catalytic processes with key importance in the use of solar energy as thermal and light source. This Review provides an update on relevant contributions about thermo-photocatalytic systems for environmental and energy applications. The reported activity data are compared with the conventional photocatalytic approach and the base of the photothermal effect is analyzed. Some of the systems based on the positive aspects of thermo- and photocatalysis could be the answer to the energy and environmental crisis when taking into account the outstanding results with regard to chemical efficiency and energy saving. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei

Detection of a 73-75 kDa and a 123 kDa fractions of Leishmania antigen in urine of patients with visceral leishmaniosis

Two polypeptide fractions of 72-75 kD were detected in the urine of 14 of 15 patients with visceral leishmaniasis (VL) and another fraction of 123 kD was found in 10 of the 15 patients by using a Western blot technique. None of these fractions was detected in the urine of 20 controls. These results suggest that antigen detection in urine could be a powerful, noninvasive method for VL diagnosi

Detection of a 73-75 kDa and a 123 kDa fractions of Leishmania antigen in urine of patients with visceral leishmaniosis

Two polypeptide fractions of 72-75 kD were detected in the urine of 14 of 15 patients with visceral leishmaniasis (VL) and another fraction of 123 kD was found in 10 of the 15 patients by using a Western blot technique. None of these fractions was detected in the urine of 20 controls. These results suggest that antigen detection in urine could be a powerful, noninvasive method for VL diagnosi

Dependence of induced biological damage on the energy distribution and intensity of clinical Intra-operative radiotherapy electron beams

The survival fraction of epithelial HaCaT cells was analysed to assess the biological damage caused by intraoperative radiotherapy electron beams with varying energy spectra and intensities. These conditions were achieved by irradiating the cells at different depths in water using nominal 6 MeV electron beams while consistently delivering a dose of 5 Gy to the cell layer. Furthermore, a Monte Carlo simulation of the entire irradiation procedure was performed to evaluate the molecular damage in terms of molecular dissociations induced by the radiation. A significant agreement was found between the molecular damage predicted by the simulation and the damage derived from the analysis of the survival fraction. In both cases, a linear relationship was evident, indicating a clear tendency for increased damage as the averaged incident electron energy and intensity decreased for a constant absorbed dose, lowering the dose rate. This trend suggests that the radiation may have a more pronounced impact on surrounding healthy tissues than initially anticipated. However, it is crucial to conduct additional experiments with different target geometries to confirm this tendency and quantify the extent of this effect.Ministerio de Ciencia e Innovación (España)Ministerio de Economía y Competitividad (España)Instituto de Salud Carlos IIIEuropean CommissionDepto. de Estructura de la Materia, Física Térmica y ElectrónicaFac. de Ciencias FísicasTRUEpubDescuento UC