Exchange reactions of poly(arylene ether ketone) dithioketals with aliphatic diols: formation and deprotection of poly(arylene ether ketal)s

The dithioketal derivatives of industrially important, semi-crystalline poly(arylene ether ketone)s undergo facile exchange with aliphatic diols in the presence of N-bromo-succinimide to give a range of novel poly(arylene ether ketal)s. These are amorphous and readily soluble in a wide range of organic solvents. Although generally stable under ambient conditions, they undergo rapid and quantitative hydrolysis in the presence of acids to regenerate the original polyketones. The poly(ether ketal)s reported here are not accessible from ketal-type monomers, nor can they be obtained by direct reaction of poly(ether ketone)s with aliphatic diols. The starting polyketones are essentially unchanged after sequential dithioketalization, dithioketal-ketal exchange, ketal hydrolysis, and re-dithioketalization. Poly(arylene ether ketal)s provide a new approach to the processing of poly(arylene ether ketone)s into carbon fiber composite materials

Some issues when using Fourier analysis for the extraction of modal parameters

It is sometimes necessary to determine the manner in which structures deteriorate with respect to time; for instance when quantifying a material's ability to withstand sustained dynamic loads. In such cases, it is well established that loss of structural integrity is reflected by variations in modal characteristics such as stiffness. This paper addresses some practical limitations of Fourier analysis with respect to temporal resolution and the uncertainties associated with extracting variations in modal parameters. The statistical analysis of numerous numerical experiments shows how techniques, such as data overlapping and zero-padding, can be used to improve the sensitivity of modal parameter extraction

Asymptotic Karlin-Rubin's Theorem with Application to Signal Detection in a Subspace Cone

International audienc

Thermoplastic infusible resin systems: candidates for the marine sector?

This work investigated the feasibility of the use of a novel infusible thermoplastic resin (Elium 150 from Arkema) for composite laminate manufacture by resin infusion methods and possible application in the shipbuilding sector. We compared the properties of Elium glass-fibre laminates with those of laminates infused with state-of-the-art thermosetting epoxy and urethane acrylate resins. The Elium laminates matched the mechanical performance (flexure and interlaminar shear strength) of the epoxy and surpassed that of the urethane acrylate counterpart. However, the mechanical performance of the Elium laminates after immersion in water at 35 oC for 28 days deteriorated compared to urethane acrylate, but was comparable in flexural properties to that of the epoxy. The combination of superior mechanical performance coupled with acceptable environmental resistance and comparable composite laminate manufacturing conditions makes the infusible thermoplastic a possible future candidate matrix over commercial thermosetting resin options

Retention of Mechanical Properties After Water Immersion for Glass-Fibre Polymer Composite Laminates with Thermoset & Thermoplastic Infusible Resins

In this work, we conducted an extensive comparative study of the water absorption behavior and retention of mechanical properties of a group of GRP composite laminates manufactured with a range of infusible thermosetting and thermoplastics resins. All laminates were manufactured by Vacuum-Assisted Resin Transfer Moulding (VARTM; the most relevant manufacturing technique in shipbuilding) with a range of state-of-the-art thermosetting resins (Urethane acrylate Crestapol 1210, Epoxy SR1125, Bio-epoxy Supersap CLR, Phenolic Cellobond J2027X) and a novel infusible acrylic thermoplastic resin (Acrylic Elium 150). The reinforcement of choice for each laminate was a unidirectional glass fabric of 996 gsm. Sample preparation for water immersion studies was according to ASTM D5229. This study was part of a comprehensive down-selection of commercially available resins in terms of their suitability for shipbuilding applications, as part of the EU H2020 project FIBRESHIP2 .  A selection of relevant properties of the laminates with different resin systems is presented in this paper including fibre volume fraction, apparent interlaminar shear strength (dry and wet condition), flexural strength (dry and wet condition) and flexural modulus (dry and wet condition)

Mechanical evaluation of a fire retardant through-thickness reinforced sandwich structure for marine applications

One of the main restrictions in adopting polymer composite materials for primary and secondary structural applications in marine vessels over 50 meters in length is concerns regarding fire retardancy and also a lack of design guidelines in general. The aim of this study is to evaluate the edgewise compression strength and core-shear strength of a fire retardant sandwich structure reinforced with through thickness composite ‘bridges’ under ambient conditions. These properties are important for structural components subjected to in-plane loads such as bulkheads. Core shear strength of the through-thickness reinforced sandwich far exceeded non-reinforced sandwich. However, edgewise compression strength and stiffness of the reinforced case was found to be similar to the unreinforced case

Performance metrics for the evaluation of hyperspectral chemical identification systems

Remote sensing of chemical vapor plumes is a difficult but important task for many military and civilian applications. Hyperspectral sensors operating in the long-wave infrared regime have well-demonstrated detection capabilities. However, the identification of a plume’s chemical constituents, based on a chemical library, is a multiple hypothesis testing problem which standard detection metrics do not fully describe. We propose using an additional performance metric for identification based on the so-called Dice index. Our approach partitions and weights a confusion matrix to develop both the standard detection metrics and identification metric. Using the proposed metrics, we demonstrate that the intuitive system design of a detector bank followed by an identifier is indeed justified when incorporating performance information beyond the standard detection metrics.United States. Defense Threat Reduction Agency (Air Force contract FA8721-05-C-0002

Bio-based epoxy resin systems as potential alternatives to petroleum based epoxy matrices in marine fibre-reinforced polymer composites

Fibre-reinforced polymers (FRP) are extensively used in the marine industry for the manufacture of lightweight hull structures for vessels up to 50m in length, and for secondary structures and components in larger vessels. The main benefits resulting in the application of FRP in shipbuilding include: significant weight reduction resulting in substantial fuel saving, increase in cargo capacity and subsequent reduction of greenhouse gas emissions, improved life cycle performance and reduced maintenance costs due to corrosion resistance. As the use of thermoset polymers in shipbuilding increases, so too does the interest in finding suitable alternatives to the use of petroleum-based raw materials. Much work has been published on bio-based epoxy resin systems from natural raw materials, such as vegetable oils, however, the mechanical performance of the bio-based resin systems in comparison to equivalent petroleum-based systems is not widely documented. This research focusses on the comparison of petroleum-based and bio-based two-part commercial epoxy resin systems to manufacture glass fibre reinforced polymers (GFRP) for marine applications. Laminates were manufactured using the Vacuum Assisted Resin Transfer Moulding (VARTM) manufacturing process. Specimens were mechanically characterised in order to evaluate fibre volume fraction, density, apparent inter-laminar shear strength, flexural modulus and strength. The effect of water ingress on the mechanical properties of laminates was also studied by soaking samples in water at 35°C for 28 days. Specimen quality and fracture surfaces were assessed using optical and scanning electron microscopy. Initial results have shown that the average apparent inter-laminar shear strength of the petroleum-based samples was almost identical to the bio-based samples (within 1%), while the flexural strength and modulus of the petroleum-based samples was only 6% and 7% higher than the bio-based samples. Despite the comparatively good mechanical performance of the bio-based laminate, the high viscosity of the resin resulted in higher infusion temperatures and longer infusion times than for the petroleum-based epoxy

La escuela atrapada en la red : Algunos signos de su parálisis

El presente trabajo intentará explorar algunos interrogantes sobre la cultura escolar ¿es posible incluir en la escuela las nuevas tecnologías de la información y la comunicación? ¿Es solo cuestión de aparatos? ¿En qué consiste la mass-mediatización de la cultura? ¿La escuela puede procesar el pasaje de la cultura de la espera a la mass-mediática? ¿Estas nuevas características producen cambios significativos o sólo son metabolizadas por la cultura escolar? ¿La escuela está en peligro de extinción?Trabajo presentado en el Panel 7: Producciones, encuentros y conflictos de la cultura material de la escuelaFacultad de Humanidades y Ciencias de la EducaciónSociedad Argentina de Historia de la Educación (SAHE