Knowledge Management and the Effectiveness of Innovation Outcomes: The Role of Cultural Barriers

In this paper we propose a conceptual model to test the moderating effect of cultural barriers on the link between knowledge strategies and innovation using healthcare organizations. In order to study the tie (knowledge-innovation) and the effects of the moderating variable (cultural barriers), the resource-based view is followed. It has been generally accepted that both explicit and tacit knowledge play a basic role in organizational innovation. However, there are few research works that study the relationship between knowledge management strategy and the effectiveness of the innovation process. On the other hand, the extant research on this relationship has yielded inconclusive results. Our paper revisits this research topic based on data of knowledge management strategy, Knowledge base, cultural barriers and innovation outcomes from a sample of Spanish hospitals

Ca-looping for postcombustion CO2 capture: A comparative analysis on the performances of dolomite and limestone

The low cost and wide availability of natural limestone (CaCO3) is at the basis of the industrial competitiveness of the Ca-looping (CaL) technology for postcombustion CO2 capture as already demonstrated by ~1Mwt scale pilot projects. A major focus of studies oriented towards further improving the efficiency of the CaL technology is how to prevent the gradual loss of capture capacity of limestone derived CaO as the number of carbonation/calcination cycles is increased. Natural dolomite (MgCa(CO3)2) has been proposed as an alternative sorbent precursor to limestone. Yet, carbonation of MgO is not thermodynamically favorable at CaL conditions, which may hinder the capture performance of dolomite. In the work described in this paper we carried out a thermogravimetric analysis on the multicyclic capture performance of natural dolomite under realistic regeneration conditions necessarily implying high calcination temperature, high CO2 concentration and fast transitions between the carbonation and calcination stages. Our study demonstrates that the sorbent derived from dolomite has a greater capture capacity as compared to limestone. SEM analysis shows that MgO grains in the decomposed dolomite are resistant to sintering under severe calcination conditions and segregate from CaO acting as a thermally stable support which mitigates the multicyclic loss of CaO conversion. Moreover, full decomposition of dolomite is achieved at significantly lower calcination temperatures as compared to limestone, which would help improving further the industrial competitiveness of the technology.Junta de Andalucía FQM-5735, TEP-7858, TEP-1900Ministerio de Economía y Competitividad FIS2011-25161, CTQ2011- 2762

The mOxy-CaL Process: Integration of Membrane Separation, Partial Oxy-combustion and Calcium Looping for CO2 Capture

CO2 capture and storage (CCS) is considered as a key strategy in the short to medium term to mitigate global warming. The Calcium-Looping process, based on the reversible carbonation/calcination of CaO particles, is a promising technology for post-combustion CO2 capture because of the low cost and non-toxicity of natural CaO precursors and the minor energy penalty on the power plant in comparison with amines capture based technologies (4-9 % compared to 8-12 %). Another interesting process to reduce CO2 emissions in power plants is oxy-combustion, which is based on replacing the air used for combustion by a highly concentrated (~95 % v/v) O2 stream. This work proposes a novel process (mOxy-CaL) for post-combustion CO2 capture based on the integration of membrane separation, partial oxy-combustion and the Calcium-Looping process. An oxygenenriched air stream, which is obtained from air separation by using highly permeable polymeric membranes, is used to carry out partial oxy-combustion. The flue gas exiting partial oxy-combustion shows a CO2 concentration of ~30 % v/v (higher than 15 % v/v typical in coal power plants). After that, the flue gas is passed to the CaL process where the CO2 reacts with CaO solids according to the carbonation reaction. Thermogravimetric analysis show that the multicycle CaO conversion is enhanced as the CO2 concentration in the flue gas stream is increased. Process simulations show that the mOxy-CaL process has a high CO2 capture efficiency (~95%) with lower energy consumption per kg of CO2 avoided than previously proposed post-combustion CO2 capture technologies. Moreover, the overall system size is significantly lower that state-of-the-art CaL systems, which allows for an important reduction in the capital cost of the technology

CO2 multicyclic capture of pretreated/doped CaO in the Ca-looping process. Theory and experiments

We study in this paper the conversion of CaO-based CO2 sorbents when subjected to repeated carbonation/calcination cycles with a focus on thermally pretreated/doped sorbents. Analytical equations are derived to describe the evolution of conversion with the cycle number from a unifying model based on the balance between surface area loss due to sintering in the loopingcalcination stage and surface area regeneration as a consequence of solid-state diffusion during the looping-carbonation stage. Multicyclic CaO conversion is governed by the evolution of surface area loss/regeneration that strongly depends on the initial state of the pore skeleton. In the case of thermally pretreated sorbents, the initial pore skeleton is highly sintered and regeneration is relevant whereas, for nonpretreated sorbents, the initial pore skeleton is soft and regeneration is negligible. Experimental results are obtained for sorbents subjected to a preheating controlled rate thermal analysis (CRTA) program. By applying this preheating program in a CO2 enriched atmosphere, CaO can be subjected to a rapid carbonation followed by a slow rate controlled decarbonation, which yields a highly sintered skeleton displaying a small conversion in the first cycle and self-reactivation in the next ones. Conversely, carbonation of the sorbent at a slow controlled rate enhances CO2 solid-state diffusion, which gives rise, after a quick decarbonation, to a highly porous skeleton. In this case, CaO conversion in the first cycle is very large but it decays abruptly in subsequent cycles. Data on CaO conversion retrieved from the literature and from further experimental measurements performed in our work are analyzed as influenced by a variety of experimental variables such as preheating temperature program, preheating exposition time, atmosphere composition, presence of additives, and carbonation/calcination conditions. Conversion data are well fitted by the proposed model equations, which are of help for a quantitative interpretation on the effect of experimental conditions on the multicyclic sorbent performance as a function of sintering/ regeneration parameters inferred from the fittings and allow foreseeing the critical conditions to promote reactivation. The peculiar behavior of some pretreated sorbents, showing a maximum of conversion at a small number of cycles, is explained in the light of the mode

Composition, spatial distribution and sources of macro-marine litter on the Gulf of Alicante seafloor (Spanish Mediterranean)

The composition, spatial distribution and source of marine litter in the Spanish Southeast Mediterranean were assessed. The data proceed from a marine litter retention programme implemented by commercial trawlers and were analysed by GIS. By weight, 75.9% was plastic, metal and glass. Glass and plastics were mainly found close to the coast. A high concentration of metal was observed in some isolated zones of both open and coastal waters. Fishing activity was the source of 29.16% of the macro-marine litter, almost 68.1% of the plastics, and 25.1% of the metal. The source of the other 60.84% could not be directly identified, revealing the high degree of uncertainty regarding its specific origin. Indirectly however, a qualitative analysis of marine traffic shows that the likely sources were merchant ships mainly in open waters and recreational and fishing vessels in coastal waters.We are grateful for the support of the PESCAL Project by European funds through General Secretary of Fisheries of Spain, led by CETMAR with the participation of the Joint Research Unit between the Spanish Oceanography Institute (IEO) and the University of Alicante (UA). Santiago García-Rivera was supported by PESCAL Project and a PhD grant from the University of Alicante

Recent tectonic effects in the Campo de Calatrava deduced from the paleomagnetic data of the neogene volcanism

The Campo de Calatrava region shows some effects of the recent tectonics related to origin of the Betic orogen. Some of the effect recognizable at Campo de Calatrava was: vertical blocks movements leading to depressions where neogene sediments began to deposit giving rise to the tertiary basins located in the center of the Ciudad Real province. The neotectonic also has influenced in the distribution of the volcanism, which appears aligned with the main structures activity. The analysis of the variations of the magnetic declination of some of existing volcanoes allows detect the block rotations over vertical axis. Nevertheless the results show that the declination values do not prove that there has been a generalized rotation of all the are

La influencia de la cultura organizativa en el rendimiento de los programas de Gestión de la Calidad Total

This paper aims to examine the relationships between different types of cultures and effectiveness in Total Quality Management (TQM) implementation. Using Cameron’s framework, we have tested the connection between a quality culture taxonomy and TQM programme performance using data from a survey carried out with 113 Spanish companies that have implemented TQM systems. A structural equation modelling is proposed to assess the links between both types of constructs using the Partial Least Squares (PLS) technique. The most substantial results confirm, in the sample analysed, the relationship between quality culture types and the TQM programme performance, and there being different influence levels of the quality cultures.Este artículo examina las relaciones entre los diferentes tipos de cultura y la efectividad en la implantación de la Gestión de la Calidad Total (GCT). Utilizando el modelo de Cameron, hemos testado la relación entre una taxonomía de culturas de calidad y el rendimiento de un programa de GCT en una muestra de 113 empresas espanolas ˜ que tienen implantados sistemas GCT. Se propone un modelo de ecuaciones estructurales para evaluar las relaciones entre ambos tipos de constructos utilizando para ello la técnica Partial Least Squares (PLS). Los resultados en la muestra utilizada confirman las relaciones entre los tipos de culturas de calidad y el rendimiento de los programas GCT, así como la existencia de diferentes niveles de influencia de estas culturas de calidad

The Calcium-Looping (CaCO3/CaO) Process for Thermochemical Energy Storage in Concentrating Solar Power Plants

Articulo aceptado por la revista. * No publicado aún [28-06-2019]Energy storage based on thermochemical systems is gaining momentum as potential alternative to molten salts in Concentrating Solar Power (CSP) plants. This work is a detailed review about the promising integration of a CaCO3/CaO based system, the so-called Calcium-Looping (CaL) process, in CSP plants with tower technology. The CaL process relies on low cost, widely available and non-toxic natural materials (such as limestone or dolomite), which are necessary conditions for the commercial expansion of any energy storage technology at large scale. A comprehensive analysis of the advantages and challenges to be faced for the process to reach a commercial scale is carried out. The review includes a deep overview of reaction mechanisms and process integration schemes proposed in the recent literature. Enhancing the multicycle CaO conversion is a major challenge of the CaL process. Many lab-scale analyses carried out show that residual effective CaO conversion is highly dependent on the process conditions and CaO precursors used, reaching values as different as 0.07-0.82. The selection of the optimal operating conditions must be based on materials, process integration, technology and economics aspects. Global plant efficiencies over 45% (without considering solar-side losses) show the interest of the technology. Furthermore, the technological maturity and potential of the process is assessed. The direction towards which future works should be headed is discussed.Ministerio de Economia y Competitividad CTQ2014-52763-C2, CTQ2017- 83602-C2 (-1-R and -2-R)Unión Europea Horizon 2020 Grant agreement No 727348, project SOCRATCES

Coal purchase optimization: a review from Spain

The study addresses the need to manage the risk of the purchase price of coal in a power company by changing the management model of the purchasing department. It eliminates the risk of price reduces the cost of buying coal and optimizing the performance of all electricity generation plants belonging to the company. You get more flexibility and optionallity to gain additional benefits both economic and efficiency in the supply to our generation fleet. The tools to achieve the above purpose will be financial derivatives that will be used as elements of management and not as mere speculation in the markets

Active Q-switched distributed feedback erbium-doped fiber lasers

This letter presents a distributed feedback fiber laser that operates in an actively controlled Q-switched regime. The laser is based on a Bragg grating made in an erbium-doped fiber. The grating has a defect induced by a magnetostrictive transducer that configures the distributed feedback laser structure. The phase shift generated by the defect can be dynamically modified by an electric current, permitting active Q-switching of the laser. The laser generates pulses of 75 ns duration and the repetition rate can be continuously adjusted from 0 to 10 kHz