7,022 research outputs found
Theoretical evidence for strong correlations and incoherent metallic state in FeSe
The role of electronic Coulomb correlations in iron-based superconductors is
an important open question. We provide theoretical evidence for strong
correlation effects in the FeSe compound, based on dynamical mean field
calculations. A lower Hubbard band is found in the spectral properties.
Moreover, together with significant orbital-dependent mass enhancements, we
find that the normal state is a bad metal over an extended temperature range,
implying a non-Fermi liquid. Predictions for angle-resolved photoemission
spectroscopy are made.Comment: 5 pages, 5 figures, published versio
Roles of Critical Valence Fluctuations in Ce- and Yb-Based Heavy Fermion Metals
The roles of critical valence fluctuations of Ce and Yb are discussed as a
key origin of several anomalies observed in Ce- and Yb-based heavy fermion
systems. Recent development of the theory has revealed that a magnetic field is
an efficient control parameter to induce the critical end point of the
first-order valence transition. Metamagnetism and non-Fermi liquid behavior
caused by this mechanism are discussed by comparing favorably with CeIrIn5,
YbAgCu4, and YbIr2Zn20. The interplay of the magnetic order and valence
fluctuations offers a key concept for understanding Ce- and Yb-based systems.
It is shown that suppression of the magnetic order by enhanced valence
fluctuations gives rise to the coincidence of the magnetic-transition point and
valence-crossover point at absolute zero as a function of pressure or magnetic
field. The interplay is shown to resolve the outstanding puzzle in CeRhIn5 in a
unified way. The broader applicability of this newly clarified mechanism is
discussed by surveying promising materials such as YbAuCu4, beta-YbAlB4, and
YbRh2Si2.Comment: 17 pages, 8 figures, invited paper in special issue on strongly
correlated electron system
Antiferromagnetic order in CeCoIn5 oriented by spin-orbital coupling
An incommensurate spin density wave ( phase) confined inside the
superconducting state at high basal plane magnetic field is an unique property
of the heavy fermion metal CeCoIn. The neutron scattering experiments and
the theoretical studies point out that this state come out from the soft mode
condensation of magnetic resonance excitations. We show that the fixation of
direction of antiferromagnetic modulations by a magnetic field reported by
Gerber et al., Nat. Phys. {\bf 10}, 126 (2014) is explained by spin-orbit
coupling. This result, obtained on the basis of quite general phenomenological
arguments, is supported by the microscopic derivation of the
susceptibility dependence on the mutual orientation of the basal plane magnetic
field and the direction of modulation of spin polarization in a multi-band
metal.Comment: 7 pages plus 2 pages with 2 figure
Polar type density of states in non-unitary odd-parity superconducting states of gap with point nodes
It is shown that the density of states (DOS) proportional to the excitation
energy, the so-called polar like DOS, can arise in the odd-parity states with
the superconducting gap vanishing at points even if the spin-orbit interaction
for Cooper pairing is strong enough. Such gap stuructures are realized in the
non-unitary states, F_{1u}(1,i,0), F_{1u}(1,varepsilon,varepsilon^{2}), and
F_{2u}(1,i,0), classified by Volovik and Gorkov, Sov. Phys.-JETP Vol.61 (1985)
843. This is due to the fact that the gap vanishes in quadratic manner around
the point on the Fermi surface. It is also shown that the region of quadratic
energy dependence of DOS, in the state F_{2u}(1,varepsilon,varepsilon^{2}), is
restricted in very small energy region making it difficult to distinguish from
the polar-like DOS.Comment: 5 pages, 3 figures, submitted to J. Phys.: Condens. Matter Lette
Low-energy excitations in electron-doped metal phthalocyanine from NMR in LiMnPc
Li and H NMR and magnetization measurements in \lpc
(PcCHN), recently proposed as a strongly correlated
metal, are presented. Two different low-frequency dynamics are evidenced. The
first one, probed by H nuclei gives rise to a slowly relaxing magnetization
at low temperature and is associated with the freezing of MnPc spins.
This dynamic is similar to the one observed in pristine -MnPc and
originates from Li depleted chain segments. The second one, evidenced by Li
spin-lattice relaxation rate, is associated with the hopping of the electrons
along Li-rich chains. The characteristic correlation times for the two dynamics
are derived and the role of disorder is briefly discussed.Comment: 7 two-columns pages, 11 figure
Importance of electronic correlations for structural and magnetic properties of the iron pnictide superconductor LaFeAsO
We present calculations of structural and magnetic properties of the
iron-pnictide superconductor LaFeAsO including electron-electron correlations.
For this purpose we apply a fully charge self-consistent combination of
Density-Functional Theory with the Dynamical Mean-Field theory, allowing for
the calculation of total energies. We find that the inclusion of correlation
effects gives a good agreement of the Arsenic z position with experimental data
even in the paramagnetic (high-temperature) phase. Going to low temperatures,
we study the formation of the ordered moment in the striped spin-density-wave
phase, yielding an ordered moment of about 0.60, again in good agreement with
experiments. This shows that the inclusion of correlation effects improves both
structural and magnetic properties of LaFeAsO at the same time.Comment: 7 pages, 5 figures, published versio
Rovibrationally resolved photodissociation of HeH+
Accurate photodissociation cross sections have been obtained for the A-X
electronic transition of HeH+ using ab initio potential curves and dipole
transition moments. Partial cross sections have been evaluated for all
rotational transitions from the vibrational levels v"=0-11 and over the entire
accessible wavelength range 100-1129 Angstrom. Assuming a Boltzmann
distribution of the rovibrational levels of the X state, photodissociation
cross sections are presented for temperatures between 500 and 12,000 K. A
similar set of calculations was performed for the pure rovibrational
photodissociation in the X-X electronic ground state, but covering photon
wavelengths into the far infrared. Applications of the cross sections to the
destruction of HeH+in the early Universe and in UV-irradiated environments such
as primordial halos and protoplanetary disks are briefly discussed
A theory of new type of heavy-electron superconductivity in PrOs_4Sb_12: quadrupolar-fluctuation mediated odd-parity pairings
It is shown that unconventional nature of superconducting state of
PrOs_4Sb_12, a Pr-based heavy electron compound with the filled-Skutterudite
structure, can be explained in a unified way by taking into account the
structure of the crystalline-electric-field (CEF) level, the shape of the Fermi
surface determined by the band structure calculation, and a picture of the
quasiparticles in f-configuration with magnetically singlet CEF ground
state. Possible types of pairing are narrowed down by consulting recent
experimental results. In particular, the chiral "p"-wave states such as
p_x+ip_y is favoured under the magnetic field due to the orbital Zeeman effect,
while the "p"-wave states with two-fold symmetery such as p_x can be stabilized
by a feedback effect without the magnetic field. It is also discussed that the
double superconducting transition without the magnetic field is possible due to
the spin-orbit coupling of the "triplet" Cooper pairs in the chiral state.Comment: 12 pages, 2 figures, submitted to J. Phys.: Condens. Matter Lette
Performance of alumina-supported Pt catalysts in an electron-beam-sustained CO2 laser amplifier
The performance of an alumina-supported Pt catalyst system used to maintain the gas purity in an electron-beam-sustained (636) isotope CO2 laser amplifier has been tested. The system characteristics using the two-zone, parallel flow reactor were determined for both continuous- and end-of-day reactor operation using on-line mass spectrometric sampling. The laser amplifier was run with an energy loading of typically 110 J-l/atm and an electron-beam current of 4 mA/sq cm. With these conditions and a pulse repetition frequency of 10 Hz for up to 10,000 shots, increases on the order of 100 ppm O2 were observed with the purifier on and 150 ppm with it off. The 1/e time recovery time was found to be approximately 75 minutes
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