We present a careful recasting of first-principles band structure
calculations for MgB2 in a non-orthogonal sp-tight-binding (TB) basis. Our TB
results almost exactly reproduce our full potential linearized augmented plane
wave results for the energy bands, the densities of states and the total
energies. Our procedure generates transferable Slater-Koster parameters which
should be useful for other studies of this important material.Comment: REVTEX, 2 Encapsulated PostScript Figure