Organic Molecules in the Galactic Center. Hot Core Chemistry without Hot Cores

We study the origin of large abundances of complex organic molecules in the Galactic center (GC). We carried out a systematic study of the complex organic molecules CH3OH, C2H5OH, (CH3)2O, HCOOCH3, HCOOH, CH3COOH, H2CO, and CS toward 40 GC molecular clouds. Using the LTE approximation, we derived the physical properties of GC molecular clouds and the abundances of the complex molecules.The CH3OH abundance between clouds varies by nearly two orders of magnitude from 2.4x10^{-8} to 1.1x10^{-6}. The abundance of the other complex organic molecules relative to that of CH3OH is basically independent of the CH3OH abundance, with variations of only a factor 4-8. The abundances of complex organic molecules in the GC are compared with those measured in hot cores and hot corinos, in which these complex molecules are also abundant. We find that both the abundance and the abundance ratios of the complex molecules relative to CH3OH in hot cores are similar to those found in the GC clouds. However, hot corinos show different abundance ratios than observed in hot cores and in GC clouds. The rather constant abundance of all the complex molecules relative to CH3OH suggests that all complex molecules are ejected from grain mantles by shocks. Frequent (similar 10^{5}years) shocks with velocities >6km/s are required to explain the high abundances in gas phase of complex organic molecules in the GC molecular clouds. The rather uniform abundance ratios in the GC clouds and in Galactic hot cores indicate a similar average composition of grain mantles in both kinds of regions. The Sickle and the Thermal Radio Arches, affected by UV radiation, show different relative abundances in the complex organic molecules due to the differentially photodissociation of these molecules.Comment: 18 pages, 10 Postscript figures, uses aa.cls, aa.bst, 10pt.rtx, natbib.sty, revsymb.sty revtex4.cls, aps.rtx and aalongtabl.sty. Accepted in A&A 2006. version 2. relocated figures and tables. Language editor suggestions. added reference

Non-monotonic entanglement of physical EM field states in non-inertial frames

We develop a general technique to analyse the quantum effects of acceleration on realistic spatially-localised electromagnetic field states entangled in the polarization degree of freedom. We show that for this setting, quantum entanglement may build up as the acceleration increases, providing a clear signature of the quantum effects of relativistic acceleration.Comment: 5 pages, 3 figure

Hydrothermal stability of Ru/SiO2-C: A promising catalyst for biomass processing through liquid-phase reactions

In this work, structural and morphological properties of SiO2-C composite material to be used as support for catalysts in the conversion of biomass-derived oxygenated hydrocarbons, such as glycerol, were investigated in liquid water under various temperatures conditions. The results show that this material does not lose surface area, and the hot liquid water does not generate changes in the structure. Neither change in relative concentrations of oxygen functional groups nor in Si/C ratio due to hydrothermal treatment was revealed by X-ray photoelectron spectroscopy (XPS) analysis. Raman analysis showed that the material is made of a disordered graphitic structure in an amorphous silica matrix, which remains stable after hydrothermal treatment. Results of the hydrogenolysis of glycerol using a Ru/SiO2-C catalyst indicate that the support gives more stability to the active phase than a Ru/SiO2 consisting of commercial silica

Yukawa terms in noncommutative SO(10) and E6 GUTs

We propose a method for constructing Yukawa terms for noncommutative SO(10) and E6 GUTs, when these GUTs are formulated within the enveloping-algebra formalism. The most general noncommutative Yukawa term that we propose contains, at first order in thetamunu, the most general BRS invariant Yukawa contribution whose only dimensionful parameter is the noncommutativity parameter. This noncommutative Yukawa interaction is thus renormalisable at first order in thetamunu.Comment: 14 pages, no figure

H. Solari Yrigoyen, Así son las Malvinas, Buenos Aires, Hachette, 1959, 184 p.

Fil: F.de Martín, N.. Universidad Nacional de Cuyo. Facultad de Filosofía y Letra

Population bound effects on bosonic correlations in non-inertial frames

We analyse the effect of bounding the occupation number of bosonic field modes on the correlations among all the different spatial-temporal regions in a setting in which we have a space-time with a horizon along with an inertial observer. We show that the entanglement between A (inertial observer) and R (uniformly accelerated observer) depends on the bound N, contrary to the fermionic case. Whether or not decoherence increases with N depends on the value of the acceleration a. Concerning the bipartition A-antiR (Alice with an observer in Rindler's region IV), we show that no entanglement is created whatever the value of N and a. Furthermore, AR entanglement is very quickly lost for finite N and for infinite N. We will study in detail the mutual information conservation law found for bosons and fermions. By means of the boundary effects associated to N finiteness, we will show that for bosons this law stems from classical correlations while for fermions it has a quantum origin. Finally, we will present the strong N dependence of the entanglement in R-antiR bipartition and compare the fermionic cases with their finite N bosonic analogs. We will also show the anti-intuitive dependence of this entanglement on statistics since more entanglement is created for bosons than for their fermion counterparts.Comment: revtex 4, 12 pages, 10 figures. Added Journal ref

Entanglement of arbitrary spin fields in non-inertial frames

We generalise the study of fermionic and bosonic entanglement in non-inertial frames to fields of arbitrary spin and beyond the single mode approximation. After the general analysis we particularise for two interesting cases: entanglement between an inertial and an accelerated observer for massless fields of spin 1 (electromagnetic) and 3/2 (Rarita-Schwinger). We show that in the limit of infinite acceleration, no significant differences appear between the different spin fields for the states considered.Comment: 7 pages, 3 figures. Revtex 4.