Iron and Nickel Isotopic Ratios in Presolar SiC Grains

We report the first Fe isotopic anomalies and the first Ni isotopic ratio measurements in presolar SiC grains of separate KJG from the Murchison meteorite. With NanoSIMS, we analyzed Fe and Ni in 37 X grains from Type II supernovae and 53 SiC grains of other types. The Ni/Fe and Co/Fe ratios in grains of all types are much higher than in the gas from which the grains are believed to have condensed. A majority of the X grains and a couple of mainstream grains contain Fe-rich subgrains. Most X grains have large excesses in 57Fe,61Ni, and 62Ni.60Ni excesses are small and the 54Fe/56Fe ratios of almost all X grains are normal. These isotopic compositions are best explained by mixing of material from the He/N zone of Type II supernovae with material from the He/C zone. The lack of any 54Fe excesses is puzzling in view of the fact that the Si/S zone, whose contribution resulted in the 28Si excesses in X grains, is very rich in 54Fe. It has yet to be seen whether elemental fractionation between Si and Fe is an explanation. The 57Fe deficits observed in a few X grains remain unexplained. In comparison to the X grains, fewer mainstream and AB grains have anomalies. Observed 62Ni excesses in some mainstream grains are larger than predicted for AGB stars of solar metallicity and are not accompanied by corresponding 61Ni excesses. A Y grain and a Z grain have excesses in 54Fe and 62Ni, but close to normal 57Fe/56Fe and 60,61Ni/58Ni ratios. These isotopic compositions are not expected for grains from low-metallicity AGB stars

New stellar sources for high-density, presolar graphite grains

WepresentC,N,O,Si,Al-Mg,K,Ca,andTiisotopicanalyses ofsevenhigh-density(ORG1f, � � 2:02 2:04 gcm � 3 ) graphite grains from Orgueil with 12 C/ 13 C ratios smaller than 20. The presence of 44Ti in three of these grains indicates an origin in Type II supernovae (SNe). The 13 C excesses in these SNe grains, however, remain enigmatic. The remaining grains have extremely large Ca and Ti isotopic anomalies, some of which are much larger than those predicted for envelopes of asymptotic giant branch (AGB) stars. These anomalies in conjunction with low 12 C/ 13 C ratios can only be explained by pure nucleosynthetic He-shell components of AGB stars. Born-again AGB stars that experience a late He flash are able to explain the low 12 C/ 13 C ratios of some of the grains along with the presence of extreme enrichments in the Ca and Ti isotopes. This study indicates that high-density graphite grains havemultiple stellar sources: SNe and born-again AGB stars, in addition to the previously established low-metallicity AGB stars. Subject headingg dust, extinction — meteors, meteoroids — nuclear reactions, nucleosynthesis, abundances — stars: abundances — stars: AGB and post-AGB — supernovae: genera

CAIs in Semarkona (LL3.0)

Calcium, Aluminum-rich inclusions (CAIs) are the first forming solids of the Solar system. Their observed abundance, mean size, and mineralogy vary quite significantly between different groups of chondrites. These differences may reflect the dynamics and distinct cosmochemical conditions present in the region(s) of the protoplanetary disk from which each type likely accreted. Only about 11 such objects have been found in L and LL type while another 57 have been found in H type ordinary chondrites, compared to thousands in carbonaceous chondrites. At issue is whether the rare CAIs contained in ordinary chondrites truly reflect a distinct population from the inclusions commonly found in other chondrite types. Semarkona (LL3.00) (fall, ~691 g) is the most pristine chondrite available in our meteorite collection. Here we report petrography and mineralogy of 3 CAIs from Semarkon

Na, K-Rich Rim Around a Chondrule in Unequilibrated Ordinary Chondrite Lew 86018 (L3.1)

Ordinary chondrites represent the most abundant early Solar system extra-terrestrial (approximately 85% abundance) material available for laboratory studies and expectedly record the most extensive range of alterations effects from unmetamorphosed chondritic material to the highest temperatures of thermal metamorphism. The least metamorphosed chondrites belonging to petrologic type 3, the so called unequili-brated ordinary chondrites (UOCs), provide insights into alteration that happened during the primeval, ear-liest stage of Solar system formation. The higher grade petrologic types 4-6 ordinary chondrites on the other hand document up to near textural equilibrium (in type 6) extensive thermal metamorphism consisting of minerals and phases providing evidence of equilibration of heterogeneous mineral composition, solid-state recrystallization. Despite being the most abundant, the effect of alteration is less explicitly understood in ordinary chondrites (even less in UOCs) compared to other groups (e.g. CV, CO, CR). Additionally, the relationship between metasomatism (also referred as aqueous alteration or fluid-assisted metamorphism) and metamorphism (primarily thermal driven) has not been studied and alterations in the ordinary chondrites have been considered to have occurred in absence of fluids in general. Despite this conventional view, UOCs of lowest grades (3.0-3.2) show some evidence of low temperature (approximately 200 C), fluid assisted metamorphism in the form of the presence of phyllosilicates, ferroan olivine, and magnetites in their matrices and occasionally in chondrules. Here, we present petrographic and mineralogical studies of UOC, Lewis Hills (LEW) 86018 to further our understanding of the extent and relative importance of metasomatism and/or metamorphism in UOCs

Evolution of oxygen isotopic composition in the inner solar nebula

Changes in the chemical and isotopic composition of the solar nebula with time are reflected in the properties of different constituents that are preserved in chondritic meteorites. CR carbonaceous chondrites are among the most primitive of all chondrite types and must have preserved solar nebula records largely unchanged. We have analyzed the oxygen and magnesium isotopes in a range of the CR constituents of different formation temperatures and ages, including refractory inclusions and chondrules of various types. The results provide new constraints on the time variation of the oxygen isotopic composition of the inner (<5 AU) solar nebula - the region where refractory inclusions and chondrules most likely formed. A chronology based on the decay of short-lived 26Al (t1/2 ~ 0.73 Ma) indicates that the inner solar nebula gas was 16O-rich when refractory inclusions formed, but less than 0.8 Ma later, gas in the inner solar nebula became 16O-poor and this state persisted at least until CR chondrules formed ~1-2 Myr later. We suggest that the inner solar nebula became 16O-poor because meter-size icy bodies, which were enriched in 17,18O due to isotopic self-shielding during the ultraviolet photo dissociation of CO in the protosolar molecular cloud or protoplanetary disk, agglomerated outside the snowline, drifted rapidly towards the Sun, and evaporated at the snowline. This led to significant enrichment in 16O-depleted water, which then spread through the inner solar system. Astronomical studies of the spatial and/or temporal variations of water abundance in protoplanetary disks may clarify these processes.Comment: 27 pages, 5 figure

New attempts to understand nanodiamond stardust

We report on a concerted effort aimed at understanding the origin and history of the pre-solar nanodiamonds in meteorites including the astrophysical sources of the observed isotopic abundance signatures. This includes measurement of light elements by secondary ion mass spectrometry (SIMS), analysis of additional heavy trace elements by accelerator mass spectrometry (AMS) and dynamic calculations of r-process nucleosynthesis with updated nuclear properties. Results obtained indicate: a) there is no evidence for the former presence of now extinct 26Al and 44Ti in our diamond samples other than what can be attributed to silicon carbide and other "impurities"; this does not offer support for a supernova (SN) origin but neither does it negate it; b) analysis by AMS of platinum in "bulk diamond" yields an overabundance of r-only 198Pt that at face value seems more consistent with the neutron burst than with the separation model for the origin of heavy trace elements in the diamonds, although this conclusion is not firm given analytical uncertainties; c) if the Xe-H pattern was established by an unadulterated r-process, it must have been a strong variant of the main r-process, which possibly could also account for the new observations in platinum.Comment: Workshop on Astronomy with Radioactvities VII; Publications of the Astronomical Society of Australia, accepte

SEM-EDS analyses of small craters in stardust aluminium foils: implications for the Wild-2 dust distribution

Implications for the Wild-2 dust distribution of the statistical results obtained by SEM-EDS from nearly 300 impact craters on aluminium foils of the Stardust sample tray assembly

Co-production of light p-, s- and r-process isotopes in the high-entropy wind of type II supernovae

We have performed large-scale nucleosynthesis calculations within the high-entropy-wind (HEW) scenario of type II supernovae. The primary aim was to constrain the conditions for the production of the classical "p-only" isotopes of the light trans-Fe elements. We find, however, that for electron fractions in the range 0.458 $\le$ Y$_e$ $\le$ 0.478, sizeable abundances of p-, s- and r-process nuclei between $^{64}$Zn and $^{98}$Ru are coproduced in the HEW at low entropies (S $\le$ 100) by a primary charged-particle process after an $\alpha$-rich freezeout. With the above Y$_e$ -- S correlation, most of the predicted isotopic abundance ratios within a given element (e.g. $^{64}$Zn(p)/$^{70}$Zn(r) or $^{92}$Mo(p)/$^{94}$Mo(p)), as well as of neighboring elements (e.g. $^{70}$Ge(s+p)/$^{74}$Se(p) or $^{74}$Se(p)/$^{78}$Kr(p)) agree with the observed Solar-System ratios. Taking the Mo isotopic chain as a particularly challenging example, we show that our HEW model can account for the production of all 7 stable isotopes, from "p-only" $^{92}$Mo, via "s-only" $^{96}$Mo up to "r-only" $^{100}$Mo. Furthermore, our model is able to reproduce the isotopic composition of Mo in presolar SiC X-grains.}Comment: 10 pages, 2 figure

Stardust in STARDUST - the C, N, and O Isotopic Compositions of Wild 2 Cometary Matter in Al foil Impacts

In January 2006, the STARDUST mission successfully returned dust samples from the tail of comet 81P/Wild 2 in two principal collection media, low density silica aerogel and Al foil. While hypervelocity impacts at 6.1 km/s, the encounter velocity of STARDUST, into Al foils are generally highly disruptive for natural, silicate-dominated impactors, previous studies have shown that many craters retain sufficient residue to allow a determination of the elemental and isotopic compositions of the original projectile. We have used the NanoSIMS to perform C, N, and O isotope imaging measurements on four large (59-370 microns diameter) and on 47 small (0.32-1.9 microns diameter) Al foil impact craters as part of the STARDUST Preliminary Examination. Most analyzed residues in and around these craters are isotopically normal (solar) in their C, N, and O isotopic compositions. However, the debris in one large crater shows an average 15N enrichment of approx. 450 %, which is similar to the bulk composition of some isotopically primitive interplanetary dust particles. A 250 nm grain in another large crater has an O-17 enrichment with approx. 2.65 times the solar O-17/O-16 ratio. Such an O isotopic composition is typical for circumstellar oxide or silicate grains from red giant or asymptotic giant branch stars. The discovery of this circumstellar grain clearly establishes that there is authentic stardust in the cometary samples returned by the STARDUST mission. However, the low apparent abundance of circumstellar grains in Wild 2 samples and the preponderance of isotopically normal material indicates that the cometary matter is a diverse assemblage of presolar and solar system materials

Presolar He and Ne Isotopes in Single Circumstellar SiC Grains

Noble gas isotopes in presolar silicon carbide (SiC) dust grains from primitive meteorites provide, together with major element isotopic compositions, insight into the nucleosynthetic output of different types of evolved stars >4.5 Gyr ago. We report here new results from helium and neon isotopic analyses of single presolar SiC grains with sizes between 0.6 and 6.3 μm using an ultrahigh sensitivity mass spectrometer. These noble gas studies were complemented by an ion microprobe study (NanoSIMS) of Si, C, and N isotopic compositions of the same grains. About 40%, or 46 of the 110 grains analyzed, contain nucleosynthetic 22Ne and/or 4He from their parent stars above our mass spectrometer's detection limit. We discuss the possible stellar sources using isotopic ratios as constraints combined with new model predictions for low- to intermediate-mass (1.5, 2, 3, and 5 M☉) asymptotic giant branch (AGB) stars of different metallicities (1, 1/2, 1/3, and 1/6 Z☉). Most SiC grains are of the mainstream type and originated in low-mass AGB stars. We find a higher-than-expected percentage of A/B type grains, with some containing 22Ne and/or 4He. In addition, we find one noble gas-rich nova grain candidate, one supernova grain (X-type grain), and one 22Ne-rich X- or Z-type grain candidate