HD 174005: another binary classified as lambda Boo

We demonstrate that HD 174005, a star recently classified as belonging to the lambda Boo group, is in reality a double lined spectroscopic binary; at some phases, the observed composite spectrum may be similar to that of a single star with weak metal lines.Comment: Accepted by A&

The Latin Leaflet, Number 29

Polymer electrolytes represent the ultimate in terms of desirable properties of energy storage/conversion devices, as they can offer an all-solid-state construction, a wide variety of shapes and sizes, light-weight, low costs, high energy density and safety. Here we present our recent results concerning a novel strategy for preparing efficient polymer membranes which are successfully demonstrated as suitable electrolytes for several energy conversion and storage devices (i.e., Li- and Na-based batteries and DSSCs). Highly ionic conducting polymer electrolytes containing PEO-based functionalities and different components (e.g., Li/Na salts, RTILs, natural biosourced and cellulosic fillers) are successfully prepared via a rapid process and, directly or subsequently, cross-linked via UV irradiation (patent pending, PCT/IT2014/000008). All the prepared materials are thoroughly characterised in terms of their physical, chemical and morphological properties and tested for their electrochemical performances and durability. The UV-curing process on such materials led to the production of elastic and resistant amorphous macromolecular networks. Noticeably increased ionic conductivities are registered (10-3 S cm-1 at RT), along with very stable interfacial and storage stability and wide electrochemical stability windows. The different lab-scale solid-state devices show remarkable performances even at ambient temperature, at the level of those using liquid electrolytes, respect to which demonstrate much greater durability and safety. The obtained findings demonstrate a new, easy and low cost approach to fabricate and tailor-make polymer electrolytes with highly promising prospects for the next generation of advanced flexible energy production and storage devices

Carrier mobility and scattering lifetime in electric double-layer gated few-layer graphene

We fabricate electric double-layer field-effect transistor (EDL-FET) devices on mechanically exfoliated few-layer graphene. We exploit the large capacitance of a polymeric electrolyte to study the transport properties of three, four and five-layer samples under a large induced surface charge density both above and below the glass transition temperature of the polymer. We find that the carrier mobility shows a strong asymmetry between the hole and electron doping regime. We then employ ab-initio density functional theory (DFT) calculations to determine the average scattering lifetime from the experimental data. We explain its peculiar dependence on the carrier density in terms of the specific properties of the electrolyte we used in our experiments.Comment: 6 pages, 3 figure

Spectra of binaries classified as lambda Boo stars

High angular resolution observations have shown that some stars classified as lambda Boo are binaries with low values of angular separation and magnitude difference of the components; therefore the observed spectrum of these objects is a combination of those of the two components. These composite spectra have been used to define spectroscopic criteria able to detect other binaries among stars classified as lambda Boo. The application of this method to HD 111786 is presented: the contribution of 5 components to the observed spectrum is demonstrated by the shape of the O I 7774 Angstrom feature. This result makes unreliable any attempt to perform an abundance analysis of this object which therefore must be definitely rejected from the class of the peculiar lambda Boo stars. This approach allowed us also to recognize that the SB2 star HD 153808 is in reality a triple system.Comment: Accepted for publication by A&

On the impact of electrolyte temperature on contact glow discharge electrolysis

This study aims at disclosing the effect of small temperature drops (10-15 degrees C) of the electrolyte on Contact Glow Discharge Electrolysis (CGDE). In our experiments, we measure the temperature change of electrolyte and electrode as well as the change in current following on from the addition of, first, frozen and, second, boiling KOH aqueous solution (0.1 M). Quite surprisingly, only the addition of frozen KOH aqueous solution has a significant impact on current (+130%), caused by the decrease in electrolyte temperature (-11 degrees C). In contrast, the addition of boiling KOH aqueous solution has a negligible effect on current. A very similar behavior is recorded when frozen or boiling type III deionized water is used: the addition of ice has an even stronger impact on current (+145 %) and on electrolyte temperature (-14 degrees C), while adding boiling water has no measurable effect. Thus, we here demonstrated that electrolyte temperature is critical for managing the responsiveness of the CGDE system. Our results pave the way toward temperature controlled CGDE, a powerful tool for a greener and a more efficient environmental chemistry

Lambda Boo stars with composite spectra

We examine the large sample of lambda Boo candidates collected in Table 1 of Gerbaldi et al. (2003) to see how many of them show composite spectra. Of the 132 lambda Boo candidates we identify 22 which definitely show composite spectra and 15 more for which there are good reasons to suspect a composite spectrum. The percentage of lambda Boo candidates with composite spectra is therefore > 17 and possibly considerably higher. For such stars the lambda Boo classification should be reconsidered taking into account the fact that their spectra are composite. We argue that some of the underabundances reported in the literature may simply be the result of the failure to consider the composite nature of the spectra. This leads to the legitimate suspicion that some, if not all, the lambda Boo candidates are not chemically peculiar at all. A thorough analysis of even a single one of the lambda Boo candidates with composite spectra, in which the composite nature of the spectrum is duly considered, which would demonstrate that the chemical peculiarities persist, would clear the doubt we presently have that the stars with composite spectra may not be lambda Boo at all.Comment: Accepted for publication by A&A on June 3rd 200

Rotational velocities of A-type stars I. Measurement of vsini in the southern hemisphere

Within the scope of a Key Programme determining fundamental parameters of stars observed by HIPPARCOS, spectra of 525 B8 to F2-type stars brighter than V=8 have been collected at ESO. Fourier transforms of several line profiles in the range 4200-4500 A are used to derive vsini from the frequency of the first zero. Statistical analysis of the sample indicates that measurement error is a function of vsini and this relative error of the rotational velocity is found to be about 6% on average. The results obtained are compared with data from the literature. There is a systematic shift from standard values from Slettebak et al. (1975), which are 10 to 12% lower than our findings. Comparisons with other independent vsini values tend to prove that those from Slettebak et al. are underestimated. This effect is attributed to the presence of binaries in the standard sample of Slettebak et al., and to the model atmosphere they used.Comment: 17 pages, includes 18 figures, accepted in A&

Li1.4Al0.4Ge0.4Ti1.4(PO4)3 promising NASICON-structured glass-ceramic electrolyte for all-solid-state Li-based batteries: Unravelling the effect of diboron trioxide

Li-ion batteries (LIBs) are the ubiquitous technology to power portable electronics; however, for the next-generation of high-performing electrochemical energy storage systems for electric vehicles and smart grid facilities, breakthroughs are needed, particularly in the development of solid-state electrolytes, which may allow for enhanced energy density while enabling lithium metal anodes, combined with unrivalled safety and operative reliability. In this respect, here we present the successful synthesis of a glass-ceramic Li1.4Al0.4Ge0.4Ti1.4(PO4)3 NASICON-type solid-state electrolyte (SSE) through a melt-casting technique. Being grain boundaries crucial for the total ionic conductivity of SSEs, the effect of the addition of diboron trioxide (B2O3, 0.05 wt.%) to promote their liquefaction and restructuring is investigated, along with the effects on the resulting microstructures and ionic conductivities. By the thorough combination of structural-morphological and electrochemical techniques, we demonstrate that bulk materials show improved performance compared to their powder sintered counterpart, achieving remarkable ion mobility (> 0.1 mS cm–1 at –10 °C) and anodic oxidation stability (> 4.8 V vs Li+/Li). The addition of B2O3 positively affects the grain cohesion and growth, thus reducing the extension of the grain boundaries (and the related grain/grain interface resistance) and, therefore, increasing the overall ion mobility. In addition, B2O3 is seen to contrast the microcracks formation in the LAGTP system under study which, overall, shows very promising prospects as SSE for the next-generation of high-energy density, safe lithium-based batteries