Organic Molecules in the Galactic Center. Hot Core Chemistry without Hot Cores

We study the origin of large abundances of complex organic molecules in the Galactic center (GC). We carried out a systematic study of the complex organic molecules CH3OH, C2H5OH, (CH3)2O, HCOOCH3, HCOOH, CH3COOH, H2CO, and CS toward 40 GC molecular clouds. Using the LTE approximation, we derived the physical properties of GC molecular clouds and the abundances of the complex molecules.The CH3OH abundance between clouds varies by nearly two orders of magnitude from 2.4x10^{-8} to 1.1x10^{-6}. The abundance of the other complex organic molecules relative to that of CH3OH is basically independent of the CH3OH abundance, with variations of only a factor 4-8. The abundances of complex organic molecules in the GC are compared with those measured in hot cores and hot corinos, in which these complex molecules are also abundant. We find that both the abundance and the abundance ratios of the complex molecules relative to CH3OH in hot cores are similar to those found in the GC clouds. However, hot corinos show different abundance ratios than observed in hot cores and in GC clouds. The rather constant abundance of all the complex molecules relative to CH3OH suggests that all complex molecules are ejected from grain mantles by shocks. Frequent (similar 10^{5}years) shocks with velocities >6km/s are required to explain the high abundances in gas phase of complex organic molecules in the GC molecular clouds. The rather uniform abundance ratios in the GC clouds and in Galactic hot cores indicate a similar average composition of grain mantles in both kinds of regions. The Sickle and the Thermal Radio Arches, affected by UV radiation, show different relative abundances in the complex organic molecules due to the differentially photodissociation of these molecules.Comment: 18 pages, 10 Postscript figures, uses aa.cls, aa.bst, 10pt.rtx, natbib.sty, revsymb.sty revtex4.cls, aps.rtx and aalongtabl.sty. Accepted in A&A 2006. version 2. relocated figures and tables. Language editor suggestions. added reference

Struggles and pacification in the history of american kinesiology

En este artículo estudiamos la disputa epistemológica y pedagógica sobre la kinesiología/educación física que ha tenido lugar en las universidades de Estados Unidos desde 1990 hasta la actualidad. Hemos recogido el pensamiento de una muestra amplia de autores involucrados, con el propósito de obtener una visión de conjunto de un proceso que, de acuerdo con Morrow (2006), trata de esclarecer ¿de dónde venimos?, ¿qué somos?, ¿a dónde vamos? Tras el cotejo y análisis de la documentación más relevante concluimos que el periodo 1990-2013, caracterizado por una enconada pugna de paradigmas –en la que han estado implicados humanistas, positivistas, crosdisciplinaristas y subdisciplinaristas–, ha dado como resultado el dominio del paradigma integrador de Kretchmar (2007, 2008)In this article we review the epistemological and pedagogical debate on Kinesiology and Physical Education that has been going on in the universities of the US from 1990 to the present. We have compiled the opinions of a wide sample of authors, with the intention of getting the most complete picture of a process that, according to Morrow (2006), seeks to answer the questions "where we come from, who we are, and where we are going". After comparing and analysing the most relevant documents, we conclude that the period 1990-2013, characterized by a bitter struggle between paradigms fought by humanists, positivists, cross-disciplinarists, and sub-disciplinarists, has revealed the eventual predominance of the integrative paradigm of Kretchmar (2007, 2008

Culture of paso de la amada, creator of ‘mesoamerican ballgame’

Se realiza una revisión sobre el origen del juego de pelota mesoamericano en el preclásico temprano (ca.1.700-1.000 a.C.). Por la antigüedad propuesta para sus vestigios sobre el juego de pelota, son candidatos a ser los ‘creadores del juego’ las culturas de Paso de la Amada, los pre-olmecas de San Lorenzo y El Opeño. Los vestigios referidos son fundamentalmente, la cancha de Paso de la Amada, las pelotas de hule de Manatí y las figurillas de El Opeño. Se concluye que la gran cancha de Paso de la Amada, la mayor construcción de Mesoamérica de su tiempo, aparece como el vestigio más antiguo del juego, y se le relaciona con la aparición de la primera sociedad no igualitaria en Mesoamérica. Se sugiere que los pobladores de Paso de la Amada, hacia 1650 a.C., fueron los creadores del juego y no los olmecas como generalmente se ha defendidoWe study here the origin of the Mesoamerican ballgame during the early formative period (ca. 1700 B.C.). We select as candidates for the creators of the Mesoamerican ballgame the cultures of Paso de la Amada, pre-Olmec at San Lorenzo, and El Opeño, as they have the oldest vestiges of the ballgame. These vestiges are, to be exact, a ball court at Paso de la Amada, some rubber balls at Manati, and ceramic figurines at El Opeño. We conclude that the great ball court at Paso de la Amada, the biggest building of Mesoamerica at that time, appears as the oldest vestige of the game and it is in relation with the emergence of ranked societies in Mesoamerica. We suggest that the people of Paso de la Amada, around 1650 BC, were the creators of the game, and not the Olmecs, as generally defende

Effect of dopants on the structure of titanium oxide used as a photocatalyst for the removal of emergent contaminants

Photocatalysts composed of titanium dioxide modified with B, F, N and P have been synthesized, characterized and applied to the degradation of caffeine, diclofenac, ibuprofen and salicylic acid. The modified TiO2 samples were prepared by the sol–gel technique starting from titanium(IV) isopropoxide and using H3BO3, NH4F, N(C2H5OH)3 and H3PO4 as precursors of the modifiers, with the content varying between 0 and 5 wt%. Structural characterization was based on nitrogen physisorption at −196 °C, powder X-ray diffraction (PXRD), simultaneous thermogravimetric/differential thermal analysis (TG/DTA) and X-ray photoelectron spectroscopy (XPS). The structural properties of the modified TiO2 solids were significantly different depending on the nature and amount of modifiers and the calcination temperature. TiO2 in the anatase phase was obtained in all cases and was stable upon calcination at 400 °C. The photocatalytic degradation of caffeine, diclofenac, ibuprofen and salicylic acid by modified TiO2 was investigated under ultraviolet irradiation at 25 °C. The photocatalytic degradation behavior followed the order: caffeine > diclofenac = ibuprofen > salicylic acid. B-doped TiO2 was the most efficient catalyst in the degradation of these selected emerging contaminants

Kinematic and dynamic array of the alpine deformations in alto Tajo area (Guadalajara)

The geological macrostructure of Alto Tajo is defined by several N1500E dextral strike-slip faults with related secundary structures. The former set of faults together with others N-S sinistral strike-slip faults delimited areas in transtension and transpession. Four tectonic phases have been detected by means of microstructural analysis: N600E compression; N1500E compression (the main deformation phase). N-S compression, without important structures asociated and a last episode of radial extension.Depto. de Geodinámica, Estratigrafía y PaleontologíaFac. de Ciencias GeológicasFALSEpu

On the heating of source of the Orion KL hot core

We present images of the J=10-9 rotational lines of HC3N in the vibrationally excited levels 1v7, 1v6 and 1v5 of the hot core (HC) in Orion KL. The images show that the spatial distribution and the size emission from the 1v7 and 1v5 levels are different. While the J=10-9 1v7 line has a size of 4''x 6'' and peaks 1.1'' NE of the 3 mm continuum peak, the J=10--9 1v5 line emission is unresolved (<3'') and peaks 1.3'' south of the 3 mm peak. This is a clear indication that the HC is composed of condensations with very different temperatures (170 K for the 1v7 peak and $>230$ K for the 1v5 peak). The temperature derived from the 1v7 and 1v5 lines increases with the projected distance to the suspected main heating source I. Projection effects along the line of sight could explain the temperature gradient as produced by source I. However, the large luminosity required for source I, >5 10^5 Lsolar, to explain the 1v5 line suggests that external heating by this source may not dominate the heating of the HC. Simple model calculations of the vibrationally excited emission indicate that the HC can be internally heated by a source with a luminosity of 10^5 Lsolar, located 1.2'' SW of the 1v5 line peak (1.8'' south of source I). We also report the first detection of high-velocity gas from vibrationally excited HC3N emission. Based on excitation arguments we conclude that the main heating source is also driving the molecular outflow. We speculate that all the data presented in this letter and the IR images are consistent with a young massive protostar embedded in an edge-on disk.Comment: 13 pages, 3 figures, To be published in Ap.J. Letter

Paleoseismological analysis of late Miocene lacustrine successions in the Prebetic Zone, SE Spain

El estudio paleosismológico en las cuencas neógenas (Mioceno superior) lacustres del Prebético de Albacete ha sido abordado mediante un enfoque multidisciplinar para poder extrapolar los datos paleosímicos a la actualidad. Dicho enfoque integra las siguientes disciplinas: estratigrafía, análisis estructural, análisis de la sismicidad y paleosismología. El estudio paleosismológico se ha realizado en depósitos de facies someras y profundas, ya que los sedimentos de ambas zonas presentan un comportamiento diferente frente a la deforrmación. Las sismitas localizadas en sedimentos someros fueron generadas por fenómenos de licuefacción y son: diques de arena, estructuras en almohadilla y licuefacción y fracturación en gr avas. Las zonas profundas presentan estructuras más diversas: loop bedding, alteración de la estructura planar de va rvas, niveles de mezcla y pseudonódulos. Las sismitas estudiadas se pueden utilizar como indicadores de intervalos de magnitudes sísmicas. Las estructuras se orientan sistemáticamente según los campos de esfuerzo reciente y actual (que se mantienen desde el Mioceno superior hasta la actualidad): NW-SE y NE-SW. Éste es un punto que permite relacionar genéticamente la tectónica y las sismitas. Se ha utilizado el carácter anual de la sedimentación va rvada para datar de forma relativa las estructuras y establecer periodos de recurrencia de paleoterremotos. El intervalo de recurrencia medio está próximo a los 130 años (9.446 años de registro total y 73 eventos datados), el intervalo máximo es de 454 años y el mínimo de 23 años y la magnitud media estimada es de 5,1. Se ha aplicado la ley de Gutenberg-Richter a los datos paleosísmicos y de sismicidad actual y se obtienen valores del parámetro "b" muy similares, próximos a 0,86. Todas estas premisas indican que las condiciones de la sismicidad en el Mioceno superior fueron muy similares a las actuales.A paleoseismological study of late Miocene lacustrine sediments was carried out in the Neogene basins of the Prebetic Zone in Albacete (Spain). We developed a multidisciplinary methodology which could be used to extrapolate the paleoseismic data to the present day. This multidisciplinary approach includes different disciplines, i.e. stratigraphy, structural analysis, seismological analysis and paleoseismology. Paleoseismological analysis was focussed on both shallow and deep lake deposits given that these sediments behave differently in different deformation fields. The seismites formed in shallow sediments were generated by liquefaction and include: sand dikes, pillow structures and intruded and fractured gr avels. The deep lake deposits show varied structures, such as loop bedding, disturbed varved lamination, mixed layers and pseudonodules. Seismites indicate paleoearthquake magnitude intervals. The trends of the seismites are usually oriented ve ry close to the stress field trends (from the late Miocene to the Present): NW-SE and NE-SW trends. This constitutes a link between tectonics and seismites. The va rved annual sedimentation evidenced by the deep lake facies was used as a relative dating method. Mixed layers were employed as paleoseismic indicators to calculate the earthquake recurrence interval. The mean recurrence interval is close to 130 years (9446 years of total record with 73 dated events), one maximum interval of 454 years and one minimum interval of 23 years and the mean estimated magnitude value is 5.1. The Gutenberg-Richter relationship shows similar "b" values close to 0.86 from paleoseismological and seismological data. This suggests that the seismic conditions have been similar since the late Miocene

Feeding with Badly Preserved Silages and Occurrence of Subclinical Ketosis in Dairy Cows

Ketosis in dairy cows is due to high levels of circulating ketone bodies in blood (Duffiel, 2000). In early lactation, the capacity of voluntary dry matter intake does not allow dairy cows to cover the total energy requirements for maintenance and production, and then the body reserves are mobilised. However, the amounts of fatty acids that can be metabolised in the liver are limited, later they are converted to ketone bodies (Tveit et al., 1992). During forage ensiling, acetic and lactic fermentations only are desirable, but frequently butyric and alcoholic fermentations appear. When the animals ingest these silages, the butyric acid is metabolised to ketone bodies (Chalupa, 1974). The ketosis problems could be due to both causes simultaneously. The objective of this paper was to establish the incidence of subclinical ketosis in dairy herds of Asturias (Spain) and its relationship with the nutritive and fermentative characteristics of silages used in the ration

Recreational water skiing in people with paraplegia: A study of three cases

Objetivos: se analizaron la condición cardiorrespiratoria y la intensidad de esfuerzo durante la práctica recreativa del esquí náutico de slalom. Metodología: participaron tres esquiadores náuticos con paraplejia moderadamente activos. Realizaron un test incremental en un ergómetro de brazos para determinar su VO2pico y los umbrales ventilatorios y completaron 3 sesiones de práctica de esquí náutico, separadas por 48h, registrándose la FC cada 5 s. Resultados: obtuvieron un VO2pico de 22,3 ± 0,6 mL·kg-1·min-1 y los umbrales ventilatorios se analizaron al ~80 y ~50% del VO2pico. La FC media en las sesiones de esquí náutico fue de 111 ppm, lo que representó una intensidad de ~45% de la FC de reserva (FCR), permaneciendo por encima del 40% de la FCR ~12 min. Conclusión: la intensidad moderada de la práctica recreativa de esquí náutico de slalom podría servir para mantener o mejorar la condición cardiorrespiratoria en estas tres personas con paraplejiaObjectives: the cardiorespiratory fitness and the intensity of effort were analyzed during the recreational practice of slalom water skiing. Methodology: three moderately active water skiers with paraplegia participated. They performed an incremental test on an arm ergometer to determine their VO2peak and ventilatory thresholds and completed 3 sessions of water skiing, separated by 48h, where the HR was recorded every 5 s. Results: they obtained a VO2peak of 22.3 ± 0.6 mL·kg-1·min-1 and the ventilatory thresholds were analyzed at ~80 and ~50% of the VO2peak. The average heart rate in the water ski sessions was 111 bpm, which represented an intensity of ~45% of the heart rate reserve (HRR), remaining above 40% of the HRR ~12 min. Conclusion: the moderate intensity of recreational slalom skiing could serve to maintain or improve the cardiorespiratory fitness in these three people with paraplegi

Contraste de las formulaciones existentes para la estimación de la tasa de rebase en diques de abrigo portuario

The research that is summarized in this article, resultant of diverse studies realized in the CEDEX, has for object a comparative analysis of methods of overtopping rates developed by different authors. For that, the summary was realized first and the analysis of the existing formulations to estimate the rate of overtopping on rubble mound and vertical breakwaters. Later, there was carried out the contrast of the above mentioned formulations by the results obtained in two hydraulic model tests of the Hydraulic Research Laboratory (Center of Studies of Ports and Coasts of the CEDEX, Madrid, Spain)