Management of singlet and triplet excitons for efficient white organic light-emitting devices

Lighting accounts for approximately 22 per cent of the electricity consumed in buildings in the United States, with 40 per cent of that amount consumed by inefficient (similar to 15 lm W-1) incandescent lamps(1,2). This has generated increased interest in the use of white electroluminescent organic light-emitting devices, owing to their potential for significantly improved efficiency over incandescent sources combined with low-cost, high-throughput manufacturability. The most impressive characteristics of such devices reported to date have been achieved in all-phosphor-doped devices, which have the potential for 100 per cent internal quantum efficiency(2): the phosphorescent molecules harness the triplet excitons that constitute three-quarters of the bound electron-hole pairs that form during charge injection, and which (unlike the remaining singlet excitons) would otherwise recombine non-radiatively. Here we introduce a different device concept that exploits a blue fluorescent molecule in exchange for a phosphorescent dopant, in combination with green and red phosphor dopants, to yield high power efficiency and stable colour balance, while maintaining the potential for unity internal quantum efficiency. Two distinct modes of energy transfer within this device serve to channel nearly all of the triplet energy to the phosphorescent dopants, retaining the singlet energy exclusively on the blue fluorescent dopant. Additionally, eliminating the exchange energy loss to the blue fluorophore allows for roughly 20 per cent increased power efficiency compared to a fully phosphorescent device. Our device challenges incandescent sources by exhibiting total external quantum and power efficiencies that peak at 18.7 +/- 0.5 per cent and 37.6 +/- 0.6 lm W-1, respectively, decreasing to 18.4 +/- 0.5 per cent and 23.8 +/- 0.5 lm W-1 at a high luminance of 500 cd m(-2).Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/62889/1/nature04645.pd

Quark deconfinement in neutron star cores and the ground state of neutral matter

Whether or not deconfined quark phase exists in neutron star cores and represents the ground state of neutral matter at moderate densities are open questions. We use two realistic effective quark models, the three-flavor Nambu-Jona-Lasinio model and the modified quark-meson coupling model, to describe the neutron star matter. After constructing possible hybrid equations of state (EOSes) with unpaired or color superconducting quark phase, we systematically discuss the observational constraints of neutron stars on the EOSes. It is found that the neutron star with pure quark matter core is unstable and the hadronic phase with hyperons is denied, while hybrid EOSes with two-flavor color superconducting phase or unpaired quark matter phase are both allowed by the tight and most reliable constraints from two stars Ter 5 I and EXO 0748-676. And the hybrid EOS with unpaired quark matter phase is allowed even compared with the tightest constraint from the most massive pulsar star PSR J0751+1807. Therefore, we conclude that the ground state of neutral matter at moderate densities is in deconfined quark phase likely.Comment: 13 pages, 4 figure

Liquid-gas phase transition in hot asymmetric nuclear matter with density-dependent relativistic mean-field models

The liquid-gas phase transition in hot asymmetric nuclear matter is studied within density-dependent relativistic mean-field models where the density dependence is introduced according to the Brown-Rho scaling and constrained by available data at low densities and empirical properties of nuclear matter. The critical temperature of the liquid-gas phase transition is obtained to be 15.7 MeV in symmetric nuclear matter falling on the lower edge of the small experimental error bars. In hot asymmetric matter, the boundary of the phase-coexistence region is found to be sensitive to the density dependence of the symmetry energy. The critical pressure and the area of phase-coexistence region increases clearly with the softening of the symmetry energy. The critical temperature of hot asymmetric matter separating the gas phase from the LG coexistence phase is found to be higher for the softer symmetry energy.Comment: To be published in Phys. Lett.

Dirac-Brueckner Hartree-Fock Approach: from Infinite Matter to Effective Lagrangians for Finite Systems

One of the open problems in nuclear structure is how to predict properties of finite nuclei from the knowledge of a bare nucleon-nucleon interaction of the meson-exchange type. We point out that a promising starting point consists in Dirac-Brueckner-Hartree-Fock (DBHF) calculations us- ing realistic nucleon-nucleon interactions like the Bonn potentials, which are able to reproduce satisfactorily the properties of symmetric nuclear matter without the need for 3-body forces, as is necessary in non-relativistic BHF calculations. However, the DBHF formalism is still too com- plicated to be used directly for finite nuclei. We argue that a possible route is to define effective Lagrangians with density-dependent nucleon-meson coupling vertices, which can be used in the Relativistic Hartree (or Relativistic Mean Field (RMF)) or preferrably in the Relativistic Hartree- Fock (RHF) approach. The density-dependence is matched to the nuclear matter DBHF results. We review the present status of nuclear matter DBHF calculations and discuss the various schemes to construct the self-energy, which lead to differences in the predictions. We also discuss how effective Lagrangians have been constructed and are used in actual calculations. We point out that completely consistent calculations in this scheme still have to be performed.Comment: 16 pages, to be published in Journal of Physics G: Nuclear and Particle Physics, special issue

Wolbachia and DNA barcoding insects: patterns, potential and problems

Wolbachia is a genus of bacterial endosymbionts that impacts the breeding systems of their hosts. Wolbachia can confuse the patterns of mitochondrial variation, including DNA barcodes, because it influences the pathways through which mitochondria are inherited. We examined the extent to which these endosymbionts are detected in routine DNA barcoding, assessed their impact upon the insect sequence divergence and identification accuracy, and considered the variation present in Wolbachia COI. Using both standard PCR assays (Wolbachia surface coding protein – wsp), and bacterial COI fragments we found evidence of Wolbachia in insect total genomic extracts created for DNA barcoding library construction. When >2 million insect COI trace files were examined on the Barcode of Life Datasystem (BOLD) Wolbachia COI was present in 0.16% of the cases. It is possible to generate Wolbachia COI using standard insect primers; however, that amplicon was never confused with the COI of the host. Wolbachia alleles recovered were predominantly Supergroup A and were broadly distributed geographically and phylogenetically. We conclude that the presence of the Wolbachia DNA in total genomic extracts made from insects is unlikely to compromise the accuracy of the DNA barcode library; in fact, the ability to query this DNA library (the database and the extracts) for endosymbionts is one of the ancillary benefits of such a large scale endeavor – for which we provide several examples. It is our conclusion that regular assays for Wolbachia presence and type can, and should, be adopted by large scale insect barcoding initiatives. While COI is one of the five multi-locus sequence typing (MLST) genes used for categorizing Wolbachia, there is limited overlap with the eukaryotic DNA barcode region

Nuclear and Neutron Matter Calculations with Different Model Spaces

In this work we investigate the so-called model-space Brueckner-Hartree-Fock (MBHF) approach for nuclear matter as well as for neutron matter and the extension of this which includes the particle-particle and hole-hole (PPHH) diagrams. A central ingredient in the model-space approach for nuclear matter is the boundary momentum $k_M$ beyond which the single-particle potential energy is set equal to zero. This is also the boundary of the model space within which the PPHH diagrams are calculated. It has been rather uncertain which value should be used for $k_M$. We have carried out model-space nuclear matter and neutron matter calculations with and without PPHH diagrams for various choices of $k_M$ and using several modern nucleon-nucleon potentials. Our results exhibit a saturation region where the nuclear and neutron matter matter energies are quite stable as $k_M$ varies. The location of this region may serve to determine an "optimum" choice for $k_M$. However, we find that the strength of the tensor force has a significant influence on binding energy variation with $k_M$. The implications for nuclear and neutron matter calculations are discussed.Comment: 24 pages, Elsevier LaTeX style, 17 figs include

Short-Range Correlations and the One-Body Density Matrix in Finite Nuclei

The effects of short-range correlations derived from a realistic meson-exchange potential on the single-particle density matrix in finite nuclei are investigated by analyzing the one-body density in terms of the natural orbits. Basic features of these natural orbits and their spectral distributions are discussed. For many observables it seems to be sufficient to approximate the one-body density matrix in terms of those natural orbits, which exhibit the largest occupation probabilities. For the investigation of the high-momentum components in the single-particle density, however, it is important to take into account natural orbits with small occupation probabilities, originating from the single-particle Green function at large negative energies.Comment: 13 pages, RevTeX, 5 figures adde

Cathepsin B-associated Activation of Amyloidogenic Pathway in Murine Mucopolysaccharidosis Type I Brain Cortex

Mucopolysaccharidosis type I (MPS I) is caused by genetic deficiency of alpha-l-iduronidase and impairment of lysosomal catabolism of heparan sulfate and dermatan sulfate. In the brain, these substrates accumulate in the lysosomes of neurons and glial cells, leading to neuroinflammation and neurodegeneration. Their storage also affects lysosomal homeostasis-inducing activity of several lysosomal proteases including cathepsin B (CATB). In the central nervous system, increased CATB activity has been associated with the deposition of amyloid plaques due to an alternative pro-amyloidogenic processing of the amyloid precursor protein (APP), suggesting a potential role of this enzyme in the neuropathology of MPS I. In this study, we report elevated levels of protein expression and activity of CATB in cortex tissues of 6-month-old MPS I (Idua -/- mice. Besides, increased CATB leakage from lysosomes to the cytoplasm of Idua -/- cortical pyramidal neurons was indicative of damaged lysosomal membranes. The increased CATB activity coincided with an elevated level of the 16-kDa C-terminal APP fragment, which together with unchanged levels of beta-secretase 1 was suggestive for the role of this enzyme in the amyloidogenic APP processing. Neuronal accumulation of Thioflavin-S-positive misfolded protein aggregates and drastically increased levels of neuroinflammatory glial fibrillary acidic protein (GFAP)-positive astrocytes and CD11b-positive activated microglia were observed in Idua -/- cortex by confocal fluorescent microscopy. Together, our results point to the existence of a novel CATB-associated alternative amyloidogenic pathway in MPS I brain induced by lysosomal storage and potentially leading to neurodegeneration

Generalized entropy and temperature in nuclear multifragmentation

In the framework of a 2D Vlasov model, we study the time evolution of the "coarse-grained" Generalized Entropy (GE) in a nuclear system which undergoes a multifragmentation (MF) phase transition. We investigate the GE both for the gas and the fragments (surface and bulk part respectively). We find that the formation of the surface causes the growth of the GE during the process of fragmentation. This quantity then characterizes the MF and confirms the crucial role of deterministic chaos in filling the new available phase-space: at variance with the exact time evolution, no entropy change is found when the linear response is applied. Numerical simulations were used also to extract information about final temperatures of the fragments. From a fitting of the momentum distribution with a Fermi-Dirac function we extract the temperature of the fragments at the end of the process. We calculate also the gas temperature by averaging over the available phase space. The latter is a few times larger than the former, indicating a gas not in equilibrium. Though the model is very schematic, this fact seems to be very general and could explain the discrepancy found in experimental data when using the slope of light particles spectra instead of the double ratio of isotope yields method in order to extract the nuclear caloric curve.Comment: 26 pages, 9 postscript figures included, Revtex, some figures and part of text changed, version accepted for publication in PR

Room temperature triplet state spectroscopy of organic semiconductors

Organic light-emitting devices and solar cells are devices that create, manipulate, and convert excited states in organic semiconductors. It is crucial to characterize these excited states, or excitons, to optimize device performance in applications like displays and solar energy harvesting. This is complicated if the excited state is a triplet because the electronic transition is ‘dark’ with a vanishing oscillator strength. As a consequence, triplet state spectroscopy must usually be performed at cryogenic temperatures to reduce competition from non-radiative rates. Here, we control non-radiative rates by engineering a solid-state host matrix containing the target molecule, allowing the observation of phosphorescence at room temperature and alleviating constraints of cryogenic experiments. We test these techniques on a wide range of materials with functionalities spanning multi-exciton generation (singlet exciton fission), organic light emitting device host materials, and thermally activated delayed fluorescence type emitters. Control of non-radiative modes in the matrix surrounding a target molecule may also have broader applications in light-emitting and photovoltaic devices.United States. Dept. of Energy. Center for Excitonics (Award DE-SC0001088