85 research outputs found

    Planning in the face of immovable subjects: a dialogue about resistance to development forces

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    Urban development can often seem an irresistible force. The imperatives of development are deeply inscribed in the DNA of liberal capitalist societies. As well as realising profit-making opportunities for the private sector, urban change is a mechanism for (re)generating neighbourhoods, for providing public goods such as waste management, energy generation or public housing. The state may seek to mediate, ameliorate or shape development forces, thereby alleviating tensions and inequalities between divergent publics, and establishing claims to a greater public interest in certain forms of change. As it does so, state support may make development seem even more irresistible, especially if space for political challenge closes down. Yet, the seemingly irresistible force often summons seemingly immovable subjects of resistance: namely citizens and campaign groups who stand against planned changes and declare: ‘we shall not be moved’. Sometimes resistance dissolves with meaningful public input and project improvements; sometimes it remains steadfast in its opposition. The ‘immovable subjects’ who resist are mobilised by concerns to which we may be more or less sympathetic: perceived threats to valued place attachments and identities; outrage at environmental injustices; the desire to defend private property rights; racism and anti-immigrant sentiment. Whether singly or collectively, these claims and their nuanced interpretations can motivate intractable and sometimes violent opposition. The starting point for this Interface is a view that contemporary planning theory and practice continue to struggle with the complex and ambiguous political and ethical challenges posed by the forms of opposition that coalesce around state-mediated urban development. How can, and how should, the ‘essential injustices’ (Davy, 1997) that planning and development generate be managed and distributed? Can meaningful engagement with opposition address tensions and contribute to better outcomes? The implications for representative democracy and collaborative governance are no less profound: from the local to the global, resistance and opposition are central but also often disruptive to the democratic exercise of power.info:eu-repo/semantics/publishedVersio

    Synthesis of Supported Pd-0 Nanoparticles from a Single-Site Pd2+ Surface Complex by Alkene Reduction

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    A surface metal-organic complex, (-AlOx)Pd(acac) (acac = acetylacetonate), is prepared by chemically grafting the precursor Pd(acac)(2) onto gamma-Al2O3 in toluene at 25 degrees C. The resulting surface complex is characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and dynamic nuclear polarization surface-enhanced solid-state nuclear magnetic resonance spectroscopy (DNP SENS). This surface complex is a precursor in the direct synthesis of size-controlled Pd nanoparticles under mild reductive conditions and in the absence of additional stabilizers or pretreatments. Indeed, upon exposure to gaseous ethylene or liquid 1-octene at 25 degrees C, the Pd2+ species is reduced to form Pd-0 nanoparticles with a mean diameter of 4.3 +/- 0.6 nm, as determined by scanning transmission electron microscopy (STEM). These nanoparticles are catalytically relevant using the aerobic 1-phenylethanol oxidation as a probe reaction, with rates comparable to a conventional Pd/Al2O3 catalyst but without an induction period. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature-programmed reaction mass spectrometry (TPR-MS) reveal that the surface complex reduction with ethylene coproduces H-2, acetylene, and 1,3-butadiene. This process reasonably proceeds via an olefin activation/coordination/insertion pathway, followed by beta-hydride elimination to generate free Pd-0. The well-defined nature of the single-site supported Pd2+ precursor provides direct mechanistic insights into this unusual and likely general reductive process

    The effects of quercetin on SW480 human colon carcinoma cells: a proteomic study

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    BACKGROUND: High fruit and vegetable intake is known to reduce the risk of colon cancer. To improve understanding of this phenomenon the action of different phytochemicals on colon cells has been examined. One such compound is quercetin that belongs to the group known as flavonoids. The purpose of this study was to determine the influence of quercetin on the proteome of the SW480 human colon adenocarcinoma cell line, specifically to identify proteins that could be the molecular targets of quercetin in its amelioration of the progression of colon cancer. To this end, two-dimensional gel electrophoresis and mass spectrometry were used to identify proteins that underwent a change in expression following treatment of the cells with 20 ÎŒM quercetin. This could elucidate how quercetin may reduce the progression of colon cancer. RESULTS: Quercetin treatment of the SW480 human colon cancer cells was found to result in the decreased expression of three proteins and the increased expression of one protein. The identified proteins with decreased expression were type II cytoskeletal 8 keratin and NADH dehydrogenase Fe-S protein 3. The other protein with decreased expression was not identified. The protein with increased expression belonged to the annexin family. CONCLUSION: Several proteins were determined to have altered expression following treatment with quercetin. Such changes in the levels of these particular proteins could underlie the chemo-protective action of quercetin towards colon cancer

    Enhancing public awareness and promoting co-responsibility for marine litter in Europe: The challenge of MARLISCO

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    Marine litter is a pervasive and complex societal problem but has no simple solution. Inadequate practices at all levels of production–use–disposal contribute to accumulation of waste on land and at sea. Enhanced societal awareness but also co-responsibility across different sectors and improved interactions between stakeholders are necessary. MARLISCO was a European initiative, which developed and implemented activities across 15 countries. It worked towards raising societal awareness and engagement on marine litter, through a combination of approaches: public exhibitions in over 80 locations; a video competition involving 2100 students; and a legacy of educational and decision-supporting tools. 12 national participatory events designed to facilitate dialogue on solutions brought together 1500 stakeholders and revealed support for cross-cutting, preventive measures. Evaluation during implementation shows that these activities are effective in improving individuals' perceptions about the problem but also commitment in being part of the solution. This paper summarises MARLISCO's approach and highlights a selection of outcomes

    Scale-up of an intensified bioprocess for the expansion of bovine adipose-derived stem cells (bASCs) in stirred tank bioreactors

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    Cultivated meat is an emerging field, aiming to establish the production of animal tissue for human consumption in an in vitro environment, eliminating the need to raise and slaughter animals for their meat. To realise this, the expansion of primary cells in a bioreactor is needed to achieve the high cell numbers required. The aim of this study was to develop a scalable, microcarrier based, intensified bioprocess for the expansion of bovine adipose-derived stem cells as precursors of fat and muscle tissue. The intensified bioprocess development was carried out initially in spinner flasks of different sizes and then translated to fully controlled litre scale benchtop bioreactors. Bioprocess intensification was achieved by utilising the previously demonstrated bead-to-bead transfer phenomenon and through the combined addition of microcarrier and medium to double the existing surface area and working volume in the bioreactor. Choosing the optimal time point for the additions was critical in enhancing the cell expansion. A significant fold increase of 114.19 ± 1.07 was obtained at the litre scale in the intensified bioprocess compared to the baseline (**p < .005). The quality of the cells was evaluated pre- and post-expansion and the cells were found to maintain their phenotype and differentiation capacity

    Exploring public views on marine litter in Europe: Perceived causes, consequences and pathways to change

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    Marine litter is a global challenge and society plays an important role via lifestyles and behaviour, including policy support. We analysed public perceptions of marine litter and contributing factors, using data from 1133 respondents across 16 European countries. People reported high levels of concern about marine litter, and the vast majority (95%) reported seeing litter when visiting the coast. The problem was attributed to product and packaging design and behaviour rather than lack of facilities or accidental loss of items. Retailers, industry and government were perceived as most responsible, but also least motivated and competent to reduce marine litter, whereas scientists and environmental groups were perceived as least responsible but most motivated and competent. Regression analyses demonstrated the importance of psychological factors such as values and social norms above socio-demographic variables. These findings are important for communications and interventions to reduce inputs of marine litter to the natural environment

    Um mundo novo no Atlùntico: marinheiros e ritos de passagem na linha do equador, séculos XV-XX

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    Gasoline characteristics

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    http://www.archive.org/details/gasolinecharacte00mouaThesis (B.S.)--Armour Institute of Technology, 1916 Bibliography: leaf 47 B.S. in Mechanical Engineering, 191
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