635 research outputs found
Chemical constituents of Cardiospermum corindum L. and their distribution in Sapindaceae
AbstractPhytochemical investigation on the aerial parts of Cardiospermum corindum L. led to the isolation of two triterpenes [friedelin (1) and friedelinol (2)], two coumarins, [umbelliferone (4) and scopoletin (5)], three methoxylated flavones [umuhengerin (3), luteolin 3’,4’-dimethyl ether (6) and chrysoeriol (7)], one non-cyanogenic glucoside [epidermin (8)] and one cyclitol [(L)-quebrachitol (9)]. To our knowledge, 2, 3, 6 and 8 were isolated for the first time within Sapindaceae. Of these classes of metabolites, the distribution of methoxylated flavonoids in Cardiospermum is reviewed, including the new records, indicating that polymethoxylated flavonoid (3) may be value as chemotaxonomic markers for this genus
Canted phase in double quantum dots
We perform a Hartree-Fock calculation in order to describe the ground state
of a vertical double quantum dot in the absence of magnetic fields parallel to
the growth direction. Intra- and interdot exchange interactions determine the
singlet or triplet character of the system as the tunneling is tuned. At finite
Zeeman splittings due to in-plane magnetic fields, we observe the continuous
quantum phase transition from ferromagnetic to symmetric phase through a canted
antiferromagnetic state. The latter is obtained even at zero Zeeman energy for
an odd electron number.Comment: 5 pages, 3 figure
Ultrasound attenuation in gap-anisotropic systems
Transverse ultrasound attenuation provides a weakly-coupled probe of momentum
current correlations in electronic systems. We develop a simple theory for the
interpretation of transverse ultrasound attenuation coefficients in systems
with nodal gap anisotropy. Applying this theory we show how ultrasound can
delineate between extended-s and d-wave scenarios for the cuprate
superconductors.Comment: Uuencode file: 4 pages (Revtex), 3 figures. Some references adde
Development of a molecular-based index for assessing iron status in bloom-forming pennate diatoms
Iron availability limits primary productivity in large areas of the world's oceans. Ascertaining the iron status of phytoplankton is essential for understanding the factors regulating their growth and ecology. We developed an incubation-independent, molecular-based approach to assess the iron nutritional status of specific members of the diatom community, initially focusing on the ecologically important pennate diatom Pseudo-nitzschia. Through a comparative transcriptomic approach, we identified two genes that track the iron status of Pseudo-nitzschia with high fidelity. The first gene, ferritin (FTN), encodes for the highly specialized iron storage protein induced under iron-replete conditions. The second gene, ISIP2a, encodes an iron-concentrating protein induced under iron-limiting conditions. In the oceanic diatom Pseudo-nitzschia granii (Hasle) Hasle, transcript abundance of these genes directly relates to changes in iron availability, with increased FTN transcript abundance under iron-replete conditions and increased ISIP2a transcript abundance under iron-limiting conditions. The resulting ISIP2a:FTN transcript ratio reflects the iron status of cells, where a high ratio indicates iron limitation. Field samples collected from iron grow-out microcosm experiments conducted in low iron waters of the Gulf of Alaska and variable iron waters in the California upwelling zone verify the validity of our proposed Pseudo-nitzschia Iron Limitation Index, which can be used to ascertain in situ iron status and further developed for other ecologically important diatoms
Electron energy loss and induced photon emission in photonic crystals
The interaction of a fast electron with a photonic crystal is investigated by
solving the Maxwell equations exactly for the external field provided by the
electron in the presence of the crystal. The energy loss is obtained from the
retarding force exerted on the electron by the induced electric field. The
features of the energy loss spectra are shown to be related to the photonic
band structure of the crystal. Two different regimes are discussed: for small
lattice constants relative to the wavelength of the associated electron
excitations , an effective medium theory can be used to describe the
material; however, for the photonic band structure plays an
important role. Special attention is paid to the frequency gap regions in the
latter case.Comment: 12 pages, 7 figure
Свободные аминокислоты и их азотсодержащие метаболиты в гипоталамусе крыс при острой интоксикации динилом и их корреляция с аминокислотным спектром плазмы крови
аминокислотыгипоталамусдинилотравлениеплазм
Magnetic Field Effects on Neutron Diffraction in the Antiferromagnetic Phase of
We discuss possible magnetic structures in UPt based on our analysis of
elastic neutron-scattering experiments in high magnetic fields at temperatures
. The existing experimental data can be explained by a single-{\bf q}
antiferromagnetic structure with three independent domains. For modest in-plane
spin-orbit interactions, the Zeeman coupling between the antiferromagnetic
order parameter and the magnetic field induces a rotation of the magnetic
moments, but not an adjustment of the propagation vector of the magnetic order.
A triple-{\bf q} magnetic structure is also consistent with neutron
experiments, but in general leads to a non-uniform magnetization in the
crystal. New experiments could decide between these structures.Comment: 5 figures included in the tex
Magnetic structure of CeRhIn_5 as a function of pressure and temperature
We report magnetic neutron-diffraction and electrical resistivity studies on
single crystals of the heavy-fermion antiferromagnet CeRhIn at pressures
up to 2.3 GPa. These experiments show that the staggered moment of Ce and the
incommensurate magnetic structure change weakly with applied pressure up to
1.63 GPa, where resistivity, specific heat and NQR measurements confirm the
presence of bulk superconductivity. This work places new constraints on an
interpretation of the relationship between antiferromagnetism and
unconventional superconductivity in CeRhIn.Comment: 6 pages, 6 figures, submitted to Phys. Rev.
Signatures of the sources in the gravitational waves of a perturbed Schwarzschild black hole
The explicit form of perturbation equation for the Weyl scalar,
containing the matter source terms, is derived for general type D spacetimes.
It is described in detail the particular case of the Schwarzschild spacetime
using in-going penetrating coordinates. As a practical application, we focused
on the emission of gravitational waves when a black hole is perturbed by a
surrounding dust-like fluid matter. The symmetries of the spacetime and the
simplicity of the matter source allow, by means of a spherical harmonic
decomposition, to study the problem by means of a one dimensional numerical
code.Comment: 17 pages, 8 figure
Antiferromagnetic Domains and Superconductivity in UPt3
We explore the response of an unconventional superconductor to spatially
inhomogeneous antiferromagnetism (SIAFM). Symmetry allows the superconducting
order parameter in the E-representation models for UPt3 to couple directly to
the AFM order parameter. The Ginzburg-Landau equations for coupled
superconductivity and SIAFM are solved numerically for two possible SIAFM
configurations: (I) abutting antiferromagnetic domains of uniform size, and
(II) quenched random disorder of `nanodomains' in a uniform AFM background. We
discuss the contributions to the free energy, specific heat, and order
parameter for these models. Neither model provides a satisfactory account of
experiment, but results from the two models differ significantly. Our results
demonstrate that the response of an E_{2u} superconductor to SIAFM is strongly
dependent on the spatial dependence of AFM order; no conclusion can be drawn
regarding the compatibility of E_{2u} superconductivity with UPt3 that is
independent of assumptions on the spatial dependence of AFMComment: 12 pages, 13 figures, to appear in Phys. Rev.
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