7 research outputs found
Low temperature synthesis of ionic phosphates in dimethyl sulfoxide
A new synthesis route for phosphates in an organic solvent at low temperatures is presented. The synthesis was done by dispersing a nitrate salt and phosphorus pentoxide in dimethyl sulfoxide. The synthesis can be performed under water-free conditions and yielded several organic and inorganic phosphates. Crystal structure solution of bistetramethylammonium hydrogencyclotriphosphate, N(CH3)(4)](2)HP3O9, was achieved by combining information gained from powder X- ray diffraction, liquid NMR and solid state (2D) NMR. The molecular structure of rubidium cyclotetraphosphate, Rb4P4O12, was determined using liquid state NMR and solid state (2D) NMR spectroscopy
Synthesis and characterization of methylammonium phosphates as crystalline approximants for anhydrous, low melting phosphate glasses
Finanziert aus dem DFG-geförderten Open-Access-Publikationsfonds der Universität Siegen für ZeitschriftenartikelLow-melting methylammonium phosphate glasses are synthesized from crystalline starting agents. To this end crystalline tris(methylammonium) cyclotriphosphate [CH3NH3]3P3O9, was synthesized by a novel and simple synthesis route from P4O10 and N-methylformamide. It, undergoes an irreversible phase transition to methylammonium catena-polyphosphate [CH3NH3]PO3. The crystal structure of the catena-polyphosphate was solved and refined from X-ray powder diffraction data by the Rietveld method using constraints obtained by solid-state 31P and 1H NMR spectroscopy. This compound crystallizes in a triclinic space group with a = 13.2236(9), b = 7.8924(6), c = 4.6553(2) Å, α = 91.068(4), β = 87.840(5) and γ = 106.550(3)°. Quantum chemical calculations confirm that the obtained structure lies at an energetic minimum. Finally the reaction of tris(methylammonium) cyclotriphosphate and P4O10 into methylammonium phosphate glass is presented. The synthesized, water-free phosphate glass shows a very low glass transition temperature Tg of 33 °C, which was verified by dynamic scanning calorimetry and NMR. The chain-like crystal structure of the high-temperature methylammoniumphosphate [CH3NH3]PO3 serves as an approximation for the short-range order of the glass
Low temperature synthesis of ionic phosphates in dimethyl sulfoxide
A new synthesis route for phosphates in an organic solvent at low temperatures is presented. The synthesis was done by dispersing a nitrate salt and phosphorus pentoxide in dimethyl sulfoxide. The synthesis can be performed under water-free conditions and yielded several organic and inorganic phosphates. Crystal structure solution of bistetramethylammonium hydrogencyclotriphosphate, N(CH3)(4)](2)HP3O9, was achieved by combining information gained from powder X- ray diffraction, liquid NMR and solid state (2D) NMR. The molecular structure of rubidium cyclotetraphosphate, Rb4P4O12, was determined using liquid state NMR and solid state (2D) NMR spectroscopy
Linking <sup>31</sup>P Magnetic Shielding Tensors to Crystal Structures: Experimental and Theoretical Studies on Metal(II) Aminotris(methylenephosphonates)
The <sup>31</sup>P chemical shift tensor of the phosphonate
group
[RC-PO<sub>2</sub>(OH)]<sup>−</sup> is investigated with respect
to its principal axis values and its orientation in a local coordinate
system (LCS) defined from the P atom and the directly coordinated
atoms. For this purpose, six crystalline metal aminotris(methylenephosphonates), <i>M</i>AMP·<i>x</i>H<sub>2</sub>O with <i>M</i> = Zn, Mg, Ca, Sr, Ba, and (2Na) and <i>x</i> = 3, 3, 4.5, 0, 0, and 1.5, respectively, were synthesized and identified
by diffraction methods. The crystal structure of water-free BaAMP
is described here for the first time. The principal components of
the <sup>31</sup>P shift tensor were determined from powders by magic-angle-spinning
NMR. Peak assignments and orientations of the chemical shift tensors
were established by quantum-chemical calculations from first principles
using the extended embedded ion method. Structure optimizations of
the H-atom positions were necessary to obtain the chemical shift tensors
reliably. We show that the <sup>31</sup>P tensor orientation can be
predicted within certain error limits from a well-chosen LCS, which
reflects the pseudosymmetry of the phosphonate environment