Global land use implications of biofuels: State of the art conference and workshop on modelling global land use implications in the environmental assessment of biofuels

Background, Aims and Scope On 4¿5 June 2007, an international conference was held in Copenhagen. It provided an interdisciplinary forum where economists and geographers met with LCA experts to discuss the challenges of modelling the ultimate land use changes caused by an increased demand for biofuels. Main Features The main feature of the conference was the cross-breeding of experience from the different approaches to land use modelling: The field of LCA could especially benefit from economic modelling in the identification of marginal crop production and the resulting expansion of the global agricultural area. Furthermore, the field of geography offers insights in the complexity behind new land cultivation and practical examples of where this is seen to occur on a regional scale. Results Results presented at the conference showed that the magnitude and location of land use changes caused by biofuels demand depend on where the demand arises. For instance, mandatory blending in the EU will increase land use both within and outside of Europe, especially in South America. A key learning for the LCA society was that the response to a change in demand for a given crop is not presented by a single crop supplier or a single country, but rather by responses from a variety of suppliers of several different crops in several countries. Discussion The intensification potential of current and future crop and biomass production was widely discussed. It was generally agreed that some parts of the third world hold large potentials for intensification, which are not realised due to a number of barriers resulting in so-called yield gaps. Conclusions Modelling the global land use implications of biofuels requires an interdisciplinary approach optimally integrating economic, geographical, biophysical, social and possibly other aspects in the modelling. This interdisciplinary approach is necessary but also difficult due to different perspectives and mindsets in the different disciplines. Recommendations and Perspectives The concept of a location dependent marginal land use composite should be introduced in LCA of biofuels and it should be acknowledged that the typical LCA assumption of linear substitution is not necessarily valid. Moreover, fertiliser restrictions/accessibility should be included in land use modelling and the relation between crop demand and intensification should be further explored. In addition, environmental impacts of land use intensification should be included in LCA, the powerful concept of land use curves should be further improved, and so should the modelling of diminishing returns in crop production

Wannier functions and exchange integrals: The example of LiCu2_{2}O2_{2}

Starting from a single band Hubbard model in the Wannier function basis, we revisit the problem of the ligand contribution to exchange and derive explicit formulae for the exchange integrals in metal oxide compounds in terms of atomic parameters that can be calculated with constrained LDA and LDA+U. The analysis is applied to the investigation of the isotropic exchange interactions of LiCu$_{2}$O$_{2}$, a compound where the Cu-O-Cu angle of the dominant exchange path is close to 90$^{\circ}$. Our results show that the magnetic moments are localized in Wannier orbitals which have strong contribution from oxygen atomic orbitals, leading to exchange integrals that considerably differ from the estimates based on kinetic exchange only. Using LSDA+U approach, we also perform a direct {\it ab-initio} determination of the exchange integrals LiCu$_{2}$O$_{2}$. The results agree well with those obtained from the Wannier function approach, a clear indication that this modelization captures the essential physics of exchange. A comparison with experimental results is also included, with the conclusion that a very precise determination of the Wannier function is crucial to reach quantitative estimates.Comment: 8 pages, 8 figure

A 2D quantum antiferromagnet with a four-fold degenerate valence-bond-solid ground state

We study the competition between antiferromagnetic order and valence bond solid formation in a two-dimensional frustrated spin-1/2 model. The J1-J2 model on the square lattice is further frustrated by introducing products of three-spin projectors which stabilize four dimer-product states as degenerate ground states. These four states are reminiscent of the dimerized singlet ground state of the Shastry-Sutherland model. Using exact diagonalizations, we study the evolution of the ground state by varying theratio of interactions. For a large range of parameters (J2 > 0.25J1), our model shows a direct transition between the valence-bond-solid phase and the collinear antiferromagnetic phase. For small values of J2, several intermediate phases appear which are also analyzed

Ferromagnetically coupled dimers on the distorted Shastry-Sutherland lattice: Application to (CuCl)LaNb2O7

A recent study [Tassel {\it et al.}, Phys. Rev. Lett. {\bf 105}, 167205 (2010)] has proposed a remarkable spin model for (CuCl)LaNb2O7, in which dimers are ferromagnetically coupled to each other on the distorted Shastry-Sutherland lattice. In this model, the intra-dimer exchange coupling J>0 is antiferromagnetic, while the inter-dimer exchange couplings are ferromagnetic and take different values, J_x,J_y<0, in the two bond directions. Anticipating that the highly frustrated character of this model may lead to a wide range of behaviors in (CuCl)LaNb2O7 and related compounds, we theoretically investigate the ground state phase diagram of this model in detail using the following three approaches: a strong-coupling expansion for small J_x and J_y, exact diagonalization for finite clusters, and a Schwinger boson mean field theory. When |J_x|, |J_y| <~ J, the system stays in a dimer singlet phase with a finite spin gap. This state is adiabatically connected to the decoupled-dimer limit J_x=J_y=0. We show that the magnetization process of this phase depends crucially on the spatial anisotropy of the inter-dimer couplings. The magnetization shows a jump or a smooth increase for weak and strong anisotropy, respectively, after the spin gap closes at a certain magnetic field. When |J_x| or |J_y| >~ J, quantum phase transitions to various magnetically ordered phases (ferromagnetic, collinear stripe, and spiral) occur. The Schwinger boson analysis demonstrates that quantum fluctuations split the classical degeneracy of different spiral ground states. Implications for (CuCl)LaNb2O7 and related compounds are discussed in light of our theoretical results and existing experimental data.Comment: 21 pages, 20 figure

Unusual magnetic properties of the low-dimensional quantum magnet Na2V3O7

We report the results of low-temperature measurements of the specific heat Cp(T), ac susceptibility chi(T) and 23Na nuclear magnetic resonance NMR of Na2V3O7. At liquid He temperatures Cp(T)/T exhibits broad field-dependent maxima, which shift to higher temperatures upon increasing the applied magnetic field H. Below 1.5 K the ac magnetic susceptibility chi(T) follows a Curie-Weiss law and exhibits a cusp at 0.086 mK which indicates a phase transition at very low temperatures. These results support the previous conjecture that Na2V3O7 is close to a quantum critical point (QCP) at mu_{0}H = 0 T. The entire data set, including results of measurements of the NMR spin-lattice relaxation 1/T1(T), reveals a complex magnetic behavior at low temperatures. We argue that it is due to a distribution of singlet-triplet energy gaps of dimerized V moments. The dimerization process evolves over a rather broad temperature range around and below 100 K. At the lowest temperatures the magnetic properties are dominated by the response of only a minor fraction of the V moments.Comment: 10.5 pages, 15 figures. Submitted to Phys. Rev.

Thermal critical points from competing singlet formations in fully frustrated bilayer antiferromagnets

We examine the ground-state phase diagram and thermal phase transitions in a plaquettized fully frustrated bilayer spin-1/2 Heisenberg model. Based on a combined analysis from sign-problem free quantum Monte Carlo simulations, perturbation theory, and free-energy arguments, we identify a first-order quantum phase transition line that separates two competing quantum-disordered ground states with dominant singlet formations on interlayer dimers and plaquettes, respectively. At finite temperatures, this line extends to form a wall of first-order thermal transitions, which terminates in a line of thermal critical points. From a perturbative approach in terms of an effective Ising model description, we identify a quadratic suppression of the critical temperature scale in the strongly plaquettized region. Based on free-energy arguments we furthermore obtain the full phase boundary of the low-temperature dimer-singlet regime, which agrees well with the quantum Monte Carlo data

Bridging the Gap in Physics Education

Over the past few years there has been a growing interest in the possible benefits of computer simulations in physics education. However, very little research has been conducted on how computer simulations can actually be integrated into a physics program (Zacharia & Anderson, 2003). This research investigated the effects of computer simulations on the development of accurate mental models when used in conjunction with traditional laboratory-based experiments. Since laboratory experiments can often have results that are very difficult to observe, these results only become evident to the trained eye of an expert. Computer simulations are able to present phenomena free of the normal distractions that occur during traditional laboratory-based experiments. Through the analysis of post-tests, questionnaires, and student interviews conducted in a high school physics class, it was shown that when computer simulations are used in conjunction with traditional laboratory activities students appear to make accurate revisions to their naive mental models of motion. The results also indicate that the majority of the students believe that the computer simulations assisted in the clarification of the laboratory results and allowed them to more fully understand the theoretical concepts being presented in the laboratory investigation

Hubungan antara Layanan Informasi Karir dengan Pemahaman Karir Peserta Didik Kelas XI SMA

This research aims to find out more in depth about the relationship between career information services with the understanding of career learners. The method used is descriptive method with quantitative approach, namely problem-solving procedure by describing the relationship of career information service with career understanding by means of statistics and described descriptively. The sample of this study amounted to 57 students of class XI. Data collection techniques used are indirect communication techniques and documentary/bibliographic study techniques. The data collection tools used were questionnaires and student documents. Data analysis technique used to answer sub problem one and two is percentage, while to answer sub problem three using product moment correlation. The result of data analysis shows that career information service on class XI students reach 73,39%. The achievement is in the good range. Meanwhile, the understanding of career of class XI students reached 78.01% which is in the good range. The result of product moment correlation of both variables is obtained rhitung = 0.387 which means show that there is a positive correlation between career information service with understanding of career of class XI student of State Senior High School 4 Pontianak