Absence of Metastable States in Strained Monatomic Cubic Crystals

A tetragonal (Bain path) distortion of a metal with an fcc (bcc) ground state will initially cause an increase in energy, but at some point along the Bain path the energy will again decrease until a local minimum is reached. Using a combination of parametrized tight-binding and first-principles LAPW calculations we show that this local minimum is unstable with respect to an elastic distortion, except in the rare case that the minimum is at the bcc (fcc) point on the Bain path. This shows that body-centered tetragonal phases of these materials, which have been seen in epitaxially grown thin films, must be stabilized by the substrate and cannot be free-standing films.Comment: 7 pages, 5 postscript figures, REVTEX, submitted to Phys. Rev.

Precise Tight-binding Description of the Band Structure of MgB2

We present a careful recasting of first-principles band structure calculations for MgB2 in a non-orthogonal sp-tight-binding (TB) basis. Our TB results almost exactly reproduce our full potential linearized augmented plane wave results for the energy bands, the densities of states and the total energies. Our procedure generates transferable Slater-Koster parameters which should be useful for other studies of this important material.Comment: REVTEX, 2 Encapsulated PostScript Figure

Introducing zanadio: A digitalized, multimodal program to treat obesity

While the prevalence of overweight and obesity has been increasing annually, the accessibility of on-site treatment programs is not rising correspondingly. Digital, evidence-based obesity treatment programs could potentially alleviate this situation. The application zanadio has been developed to enable patients with obesity (BMI 30-45 kg/m2) to participate in a digital, multimodal weight reduction program based on current treatment guidelines. This article is divided into two parts: (I) it introduces zanadio, its aims and therapeutic concept, and (II) provides a first impression and demographic data on more than 11,000 patients from across the country who have used zanadio within the last 16 months, which demonstrates the demand for a digital obesity treatment. zanadio has the potential to partially close the current gap in obesity care. Future work should focus on identifying predictors of successful weight loss to further individualize digital obesity treatment, and an important next step would be to prevent obesity, i.e., to start the treatment at lower BMI levels, and to invent digital treatment programs for children and adolescents

Long-Distance Wind-Dispersal of Spores in a Fungal Plant Pathogen: Estimation of Anisotropic Dispersal Kernels from an Extensive Field Experiment

Given its biological significance, determining the dispersal kernel (i.e., the distribution of dispersal distances) of spore-producing pathogens is essential. Here, we report two field experiments designed to measure disease gradients caused by sexually- and asexually-produced spores of the wind-dispersed banana plant fungus Mycosphaerella fijiensis. Gradients were measured during a single generation and over 272 traps installed up to 1000 m along eight directions radiating from a traceable source of inoculum composed of fungicide-resistant strains. We adjusted several kernels differing in the shape of their tail and tested for two types of anisotropy. Contrasting dispersal kernels were observed between the two types of spores. For sexual spores (ascospores), we characterized both a steep gradient in the first few metres in all directions and rare long-distance dispersal (LDD) events up to 1000 m from the source in two directions. A heavy-tailed kernel best fitted the disease gradient. Although ascospores distributed evenly in all directions, average dispersal distance was greater in two different directions without obvious correlation with wind patterns. For asexual spores (conidia), few dispersal events occurred outside of the source plot. A gradient up to 12.5 m from the source was observed in one direction only. Accordingly, a thin-tailed kernel best fitted the disease gradient, and anisotropy in both density and distance was correlated with averaged daily wind gust. We discuss the validity of our results as well as their implications in terms of disease diffusion and management strategy

An Analysis of Community-Based Values Informing Land Management on the Midwestern Prairie Band Potawatomi Nation of Kansas, USA

The focus of this study is to examine the interface between land management practices and values within a tribal community in rural midwestern North America. The Prairie Band Potawatomi Nation (PBPN) reside on a tribal reservation with a checkerboard distribution amongst private, non-tribal landowners. Previous studies have indicated that landowners may have different value-systems leading to variations in land-management practices. This can impose discontinuous land management in areas within shared biological boundaries, such as watersheds, especially between tribal and non-tribal entities. Preliminary spatial analysis in and around the PBPN landscape determined that the tribally-managed lands present more vegetative cover per unit land tenure than non-tribal lands. Furthermore, tribally-managed lands have more miles of intact riparian buffers present along streambanks compared to non-tribal streambanks. These factors indicate a difference in management approaches between both groups, yet the values that drive these management approaches have not been examined. To better understand PBPN land-management approaches, we coded and analyzed surveys conducted with tribal members about stream use, management, and values (n=76). Furthermore, we coded and analyzed every issue of the community newsletter Rez Recycler published within 2008-2014 for values-based themes. Our analysis demonstrated the PBPN community prioritize native land cover and ecosystem services for community benefit. Primary themes include stream condition, fish and fishing, culture and community, riparian knowledge, restoration and education. Additionally, healthy streams and healthy aquatic populations were most valued. This demonstrates tribal awareness and prioritization of the connection between land management and stream conditions. We have presented an examination of community values, and desired outcomes, in a way that can help multiple stakeholders (e.g. Federal, state, private and tribal) approach land management. This type of understanding can facilitate collaborative planning that allows the tribal community to define their own version of success and support self-determination and sovereignty

Molecular Hydrogen Formation on Low Temperature Surfaces in Temperature Programmed Desorption Experiments

The study of the formation of molecular hydrogen on low temperature surfaces is of interest both because it allows to explore elementary steps in the heterogeneous catalysis of a simple molecule and because of the applications in astrochemistry. Here we report results of experiments of molecular hydrogen formation on amorphous silicate surfaces using temperature-programmed desorption (TPD). In these experiments beams of H and D atoms are irradiated on the surface of an amorphous silicate sample. The desorption rate of HD molecules is monitored using a mass spectrometer during a subsequent TPD run. The results are analyzed using rate equations and the activation energies of the processes leading to molecular hydrogen formation are obtained from the TPD data. We show that a model based on a single isotope provides the correct results for the activation energies for diffusion and desorption of H atoms. These results can thus be used to evaluate the formation rate of H_2 on dust grains under the actual conditions present in interstellar clouds.Comment: 30 pages, 1 table, 6 figures. Published versio