FBR for Polyolefin Production in Gas Phase: Validation of a Two-phase Compartmentalized Model by Comparison with CFD

Two different modeling approaches are applied in this work to the simulation of fluidized bed reactors containing solid particles of Geldart A-B type and operated at conditions typically used for polyolefins production. On one side, a fully detailed computational fluid dynamics (CFD) model is developed, considering a 2D planar geometry and a multi-fluid description with kinetic theory of granular flows. On the other, a conventional three-phase, 1D compartmentalized model (SCM) is also developed, implementing the fluid dynamic description based on popular, semi-empirical relationships available in the literature. Given the huge difference of computational effort associated with the corresponding numerical solutions, our aim is to confirm the reliability of the simplified model by comparison with the results of the detailed CFD model. The comparison is carried out considering the fluidization of a bed of solid particles without reaction and solid injection or withdrawal, thus focusing on the steady-state fluid dynamic behavior of the expanded bed. Three different gas velocities and different monodisperse and polydisperse particle populations are analyzed. The results show that the oversimplified compartmentalized approach is capable to predict the solid mixing features established inside the reactor operated in bubbling fluidization regime with good reliability for non-reactive polyethylene particles. Average solid volume fractions are particularly close to the values predicted by the CFD model when monodisperse particles are considered inside the examined range of gas velocity values. A generally good agreement is also found when solids with broad size distribution are analyzed. Overall, these comparisons provide a meaningful validation of the simplified compartmentalized models: given their negligible computational demand and general versatility (complex kinetic schemes and single particle models are easily accounted for), they still represent an effective tool of industrial process design

Comparison between detailed (CFD) and simplified models for the prediction of solid particle size distribution in fluidized bed reactors

This work is aimed at developing a simplified model suitable to effectively describe the fluidization behavior within fluidized beds with minimal computational efforts. The simplified model was validated through detailed CFD Euler-Euler simulations showing a good agreement in the case of large particles (about 450 micron) at all the gas velocities considered (20, 40, 61 cm/s). Slightly less accurate outcomes were observed for smaller particles (about 220 micron). This was due to the underestimation of the particle size effect on the fluidization behavior by the simplified approach

A novel uncoupled quasi-3D Euler-Euler model to study the spiral jet mill micronization of pharmaceutical substances at process scale: model development and validation

In this work we present a novel approach to model the micronization of pharmaceutical ingredients at process scales and times. 3D single-phase fluid-dynamics simulations are used to compute the gas velocity field within a spiral jet mill which are provided as input in a 1D compartmentalized model to calculate solid velocities along the radial direction. The particles size reduction is taken into account through a breakage kernel that is function of gas energy and local solid holdup. Simulation results are validated against micronization experiments for lactose and paracetamol, comparing the model predictions with D10, D50 and D90 diameters values coming from Design of Experiments isosurfaces. The developed model allows for a fair estimation of the outlet particle size distribution in a short computational time, with very good predictions especially for D90 values

Effectiveness of cardiac resynchronization therapy in heart failure patients with valvular heart disease: comparison with patients affected by ischaemic heart disease or dilated cardiomyopathy. The InSync/InSync ICD Italian Registry

AimsTo analyse the effectiveness of cardiac resynchronization therapy (CRT) in patients with valvular heart disease (a subset not specifically investigated in randomized controlled trials) in comparison with ischaemic heart disease or dilated cardiomyopathy patients.Methods and resultsPatients enrolled in a national registry were evaluated during a median follow-up of 16 months after CRT implant. Patients with valvular heart disease treated with CRT (n = 108) in comparison with ischaemic heart disease (n = 737) and dilated cardiomyopathy (n = 635) patients presented: (i) a higher prevalence of chronic atrial fibrillation, with atrioventricular node ablation performed in around half of the cases; (ii) a similar clinical and echocardiographic profile at baseline; (iii) a similar improvement of LVEF and a similar reduction in ventricular volumes at 6-12 months; (iv) a favourable clinical response at 12 months with an improvement of the clinical composite score similar to that occurring in patients with dilated cardiomyopathy and more pronounced than that observed in patients with ischaemic heart disease; (v) a long-term outcome, in term of freedom from death or heart transplantation, similar to patients affected by ischaemic heart disease and basically more severe than that of patients affected by dilated cardiomyopathy.ConclusionIn 'real world' clinical practice, CRT appears to be effective also in patients with valvular heart disease. However, in this group of patients the outcome after CRT does not precisely overlap any of the two other groups of patients, for which much more data are currently available

Expansion cone for the 3-inch PMTs of the KM3NeT optical modules

[EN] Detection of high-energy neutrinos from distant astrophysical sources will open a new window on the Universe. The detection principle exploits the measurement of Cherenkov light emitted by charged particles resulting from neutrino interactions in the matter containing the telescope. A novel multi-PMT digital optical module (DOM) was developed to contain 31 3-inch photomultiplier tubes (PMTs). In order to maximize the detector sensitivity, each PMT will be surrounded by an expansion cone which collects photons that would otherwise miss the photocathode. Results for various angles of incidence with respect to the PMT surface indicate an increase in collection efficiency by 30% on average for angles up to 45 degrees with respect to the perpendicular. Ray-tracing calculations could reproduce the measurements, allowing to estimate an increase in the overall photocathode sensitivity, integrated over all angles of incidence, by 27% (for a single PMT). Prototype DOMs, being built by the KM3NeT consortium, will be equipped with these expansion cones.This work is supported through the EU, FP6 Contract no. 011937, FP7 grant agreement no. 212252, and the Dutch Ministry of Education, Culture and Science.Adrián Martínez, S.; Ageron, M.; Aguilar, JA.; Aharonian, F.; Aiello, S.; Albert, A.; Alexandri, M.... (2013). Expansion cone for the 3-inch PMTs of the KM3NeT optical modules. Journal of Instrumentation. 8(3):1-19. https://doi.org/10.1088/1748-0221/8/03/T03006S1198

High temperature rock-bed TES system suitable for industrial-scale CSP plant - CFD analysis under charge/discharge cyclic conditions

The present study aims at dimensioning and modeling, by means of accurate time-dependent 3D computational fluid dynamics simulations, the behavior of a high temperature rock-bed TES system. The latter is exploited to fulfill the round-the-clock energy requirements of a reference 80 MWe industrial-scale CSP plant, based upon the Airlight Energy technology, which uses air as heat transfer fluid. The TES system behavior was analyzed through 15 consecutive charge/discharge cycles to evaluate the thickness evolution of the thermocline zone, and hence the overall thermal efficiency of the system, under cyclic conditions. The numerical model was satisfactorily validated with experimental data, gathered from a 6.5 MWhth TES system prototype, located in Biasca, designed and built by the Swiss company Airlight Energy SA. The good agreement between CFD simulations results and experimental data allowed the authors to assess the relevance of radiative heat transfer, even at relatively low temperature (300 ÷ 350 °C), on the thermodynamics behavior of the TES system. Moreover, a porosity variation, with the packed bed depth, was also observed numerically and experimentally mainly due to the own weight of the packings (25m3 of natural river pebbles with 3 cm average diameter). The CFD simulations were performed with Fluent code from ANSYS.ISSN:1876-610

Towards a Commercial Parabolic Trough CSP System Using Air as Heat Transfer Fluid

We report on major design innovations related to the trough concentrator, solar receiver, and thermal storage of a parabolic trough CSP system. A 9.7 m aperture parabolic trough mirror is formed by inflated, metallized, polymeric films mounted on a rigid and durable concrete support structure. The novel receiver design, which uses air as the heat transfer fluid at ambient pressure, is based on an array of absorber cavities coupled to secondary concentrating optics for operating temperatures exceeding 600 °C. The solar-heated air is directly fed to a thermal energy storage unit based on a packed bed of rocks to guarantee round-the-clock dispatchability of high-temperature heat to the power block. A commercial CSP plant with a projected peak thermal power output of 3.9 MWth is currently under construction in Ait Baha, Morocco.ISSN:1876-610

ScienceDirect-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). Peer review by the scientific conference committee of SolarPACES 2014 under responsibility of PSE AG Single-tank TES system -Transient evaluation of thermal stratification ac

Abstract Single-tank thermal energy storage (TES) systems represent a valuable alternative, to the most common two-tank systems with molten slat, to effectively store thermal energy in concentrating solar power (CSP) applications. From an economic standpoint, the gap between the two TES solutions is relevant. A remarkable cost reduction can be achieved if a single-tank TES system, with a low-cost filler material, is exploited. In this kind of TES system, the buoyancy driven effects of the heat transfer fluid are exploited to establish and maintain a thermocline zone which separates the hot region on top and the cold region at the bottom of the tank. The thinner the thermocline thickness, the higher the thermodynamic quality of the stored energy. As soon as the TES is charged for the first time, i.e. startup of the system, the extent of thermal stratification may vary sharply during the first cycles before achieving a stable condition. For this reason, this study aims at evaluating, by means of accurate time-dependent 3D CFD simulations, the transient evolution of thermal stratification of a single-tank TES system exploited to fulfill the round-the-clock energy requirement of a reference 80 MW e CSP plant which uses air as heat transfer fluid. A total of 30 consecutive cycles, composed by charge/discharge phases, were simulated. Since the thermal energy stored is exploited to produce electrical energy, the performances of the TES system, operating under cyclic conditions, were qualitatively characterized by means of a stratification efficiency index based upon the second-law of thermodynamics

Design optimization of a novel receiving cavity for Concentrated Solar Power applications by means of 3D CFD simulations

The aim of this work was the design optimization, by means of accurate steady state 3D CFD simulations, of a novel receiving cavity for Concentrated Solar Power (CSP) applications. The receiving cavity has been developed by Airlight Energy Manufacturing SA in collaboration with ETH Zurich and SUPSI-DTI-ICIMSIwithin the framework of the SolAir-2 project. It is made of a helically coiled steel tube, and resulted highly effective in converting the radiative energy coming from the sun into thermal energy gathered by air which was selected as heat transfer fluid (HTF) being cheap, environmentally friendly and suitable for high temperatures applications. The main geometrical parameters considered for the optimization were: cavity height, varied by increasing or decreasing the number of coils, cavity external diameter, and the presence of a spiral coiled tube closing the cavity top. For each configuration the air flow rate, with an inlet temperature of 120 °C, was tuned in order to reach an outlet temperature close to the target value of 650 °C. Cavity performance were evaluated in terms of thermal efficiency and pressure drop under two different skew angle conditions for the incoming solar radiation, 18° and 40°. CFD simulations were performed with Ansys Fluent. Navier-Stokes and energy equations were numerically solved using the finite-volume method approach; radiation heat transfer inside the cavity was taken into account by means of the Discrete Ordinates (DO) radiation model.ISSN:1876-610