Influence of Anion and Cation Structure of Ionic Liquids on Carboxylic Acids Extraction

A recently proposed new mechanism and a model of reactive extraction of carboxylic acids by hydrophobic ionic liquids (ILs) was tested on five systems from published as well as from new equilibrium data on liquid-liquid extraction of butyric and lactic acids (BA and LA) from aqueous solutions. Two phosphonium and one ammonium ILs were used. The model describes experimental data for all systems with a good fit. The mechanism of acid extraction by ILs is very similar for all tested systems. This indicates a more general validity of the developed model. The model allows deeper understanding of regularities in carboxylic acid extraction by hydrophobic ILs. Stability constants of the first acid-IL bonds are by one to three orders of magnitude higher compared to that of acid-acid bonds. Values of stability constants related to two acid-IL bonds are sensitive to a cation and anion structure while stability constants for acid-acid bonds more distant from polar head of IL are not sensitive to IL structure. The stability constants of acid-IL bonds for LA and phosphonium ILs are by more than one order of magnitude lower compared to those for BA and are not influenced with an anion structure. The value of stability constant for the first BA-IL bond is for phosphonium IL with a decanoate anion only one third of those for IL with a phosphinate anion. Differences in the stability of acid-IL bonds for BA and LA can be attributed to hydrophobic interactions which almost do not occur in LA extraction. Ammonium IL also forms a less stable BA-IL bond than the phosphonium IL with the same phosphinate anion. A less stable BA-IL bond can favor the higher recovery of volatile acid from the solvent by vacuum evaporation where free acid is separated instead of acid salts as in classical processes what is a great advantage

Probabilistic Modelling of Signal Mixtures with Differentiable Dictionaries

We introduce a novel way to incorporate prior information into (semi-) supervised non-negative matrix factorization, which we call differentiable dictionary search. It enables general, highly flexible and principled modelling of mixtures where non-linear sources are linearly mixed. We study its behavior on an audio decomposition task, and conduct an extensive, highly controlled study of its modelling capabilities.Comment: Published in the Proceedings of the 29th European Signal Processing Conference (EUSIPCO 2021), Dublin, Ireland, August 23-27, 2021 (IEEE), 441-44

Differentiable Dictionary Search: Integrating Linear Mixing with Deep Non-Linear Modelling for Audio Source Separation

This paper describes several improvements to a new method for signal decomposition that we recently formulated under the name of Differentiable Dictionary Search (DDS). The fundamental idea of DDS is to exploit a class of powerful deep invertible density estimators called normalizing flows, to model the dictionary in a linear decomposition method such as NMF, effectively creating a bijection between the space of dictionary elements and the associated probability space, allowing a differentiable search through the dictionary space, guided by the estimated densities. As the initial formulation was a proof of concept with some practical limitations, we will present several steps towards making it scalable, hoping to improve both the computational complexity of the method and its signal decomposition capabilities. As a testbed for experimental evaluation, we choose the task of frame-level piano transcription, where the signal is to be decomposed into sources whose activity is attributed to individual piano notes. To highlight the impact of improved non-linear modelling of sources, we compare variants of our method to a linear overcomplete NMF baseline. Experimental results will show that even in the absence of additional constraints, our models produce increasingly sparse and precise decompositions, according to two pertinent evaluation measures.Comment: Published in the Proceedings of the 24th International Congress on Acoustics (ICA 2022), Gyeongju, Korea, October 24-28, 202

Packing materials suitable for using in food industry

Obalový materiál je prostředek, kterého se využívá jako ochrany potravin před vnějšími fyzikálními, chemickými a mikrobiologickými vlivy a tedy pro prodloužení údržnosti potravin. Tato bakalářská práce se zabývá vlastnostmi nejčastěji používaných obalových materiálů a zmiňuje vhodnost jejich použití pro jednotlivé typy potraviny. Cílem je zpracovat literární rešerši obalových materiálů, které jsou pro přímý styk s potravinou vhodné, popsat jejich základní vlastnosti, způsoby zpracování a následné možnosti použití. Práce se také zabývá legislativou platnou pro obalové materiály a uvádí principy funkčnosti obalových materiálů budoucnosti.Packaging material is an agent which is used for food protection against outer physical, chemical and microbiological influences and consequently for extension of food durability. This bachelor thesis deals with the properties of the most often used packaging materials and notices their suitability for each types of food. The objective is to make the literature overview of packaging materials, which are suitable for direct contact with food, to describe their basic characteristics, fabrication techniques and resulting possibility of use. Thesis also deals with the legislation valid for packaging materials and features principles of functionality for incoming packaging materials.

Effect of viscosity of a liquid membrane containing oleyl alcohol on the pertraction of butyric acid

Solvent formulation is important in the optimization of the mass-transfer through supported liquid membranes (SLM) in pertraction and membrane extraction. Oleyl alcohol (OA) is frequently used as the solvent or diluent in the extraction of carboxylic acids. A disadvantage of OA is its relatively high viscosity of 28.32 mPa s at 25°C. This can be decreased by the application of a less viscous OA diluent, e.g. dodecane. The relationship between the ratio of the distribution coefficient of butyric acid (BA), D F, and the viscosity of OA-dodecane solvents, µ, as extraction and transport characteristics, and the overall mass-transfer coefficient, K p, through SLMs was analyzed. Dependence of the D F/µ ratio on the OA concentration showed a maximum at the OA concentration of 15 mass % to 30 mass %. The OA concentration dependence of K p for SLMs exhibited also a maximum at about 30 mass % and 20 mass % of OA at the BA concentration driving force of 0.12 kmol m−3 and 0.3 kmol m−3, respectively. Shifting of the maximum in K p dependences towards lower OA concentrations by increasing the BA concentration driving force is in agreement with the D F/µ ratio dependence. Using pure OA as the solvent or diluent is not preferable and a mixture of a low viscosity diluent with the OA concentration below 40 mass % should be used. The presented results show the potential of the D F/µ ratio in the screening and formulation of solvents in extraction and SLM optimization.Support of the Slovak grant agency VEGA No. 1-1184-11 is acknowledged

Extraction of Biomolecules Using Phosphonium-Based Ionic Liquids + K3PO4 Aqueous Biphasic Systems

Aqueous biphasic systems (ABS) provide an alternative and efficient approach for the extraction, recovery and purification of biomolecules through their partitioning between two liquid aqueous phases. In this work, the ability of hydrophilic phosphonium-based ionic liquids (ILs) to form ABS with aqueous K3PO4 solutions was evaluated for the first time. Ternary phase diagrams, and respective tie-lines and tie-lines length, formed by distinct phosphonium-based ILs, water, and K3PO4 at 298 K, were measured and are reported. The studied phosphonium-based ILs have shown to be more effective in promoting ABS compared to the imidazolium-based counterparts with similar anions. Moreover, the extractive capability of such systems was assessed for distinct biomolecules (including amino acids, food colourants and alkaloids). Densities and viscosities of both aqueous phases, at the mass fraction compositions used for the biomolecules extraction, were also determined. The evaluated IL-based ABS have been shown to be prospective extraction media, particularly for hydrophobic biomolecules, with several advantages over conventional polymer-inorganic salt ABS

Crime scene and its significance in criminal justice

Cílem mé práce je definovat místo činu a vysvětlit jeho význam pro trestní právo a kriminalistiku. Dále se zaměřuji na ohledání místa činu s malým exkurzem do teorie ohledání. V poslední části se věnuji kriminalistickým stopám, které se na místě činu mohou vyskytovat a pro představu popisuji několik typických a moderních stop.ObhájenoAim of my diploma thesis is to define crime scene a explain its significance for criminal law and criminalistics. Furthermore, i focus on crime scene investigation with little refference to theory of examination. In the last chapter i deal with criminological traces, that can be found on crime scene and for demonstration i some of the modern and typical traces