14,103 research outputs found
Alloying effects on the optical properties of GeSi nanocrystals from TDDFT and comparison with effective-medium theory
We present the optical spectra of GeSi alloy nanocrystals
calculated with time-dependent density-functional theory in the adiabatic
local-density ap proximation (TDLDA). The spectra change smoothly as a function
of the compositio n . On the Ge side of the composition range, the lowest
excitations at the ab sorption edge are almost pure Kohn-Sham
independent-particle HOMO-LUMO transitio ns, while for higher Si contents
strong mixing of transitions is found. Within T DLDA the first peak is slightly
higher in energy than in earlier independent-par ticle calculations. However,
the absorption onset and in particular its composit ion dependence is similar
to independent-particle results. Moreover, classical depolarization effects are
responsible for a very strong suppression of the abs orption intensity. We show
that they can be taken into account in a simpler way using Maxwell-Garnett
classical effective-medium theory. Emission spectra are in vestigated by
calculating the absorption of excited nanocrystals at their relaxe d geometry.
The structural contribution to the Stokes shift is about 0.5 eV. Th e
decomposition of the emission spectra in terms of independent-particle transit
ions is similar to what is found for absorption. For the emission, very weak
tra nsitions are found in Ge-rich clusters well below the strong absorption
onset.Comment: submitted to Phys. Rev.
Focusing of opinions in the Deffuant model: First impression counts
The paper treats opinion dynamics of an unequal distribution as the initial
opinion distribution. Simulated is the Deffuant model on a directed
Barabasi-Albert network with discrete opinions and several subjects. Noticed is
a focusing of the the resulting opinion distribution during the simulation
towards the average value of the initial opinion distribution. A small change
of the focusing is seen. A dependency of this change on the number of subjects
and opinions is detected and indicates the change as a consequence of
discretization the opinions. Hereby the average value of the initial opinion
distribution can be identified as the guide of opinion forming.Comment: 8 pages including 5 figures, for Int. J. Mod. Phys.
Quadratic invariants for discrete clusters of weakly interacting waves
We consider discrete clusters of quasi-resonant triads arising from a Hamiltonian three-wave equation. A cluster consists of N modes forming a total of M connected triads. We investigate the problem of constructing a functionally independent set of quadratic constants of motion. We show that this problem is equivalent to an underlying basic linear problem, consisting of finding the null space of a rectangular M × N matrix with entries 1, −1 and 0. In particular, we prove that the number of independent quadratic invariants is equal to J ≡ N − M* ≥ N − M, where M* is the number of linearly independent rows in Thus, the problem of finding all independent quadratic invariants is reduced to a linear algebra problem in the Hamiltonian case. We establish that the properties of the quadratic invariants (e.g., locality) are related to the topological properties of the clusters (e.g., types of linkage). To do so, we formulate an algorithm for decomposing large clusters into smaller ones and show how various invariants are related to certain parts of a cluster, including the basic structures leading to M* < M. We illustrate our findings by presenting examples from the Charney–Hasegawa–Mima wave model, and by showing a classification of small (up to three-triad) clusters
Modeling the Local Warm/Hot Bubble
In this paper we review the modeling of the Local Bubble (LB) with special
emphasis on the progress we have made since the last major conference "The
Local Bubble and Beyond (I)" held in Garching in 1997. Since then new insight
was gained into the possible origin of the LB, with a moving group crossing its
volume during the last 10 - 15 Myr being most likely responsible for creating a
local cavity filled with hot recombining gas. Numerical high resolution 3D
simulations of a supernova driven inhomogeneous interstellar medium show that
we can reproduce both the extension of the LB and the OVI column density in
absorption measured with FUSE for a LB age of 13.5 - 14.5 Myr. We further
demonstrate that the LB evolves like an ordinary superbubble expanding into a
density stratified medium by comparing analytical 2D Kompaneets solutions to
NaI contours, representing the extension of the local cavity. These results
suggest that LB blow-out into the Milky Way halo has occurred roughly 5 Myr
ago.Comment: 8 pages, 3 figures, to appear in the proceedings of "The Local Bubble
and Beyond II", Philadelphia, USA, April 21-24, 200
A time-dependent density functional theory scheme for efficient calculations of dynamic (hyper)polarizabilities
We present an efficient perturbative method to obtain both static and dynamic
polarizabilities and hyperpolarizabilities of complex electronic systems. This
approach is based on the solution of a frequency dependent Sternheimer
equation, within the formalism of time-dependent density functional theory, and
allows the calculation of the response both in resonance and out of resonance.
Furthermore, the excellent scaling with the number of atoms opens the way to
the investigation of response properties of very large molecular systems. To
demonstrate the capabilities of this method, we implemented it in a real-space
(basis-set free) code, and applied it to benchmark molecules, namely CO, H2O,
and paranitroaniline (PNA). Our results are in agreement with experimental and
previous theoretical studies, and fully validate our approach.Comment: 9 pages, 4 figure
L1599B: Cloud Envelope and C+ Emission in a Region of Moderately Enhanced Radiation Field
We study the effects of an asymmetric radiation field on the properties of a
molecular cloud envelope. We employ observations of carbon monoxide (12CO and
13CO), atomic carbon, ionized carbon, and atomic hydrogen to analyze the
chemical and physical properties of the core and envelope of L1599B, a
molecular cloud forming a portion of the ring at approximately 27 pc from the
star Lambda Ori. The O III star provides an asymmetric radiation field that
produces a moderate enhancement of the external radiation field. Observations
of the [CII] fine structure line with the GREAT instrument on SOFIA indicate a
significant enhanced emission on the side of the cloud facing the star, while
the [Ci], 12CO and 13CO J = 1-0 and 2-1, and 12CO J = 3-2 data from the PMO and
APEX telescopes suggest a relatively typical cloud interior. The atomic, ionic,
and molecular line centroid velocities track each other very closely, and
indicate that the cloud may be undergoing differential radial motion. The HI
data from the Arecibo GALFA survey and the SOFIA/GREAT [CII] data do not
suggest any systematic motion of the halo gas, relative to the dense central
portion of the cloud traced by 12CO and 13CO.Comment: 9 Figure
On the relation between virial coefficients and the close-packing of hard disks and hard spheres
The question of whether the known virial coefficients are enough to determine
the packing fraction at which the fluid equation of state of a
hard-sphere fluid diverges is addressed. It is found that the information
derived from the direct Pad\'e approximants to the compressibility factor
constructed with the virial coefficients is inconclusive. An alternative
approach is proposed which makes use of the same virial coefficients and of the
equation of state in a form where the packing fraction is explicitly given as a
function of the pressure. The results of this approach both for hard-disk and
hard-sphere fluids, which can straightforwardly accommodate higher virial
coefficients when available, lends support to the conjecture that
is equal to the maximum packing fraction corresponding to an ordered
crystalline structure.Comment: 10 pages, 6 figures; v2: discussion about hard-square and
hard-hexagon systems on a lattice added; five new reference
Critical behavior of a Ginzburg-Landau model with additive quenched noise
We address a mean-field zero-temperature Ginzburg-Landau, or \phi^4, model
subjected to quenched additive noise, which has been used recently as a
framework for analyzing collective effects induced by diversity. We first make
use of a self-consistent theory to calculate the phase diagram of the system,
predicting the onset of an order-disorder critical transition at a critical
value {\sigma}c of the quenched noise intensity \sigma, with critical exponents
that follow Landau theory of thermal phase transitions. We subsequently perform
a numerical integration of the system's dynamical variables in order to compare
the analytical results (valid in the thermodynamic limit and associated to the
ground state of the global Lyapunov potential) with the stationary state of the
(finite size) system. In the region of the parameter space where metastability
is absent (and therefore the stationary state coincide with the ground state of
the Lyapunov potential), a finite-size scaling analysis of the order parameter
fluctuations suggests that the magnetic susceptibility diverges quadratically
in the vicinity of the transition, what constitutes a violation of the
fluctuation-dissipation relation. We derive an effective Hamiltonian and
accordingly argue that its functional form does not allow to straightforwardly
relate the order parameter fluctuations to the linear response of the system,
at odds with equilibrium theory. In the region of the parameter space where the
system is susceptible to have a large number of metastable states (and
therefore the stationary state does not necessarily correspond to the ground
state of the global Lyapunov potential), we numerically find a phase diagram
that strongly depends on the initial conditions of the dynamical variables.Comment: 8 figure
On the calculation of the bandgap of periodic solids with MGGA functionals using the total energy
During the last few years, it has become more and more clear that functionals of the meta generalized gradient approximation (MGGA) are more accurate than GGA functionals for the geometry and energetics of electronic systems. However, MGGA functionals are also potentially more interesting for the electronic structure, in particular, when the potential is nonmultiplicative (i.e., when MGGAs are implemented in the generalized Kohn-Sham framework), which may help to get more accurate bandgaps. Here, we show that the calculation of bandgap of solids with MGGA functionals can also be done very accurately in a non-self-consistent manner. This scheme uses only the total energy and can, therefore, be very useful when the self-consistent implementation of a particular MGGA functional is not available. Since self-consistent MGGA calculations may be difficult to converge, the non-self-consistent scheme may also help to speed up the calculations. Furthermore, it can be applied to any other types of functionals, for which the implementation of the corresponding potential is not trivial
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