Studying synthesis confinement effects on the internal structure of nanogels in computer simulations

We study the effects of droplet finite size on the structure of nanogel particles synthesized by random crosslinking of molecular polymers diluted in nanoemulsions. For this, we use a bead-spring computer model of polymer-like structures that mimics the confined random crosslinking process corresponding to irradiation- or electrochemically-induced crosslinking methods. Our results indicate that random crosslinking under strong confinement can lead to unusual nanogel internal structures, with a central region less dense than the external one, whereas under moderate confinement the resulting structure has a denser central region. We analyze the topology of the polymer networks forming nanogel particles with both types of architectures, their overall structural parameters, their response to the quality of the solvent and compare the cases of non-ionic and ionic systems

Surface relief of magnetoactive elastomeric films in a homogeneous magnetic field: Molecular dynamics simulations

The structure of a thin magnetoactive elastomeric (MAE) film adsorbed on a solid substrate is studied by molecular dynamics simulations. Within the adopted coarse-grained approach, a MAE film consists of magnetic particles modeled as soft-core spheres, carrying point dipoles, connected by elastic springs representing a polymer matrix. MAE films containing 20, 25 and 30 vol% of randomly distributed magnetic particles are simulated. Once a magnetic field is applied, the competition between dipolar, elastic and Zeeman forces leads to the restructuring of the layer. The distribution of the magnetic particles as well as elastic strains within the MAE films are calculated for various magnetic fields applied perpendicular to the film surface. It is shown that the surface roughness increases strongly with growing magnetic field. For a given magnetic field, the roughness is larger for the softer polymeric matrix and exhibits a nonmonotonic dependence on the magnetic particle concentration. The obtained results provide a better understanding of the MAE surface structuring as well as possible guidelines for fabrication of MAE films with a tunable surface topology. © The Royal Society of Chemistry 2019.Financial support of the Russian Foundation for Basic Research is gratefully acknowledged (grant no. 16-29-05276). The authors acknowledge support from the Ministry of Education and Science of the Russian Federation, Contract 02.A03.21.0006 (Project 3.1438.2017/4.6). P. A. S. and S. S. K. are also supported by the FWF START-Projekt Y 627-N27. S. S. K. also acknowledges support from ETN-COLLDENSE (H2020-MSCA-ITN-2014, Grant No. 642774). Computer simulations were carried out at the Vienna Scientific Cluster

Suspensions of magnetic nanogels at zero field: equilibrium structural properties

Magnetic nanogels represent a cutting edge of magnetic soft matter research due to their numerous potential applications. Here, using Langevin dynamics simulations, we analyse the influence of magnetic nanogel concentration and embedded magnetic particle interactions on the self-assembly of magnetic nanogels at zero field. For this, we calculated radial distribution functions and structure factors for nanogels and magnetic particles within them. We found that, in comparison to suspensions of free magnetic nanoparticles, where the self-assembly is already observed if the interparticle interaction strength exceeds the thermal fluctuations by approximately a factor of three, self-assembly of magnetic nanogels only takes place by increasing such ratio above six. This magnetic nanogel self-assembly is realised by means of favourable close contacts between magnetic nanoparticles from different nanogels. It turns out that for high values of interparticle interactions, corresponding to the formation of internal rings in isolated nanogels, in their suspensions larger magnetic particle clusters with lower elastic penalty can be formed by involving different nanogels. Finally, we show that when the self-assembly of these nanogels takes place, it has a drastic effect on the structural properties even if the volume fraction of magnetic nanoparticles is low.Comment: International Conference on Magnetic Fluids - ICMF 201

Coulomb Corrections in Photoelectron Spectra in the Adiabatic Limit

A momentum-dependent Coulomb correction to the probability of nonlinear ionization in a strong low-frequency laser field is derived analytically in the adiabatic limit, when the quasi-static tunneling model applies. Obtained formulas show that the Coulomb modification of photoelectron spectra can be significant both in linearly and circularly polarized fields. For linear polarization, it leads to a relative enhancement of the ionization probability for photoelectron energies of the order of the ponderomotive energy. This Coulomb effect is expected to be most significant for atomic species with relatively low ionization potentials, such as alkali atoms

Adiabatic-limit Coulomb factors for photoelectron and high-order-harmonic spectra

A momentum-dependent Coulomb factor in the probability for nonlinear ionization of atoms by a strong low-frequency laser field is calculated analytically in the adiabatic approximation. Expressions for this Coulomb factor, valid for an arbitrary laser pulse waveform, are obtained and analyzed in detail for the cases of linear and circular polarizations. The dependence of the Coulomb factor on the photoelectron momentum is shown to be significant in both cases. Using a similar technique, the Coulomb factor for emission of high-order harmonics by an atom in a bichromatic laser field is also calculated. In contrast to the case of a single-frequency field, for bichromatic fields the Coulomb factor depends significantly on the harmonic energy

Adiabatic-limit Coulomb factors for photoelectron and high-order-harmonic spectra

A momentum-dependent Coulomb factor in the probability for nonlinear ionization of atoms by a strong low-frequency laser field is calculated analytically in the adiabatic approximation. Expressions for this Coulomb factor, valid for an arbitrary laser pulse waveform, are obtained and analyzed in detail for the cases of linear and circular polarizations. The dependence of the Coulomb factor on the photoelectron momentum is shown to be significant in both cases. Using a similar technique, the Coulomb factor for emission of high-order harmonics by an atom in a bichromatic laser field is also calculated. In contrast to the case of a single-frequency field, for bichromatic fields the Coulomb factor depends significantly on the harmonic energy

Suspensions of magnetic nanogels at zero field: Equilibrium structural properties

Magnetic nanogels represent a cutting edge of magnetic soft matter research due to their numerous potential applications. Here, using Langevin dynamics simulations, we analyse the influence of magnetic nanogel concentration and embedded magnetic particle interactions on the self-assembly of magnetic nanogels at zero field. For this, we calculated radial distribution functions and structure factors for nanogels and magnetic particles within them. We found that, in comparison to suspensions of free magnetic nanoparticles, where the self-assembly is already observed if the interparticle interaction strength exceeds the thermal fluctuations by approximately a factor of three, self-assembly of magnetic nanogels only takes place by increasing such ratio above six. This magnetic nanogel self-assembly is realised by means of favourable close contacts between magnetic nanoparticles from different nanogels. It turns out that for high values of interparticle interactions, corresponding to the formation of internal rings in isolated nanogels, in their suspensions larger magnetic particle clusters with lower elastic penalty can be formed by involving different nanogels. Finally, we show that when the self-assembly of these nanogels takes place, it has a drastic effect on the structural properties even if the volume fraction of magnetic nanoparticles is low. © 2019 Elsevier B.V.This research has been supported by the Russian Science Foundation Grant No. 19-12-00209 . Authors acknowledge support from the Austrian Research Fund (FWF), START-Projekt Y 627-N27. Computer simulations were performed at the Vienna Scientific Cluster (VSC-3)

Longitudinal Momentum Fraction X_L for Two High P_t Protons in pp->ppX Reaction

We present an analysis of new data from Experiment E850 at BNL. We have characterized the inclusive cross section near the endpoint for pp exclusive scattering in Hydrogen and in Carbon with incident beam energy of 6 GeV. We select events with a pair of back-to-back hadrons at large transverse momentum. These cross sections are parameterized with a form $\frac{d \sigma}{d X_{L}}$ $\sim(1-X_{L})^{p}$, where ${X_{L}}$ is the ratio of the longitudinal momentum of the observed pair to the total incident beam momentum. Small value of $p$ may suggest that the number of partons participating in the reaction is large and reaction has a strong dependence on the center-of-mass energy. We also discuss nuclear effects observed in our kinematic region.Comment: 4 pages, 2 figures, to be published in Proceedings of CIPANP2000, Quebec, May 22-28, 2000, requires aipproc.sty(included

Energy Dependence of Nuclear Transparency in C(p,2p) Scattering

The transparency of carbon for (p,2p) quasi-elastic events was measured at beam energies ranging from 6 to 14.5 GeV at 90 degrees c.m. The four momentum transfer squared q*q ranged from 4.8 to 16.9 (GeV/c)**2. We present the observed energy dependence of the ratio of the carbon to hydrogen cross sections. We also apply a model for the nuclear momentum distribution of carbon to normalize this transparency ratio. We find a sharp rise in transparency as the beam energy is increased to 9 GeV and a reduction to approximately the Glauber level at higher energies.Comment: 4 pages, 2figures, submitted to PR