Low-power Secret-key Agreement over OFDM

Information-theoretic secret-key agreement is perhaps the most practically feasible mechanism that provides unconditional security at the physical layer to date. In this paper, we consider the problem of secret-key agreement by sharing randomness at low power over an orthogonal frequency division multiplexing (OFDM) link, in the presence of an eavesdropper. The low power assumption greatly simplifies the design of the randomness sharing scheme, even in a fading channel scenario. We assess the performance of the proposed system in terms of secrecy key rate and show that a practical approach to key sharing is obtained by using low-density parity check (LDPC) codes for information reconciliation. Numerical results confirm the merits of the proposed approach as a feasible and practical solution. Moreover, the outage formulation allows to implement secret-key agreement even when only statistical knowledge of the eavesdropper channel is available.Comment: 9 pages, 4 figures; this is the authors prepared version of the paper with the same name accepted for HotWiSec 2013, the Second ACM Workshop on Hot Topics on Wireless Network Security and Privacy, Budapest, Hungary 17-19 April 201

Synthesis and characterization of piezoelectric thin films as functional materials for sensing

This thesis reports about the sputter deposition and characterization of ZnO nanomaterials both in the form of dense and sponge-like thin films. It is shown that high-quality ZnO thin films can be successfully grown on both hard and flexible conductive substrates, with the final aim of proving that their piezoelectric and electrical properties can be successfully exploited in the fabrication of piezoelectric-based nanosensors and nanoactuators. To further state the versatility of ZnO thin films, both spin coated and sputtered dense ZnO thin films were used as seed layers for promoting the growth of well-aligned ZnO nanowires. A strong relationship between the kind of seed layer, i.e., sputtered or spin-coated, and the final NWs morphology, surface chemistry and thus wettability was noticed. In particular NWs grown on sputtered seed layers showed a superhydrophobic behavior, ideal for self-cleaning, anti-fogging or microfluidic devices. In contrast, on spin coated seed layers, highly hydrophilic NWs were obtained, being suitable for further surface functionalization with enhanced adsorption properties towards biological agents or dye for imaging, diagnostic, optical or photovoltaic applications. Finally, the sponge-like morphology is further exploited for the synthesis and characterization of Mn- and Sb- doped, sponge-like ZnO films. The presence of Mn dopant resulted in a high resistance contribution. On the contrary, typical ferroelectric switching phenomena were observed in the Sb-doped ZnO films, showing the presence of hysteretical polarization loops

Gentamicin-releasing mesoporous ZnO structures

Among metal oxides, zinc oxide (ZnO) is one of the most attractive materials thanks to its biocompatible and biodegradable properties along with the existence of various morphologies featuring piezoelectric, semiconducting and photocatalytic activities. All of these structures were successfully prepared and tested for numerous applications, including optoelectronics, sensors and biomedical ones. In the last case, biocompatible ZnO nanomaterials positively influenced cells growth and tissue regeneration as well, promoting wound healing and new bone formation. Despite showing high surface areas, ZnO morphologies generally lack an intrinsic mesoporous structure, strongly limiting the investigation of the corresponding drug loading and release properties. Within this scope, this study focuses on the adsorption and release properties of high surface area, mesoporous ZnO structures using gentamicin sulfate (GS), a well known antibiotic against bacterial infections especially in orthopedics. The particular ZnO morphology was achieved starting from sputtered porous zinc layers, finally converted into ZnO by thermal oxidation. By taking advantage of this mesoporous framework, GS was successfully adsorbed within the ZnO matrix and the kinetic release profile evaluated for up to seven days. The adsorption of GS was successfully demonstrated, with a maximum amount of 263 mg effectively loaded per gram of active material. Then, fast kinetic release was obtained in vitro by simple diffusion mechanism, thus opening further possibilities of smart pore and surface engineering to improve the controlled delivery

ZnO Nanostructures for Tissue Engineering Applications

This review focuses on the most recent applications of zinc oxide (ZnO) nanostructures for tissue engineering. ZnO is one of the most investigated metal oxides, thanks to its multifunctional properties coupled with the ease of preparing various morphologies, such as nanowires, nanorods, and nanoparticles. Most ZnO applications are based on its semiconducting, catalytic and piezoelectric properties. However, several works have highlighted that ZnO nanostructures may successfully promote the growth, proliferation and differentiation of several cell lines, in combination with the rise of promising antibacterial activities. In particular, osteogenesis and angiogenesis have been effectively demonstrated in numerous cases. Such peculiarities have been observed both for pure nanostructured ZnO scaffolds as well as for three-dimensional ZnO-based hybrid composite scaffolds, fabricated by additive manufacturing technologies. Therefore, all these findings suggest that ZnO nanostructures represent a powerful tool in promoting the acceleration of diverse biological processes, finally leading to the formation of new living tissue useful for organ repair

Porous Zinc Oxide Thin Films: Synthesis Approaches and Applications

Zinc oxide (ZnO) thin films have been widely investigated due to their multifunctional properties, i.e., catalytic, semiconducting and optical. They have found practical use in a wide number of application fields. However, the presence of a compact micro/nanostructure has often limited the resulting material properties. Moreover, with the advent of low-dimensional ZnO nanostructures featuring unique physical and chemical properties, the interest in studying ZnO thin films diminished more and more. Therefore, the possibility to combine at the same time the advantages of thin-film based synthesis technologies togetherwith a high surface area and a porous structuremight represent a powerful solution to prepare ZnO thin films with unprecedented physical and chemical characteristics that may find use in novel application fields. Within this scope, this review offers an overview on the most successful synthesis methods that are able to produce ZnO thin films with both framework and textural porosities. Moreover, we discuss the related applications, mainly focused on photocatalytic degradation of dyes, gas sensor fabrication and photoanodes for dye-sensitized solar cells

3D Printed Metallic Pillar Nanomechanical Resonators Decorated with TiO2 Nanotubes for Highly Sensitive Environmental Applications

Micro and nanomechanical devices offer enhanced sensing capabilities for detecting biological and chemical small molecules. However, miniaturization necessitates advanced fabrication processes and complex measurement systems, hindering routine sensor analysis. While alternative methods like 3D printing show promise, challenges such as low device resolution persist due to intrinsic damping of polymer inks. In this study, an array of micrometric pillar resonators is fabricated in Ti6Al4 V alloy using additive manufacturing based on laser powder bed fusion technology. These metallic nanomechanical resonators exhibit a very high quality factor with minimal difference between air and vacuum measurements due to low intrinsic damping. Furthermore, titania nanotubes grown on the pillars via anodic oxidation heighten sensitivity for molecular dye degradation evaluation. Leveraging the weak coupling phenomenon among the pillars in the array, these devices facilitate large-scale parallelized measurements, here demonstrated with real-time analysis of dye degradation process. This approach to creating mass sensing devices via metallic additive manufacturing can usher in a new generation of highly performing resonating sensor arrays, offering a cost-effective and efficient alternative to traditional silicon microfabrication methods