Electrochemical behavior of lanthanum and yttrium ions in two molten chlorides with different oxoacidic properties: The eutectic LiCl-KCl and the equimolar mixture CaCl2-NaCl

The electrochemical behavior of LaCl3 and YCl3 was studied in two molten chloride mixtures with different oxoacidic properties, the eutectic LiCl-KCl and the equimolar CaCl2-NaCl melt at different temperatures. The stable oxidation states of both elements have been found to be (III) and (0) in both melts, and it was found that both La(III) and Y(III) cations were less solvated by the chloride ions in the calcium-based melt, which was explained by the stability of CaCl4 2- ions in that melt. Transient electrochemical techniques, such as cyclic voltammetry, chronopotentiometry and chronoamperometry were used in order to study the reaction mechanism and the transport parameters of electro active species at a tungsten electrode. The results showed that in the eutectic LiCl-KCl, the electro crystallization of lanthanum and yttrium seems to be the controlling electrochemical step while in CaCl2-NaCl this phenomenon has not been observed. That was explained in terms of the differences in the physicochemical properties of the systems, especially interfacial tensions. In the eutectic LiCl-KCl chronoamperometric studies indicated instantaneous and three dimensional nucleation and crystal growth of lanthanum and yttrium whatever the applied over potential of the rare earth metal is, whereas in the equimolar mixture CaCl2-NaCl, the corresponding electrochemical exchanges were found to be quasi-reversible, and the values of the kinetic parameters, K0 and α,were obtained for both reactions. Mass transport towards the electrode is a simple diffusion process, and the diffusion coefficients have been calculated. The validity of the Arrhenius law was also verified by plotting the variation of the logarithm of the diffusion coefficient versus 1/T

Conformance Verification of Normative Specifications using C-O Diagrams

C-O Diagrams have been introduced as a means to have a visual representation of normative texts and electronic contracts, where it is possible to represent the obligations, permissions and prohibitions of the different signatories, as well as what are the penalties in case of not fulfillment of their obligations and prohibitions. In such diagrams we are also able to represent absolute and relative timing constrains. In this paper we consider a formal semantics for C-O Diagrams based on a network of timed automata and we present several relations to check the consistency of a contract in terms of realizability, to analyze whether an implementation satisfies the requirements defined on its contract, and to compare several implementations using the executed permissions as criteria.Comment: In Proceedings FLACOS 2012, arXiv:1209.169

Evidence for coseismic events of recurrent prehistoric deformation along the Alhama de Murcia fault, southeastern Spain

The Alhama de Murcia fault is a 85 km long oblique-slip fault, and is related to historical and instrumental seismic activity. A paleoseismic analysis of the Lorca-Totana sector of the fault containing MSK I=VIII historical earthquakes was made in order to identify and quantify its seismic potential. We present 1) the results of the neotectonic, structural and geomorphological analyses and, 2) the results of trenching. In the study area, the Alhama de Murcia fault forms a depressed corridor between two strands, the northwestern fault with morphological and structural features of a reverse component of slip, bounding the La Tercia range to the South, and the southeastern fault strand with evidence of sinistral oblique strike-slip movement. The offset along this latter fault trapped the sediments in transit from the La Tercia range towards the Guadalentín depression. The most recent of these sediments are arranged in three generations of alluvial fans and terraces. The first two trenches were dug in the most recent sediments across the southeastern fault strand. The results indicate a coseismic reverse fault deformation that involved the sedimentary sequence up to the intermediate alluvial fan and the Holocene terrace deposits. The sedimentary evolution observed in the trenches suggests an event of temporary damming of the Colmenar creek drainage to the South due to uplifting of the hanging wall during coseismic activation of the fault. Trench, structural and sedimentological features provide evidence of at least three coseismic events, which occurred after 125,000yr. The minimum vertical slip rate along the fault is 0.06mm/yr and the average recurrence period should not exceed 40,000yr in  accordance with the results obtained by fan topographic profiling. Further absolute dating is ongoing to constrain these estimates.

A complete 0D thermodynamic predictive model for direct injection diesel engines

[EN] Ideal models provide the simplest way to reproduce internal combustion engine (ICE) cycles, but they usually do not represent with sufficient accuracy the actual behaviour of an ICE. A suitable alternative for research and development applications is provided by zero-dimensional (0D) thermodynamic models. Such models are very useful for predicting the instantaneous pressure and temperature in the combustion chamber, which in turn allows the prediction of engine operation characteristics. However, they use simplifying hypotheses which lead, in some cases, to a lack of accuracy or a limited predictive capability.This paper describes a 0D single-zone thermodynamic model that takes into account the heat transfer to the chamber walls, the blow-by leakage, the fuel injection and engine deformations, along with the instantaneous change in gas properties. Special attention has been paid to the description of the specific sub-models that have been used for the calculation of the energy and mass equations terms. The procedures followed for the estimation of some mechanical and heat transfer parameters and the combustion model fitting are also detailed. After the fitting, the model was validated in different operation points in a 4-cylinder 2-l DI diesel engine, showing a good capability for accurate predictions of engine performance and the gas state in the closed cycle. © 2011 Elsevier Ltd.The authors thank the Universitat Politecnica de Valencia (PAID-06-09) and Generalitat Valenciana (GV/2010/045) for their valuable support to this work and the referees for their worthy comments.Payri González, F.; Olmeda, P.; Martín Díaz, J.; García Martínez, A. (2011). A complete 0D thermodynamic predictive model for direct injection diesel engines. Applied Energy. 88:4632-4641. doi:10.1016/j.apenergy.2011.06.005S463246418

Watermelon Juice: Potential Functional Drink for Sore Muscle Relief in Athletes

L-Citrulline is an excellent candidate to reduce muscle soreness, and watermelon is a fruit rich in this amino acid. This study investigated the potential of watermelon juice as a functional drink for athletes. An in vitro study of intestinal absorption of l-citrulline in Caco-2 cells was performed using unpasteurized (NW), pasteurized (80 °C for 40 s) watermelon juice (PW) and, as control, a standard of l-citrulline. l-citrulline bioavailability was greater when it was contained in a matrix of watermelon and when no heat treatment was applied. In the in vivo experiment (maximum effort test in a cycloergometer), seven athletes were supplied with 500 mL of natural watermelon juice (1.17 g of l-citrulline), enriched watermelon juice (4.83 g of l-citrulline plus 1.17 g from watermelon), and placebo. Both watermelon juices helped to reduce the recovery heart rate and muscle soreness after 24 h.Actividad Física y Deport

Development of an Integrated Virtual Engine Model to Simulate New Standard Testing Cycles

[EN] The combination of more strict regulation for pollutant and CO2 emissions and the new testing cycles, covering a wider range of transient conditions, makes very interesting the development of predictive tools for engine design and pre-calibration. This paper describes a new integrated Virtual Engine Model (VEMOD) that has been developed as a standalone tool to simulate new standard testing cycles. The VEMOD is based on a wave-action model that carries out the thermo-and fluid dynamics calculation of the gas in each part of the engine. In the model, the engine is represented by means of 1D ducts, while the volumes, such as cylinders and reservoirs, are considered as 0D elements. Different sub-models are included in the VEMOD to take into account all the relevant phenomena. Thus, the combustion process is calculated by the Apparent Combustion Time (ACT) 1D model, responsible for the prediction of the rate of heat release and NOx formation. Experimental correlations are used to determine the rest of pollutants. In order to predict tailpipe pollutant emissions to the ambient, different sub-models have been developed to reproduce the behavior of the aftertreatment devices (DOC and DPF) placed in the exhaust system. Dedicated friction and auxiliaries sub-models allow obtaining the brake power. The turbocharger consists of 0D compressor and turbine sub-models capable of extrapolating the available maps of both devices. The VEMOD includes coolant and lubricant circuits linked, on the one hand, with the engine block and the turbocharger through heat transfer lumped models; and on the other hand with the engine heat exchangers. A control system emulating the ECU along with vehicle and driver sub-models allow completing the engine simulation. The Virtual Engine Model has been validated with experimental tests in a 1.6 L Diesel engine using steady and transient tests in both hot and cold conditions. Engine torque was predicted with a mean error of 3 Nm and an error below 14 Nm for 90 % of the cycle duration. CO2 presented a mean error of 0.04 g/s, while during 80 % of the cycle, error was below 0.44 g/s.This research has been partially funded by the European Union’s Horizon 2020 Framework Programme for research, technological development and demonstration under grant agreement 723976 (“DiePeR”) and by the Spanish government under the grant agreement TRA2017-89894-R. The authors wish to thank Renault SAS, especially P. Mallet and E. Gaïffas, for supporting this research.Martín Díaz, J.; Arnau Martínez, FJ.; Piqueras, P.; Auñón-García, Á. (2018). Development of an Integrated Virtual Engine Model to Simulate New Standard Testing Cycles. SAE Technical Papers. https://doi.org/10.4271/2018-01-1413

Timed Automata Semantics for Visual e-Contracts

C-O Diagrams have been introduced as a means to have a more visual representation of electronic contracts, where it is possible to represent the obligations, permissions and prohibitions of the different signatories, as well as what are the penalties in case of not fulfillment of their obligations and prohibitions. In such diagrams we are also able to represent absolute and relative timing constraints. In this paper we present a formal semantics for C-O Diagrams based on timed automata extended with an ordering of states and edges in order to represent different deontic modalities.Comment: In Proceedings FLACOS 2011, arXiv:1109.239

Chromomagnetic Dipole Moment of the Top Quark Revisited

We study the complete one-loop contributions to the chromagnetic dipole moment $\Delta\kappa$ of the top quark in the Standard Model, two Higgs doublet models, topcolor assited technicolor models (TC2), 331 models and extended models with a single extra dimension. We find that the SM predicts $\Delta\kappa = - 0.056$ and that the predictions of the other models are also consitent with the constraints imposed on $\Delta\kappa$ by low-energy precision measurements.Comment: 20 pages, 5 figures, Updat

Enigmatic tracks of solitary sauropods roaming an extensive lacustrine megatracksite in Iberia

Sauropod remains are abundant on the Iberian Peninsula across the Jurassic-Cretaceous transition. Where the osteological record shows a high diversity of this kind of dinosaur, the ichnological findings are mainly limited to sauropod tracks characterized by kidney-shaped manus (with or without pollex impressions) and pes impressions with three claw imprints oriented laterally. Here, we present a new sauropod ichnotaxon, Iniestapodus burgensis, found at several exposures within the Las Sereas megatracksite (Burgos, Spain). These are preserved within lacustrine limestone strata of the Rupelo Formation (Tithonian-Berriasian). Iniestapodus burgensis is characterized by: semicircular manus tracks with small pollex impressions; unusual tetradactyl pes tracks with evidence of four claws oriented anteriorly (I-II) and laterally (III-IV), of variable sizes (short claw I and IV impressions, claw II and III being the largest). The combination of features and comparison with the osteological record allows us to propose a non-titanosaurian titanosauriform as a possible trackmaker. All the Iniestapodus tracks are represented by at least two different size classes of small and medium-sized individuals, and their trackways show different multidirectional orientations. The paleoenvironmental and paleoecological data suggest that Iniestapodus trackmakers were solitary individuals, likely representing different age classes, that crossed and used the Las Sereas shallow lacustrine-palustrine areas as their preferred habitat