160 research outputs found

    Luminescent Complexes of Europium (III) with 2-(Phenylethynyl)-1,10-phenanthroline: The Role of the Counterions

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    New antenna ligand, 2-(phenylethynyl)-1,10-phenanthroline (PEP), and its luminescent Eu (III) complexes, Eu(PEP)2Cl3 and Eu(PEP)2 (NO3 )3 , are synthesized and characterized. The synthetic procedure applied is based on reacting of europium salts with ligand in hot acetonitrile solutions in molar ratio 1 to 2. The structure of the complexes is refined by X-ray diffraction based on the single crystals obtained. The compounds [Eu(PEP)2Cl3 ]·2CH3CN and [Eu(PEP)2 (NO3 )3 ]·2CH3CN crystal ize in monoclinic space group P21/n and P21/c, respectively, with two acetonitrile solvent molecules. Intra- and inter-ligand π-π stacking interactions are present in solid stat and are realized between the phenanthroline moieties, as well as between the substituents and the phenanthroline units. The optical properties of the complexes are investigated in solid state, acetonitrile and dichloromethane solution. Both compounds exhibit bright red luminescence caused by the organic ligand acting as antenna for sensitization of Eu (III) emission. The newly designed complexes differ in counter ions in the inner coordination sphere, which allows exploring their influence on the stability, molecular and supramolecular structure, fluorescent properties and symmetry of the Eu (III) ion. In addition, molecular simulations are performed in order to explain the observed experimental behavior of the complexes. The discovered structure-properties relationships give insight on the role of the counter ions in the molecular design of new Eu (III) based luminescent materials

    Spiky strings and single trace operators in gauge theories

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    We consider single trace operators of the form O_{m_1 ... m_n} = tr D_+^{m_1} F ... D_+^{m_n} F which are common to all gauge theories. We argue that, when all m_i are equal and large, they have a dual description as strings with cusps, or spikes, one for each field F. In the case of N=4 SYM, we compute the energy as a function of angular momentum by finding the corresponding solutions in AdS_5 and compare with a 1-loop calculation of the anomalous dimension. As in the case of two spikes (twist two operators), there is agreement in the functional form but not in the coupling constant dependence. After that, we analyze the system in more detail and find an effective classical mechanics describing the motion of the spikes. In the appropriate limit, it is the same (up to the coupling constant dependence) as the coherent state description of linear combinations of the operators O_{m_1 ... m_n} such that all m_i are equal on average. This agreement provides a map between the operators in the boundary and the position of the spikes in the bulk. We further suggest that moving the spikes in other directions should describe operators with derivatives other than D_+ indicating that these ideas are quite generic and should help in unraveling the string description of the large-N limit of gauge theories.Comment: 23 pages, 5 figures. v2: References and comments adde

    UV and EUV Instruments

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    We describe telescopes and instruments that were developed and used for astronomical research in the ultraviolet (UV) and extreme ultraviolet (EUV) regions of the electromagnetic spectrum. The wavelength ranges covered by these bands are not uniquely defined. We use the following convention here: The EUV and UV span the regions ~100-912 and 912-3000 Angstroem respectively. The limitation between both ranges is a natural choice, because the hydrogen Lyman absorption edge is located at 912 Angstroem. At smaller wavelengths, astronomical sources are strongly absorbed by the interstellar medium. It also marks a technical limit, because telescopes and instruments are of different design. In the EUV range, the technology is strongly related to that utilized in X-ray astronomy, while in the UV range the instruments in many cases have their roots in optical astronomy. We will, therefore, describe the UV and EUV instruments in appropriate conciseness and refer to the respective chapters of this volume for more technical details.Comment: To appear in: Landolt-Boernstein, New Series VI/4A, Astronomy, Astrophysics, and Cosmology; Instruments and Methods, ed. J.E. Truemper, Springer-Verlag, Berlin, 201

    Finite-Size Corrections to Anomalous Dimensions in N=4 SYM Theory

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    The scaling dimensions of large operators in N=4 supersymmetric Yang-Mills theory are dual to energies of semiclassical strings in AdS(5)xS(5). At one loop, the dimensions of large operators can be computed with the help of Bethe ansatz and can be directly compared to the string energies. We study finite-size corrections for Bethe states which should describe quantum corrections to energies of extended semiclassical strings.Comment: 10 page
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