Dynamical Monte Carlo Study of Equilibrium Polymers : Static Properties

We report results of extensive Dynamical Monte Carlo investigations on self-assembled Equilibrium Polymers (EP) without loops in good solvent. (This is thought to provide a good model of giant surfactant micelles.) Using a novel algorithm we are able to describe efficiently both static and dynamic properties of systems in which the mean chain length \Lav is effectively comparable to that of laboratory experiments (up to 5000 monomers, even at high polymer densities). We sample up to scission energies of $E/k_BT=15$ over nearly three orders of magnitude in monomer density $\phi$, and present a detailed crossover study ranging from swollen EP chains in the dilute regime up to dense molten systems. Confirming recent theoretical predictions, the mean-chain length is found to scale as \Lav \propto \phi^\alpha \exp(\delta E) where the exponents approach $\alpha_d=\delta_d=1/(1+\gamma) \approx 0.46$ and $\alpha_s = 1/2 [1+(\gamma-1)/(\nu d -1)] \approx 0.6, \delta_s=1/2$ in the dilute and semidilute limits respectively. The chain length distribution is qualitatively well described in the dilute limit by the Schulz-Zimm distribution \cN(s)\approx s^{\gamma-1} \exp(-s) where the scaling variable is s=\gamma L/\Lav. The very large size of these simulations allows also an accurate determination of the self-avoiding walk susceptibility exponent $\gamma \approx 1.165 \pm 0.01$. ....... Finite-size effects are discussed in detail.Comment: 15 pages, 14 figures, LATE

Estimation of sea-surface temperature around southern Africa from satellite-derived microwave observations

Sea-surface temperatures may give strong indications of the location of fronts, currents, eddies and other components of ocean circulation. This has been recognized in particular for the seas around southern Africa. Almost all studies using this property have employed measurements of thermal infrared radiation from orbiting satellites. This has distinct disadvantages due to the shading effect of persistent cloud cover. Another option is to use microwave observations, which are not affected by cloud cover. Until recently, however, the spatial resolution of microwave data was far too coarse for the purpose of studying ocean circulation in detail. We describe here a new set of microwave data that does not have this disadvantage, and show how useful it is by describing examples of local applications

Wind changes above warm Agulhas Current eddies

Sea surface temperature (SST) estimated from the Advanced Microwave Scanning Radiometer E onboard the Aqua satellite and altimetry-derived sea level anomalies are used south of the Agulhas Current to identify warm-core mesoscale eddies presenting a distinct SST perturbation greater than to 1 °C to the surrounding ocean. The analysis of twice daily instantaneous charts of equivalent stability-neutral wind speed estimates from the SeaWinds scatterometer onboard the QuikScat satellite collocated with SST for six identified eddies shows stronger wind speed above the warm eddies than the surrounding water in all wind directions, if averaged over the lifespan of the eddies, as was found in previous studies. However, only half of the cases showed higher wind speeds above the eddies at the instantaneous scale; 20 % of cases had incomplete data due to partial global coverage by the scatterometer for one path. For cases where the wind is stronger above warm eddies, there is no relationship between the increase in surface wind speed and the SST perturbation, but we do find a linear relationship between the decrease in wind speed from the centre to the border of the eddy downstream and the SST perturbation. SST perturbations range from 1 to 6 °C for a mean eddy SST of 15.9 °C and mean SST perturbation of 2.65 °C. The diameter of the eddies range from 100 to 250 km. Mean background wind speed is about 12 m s−1 (mostly southwesterly to northwesterly) and ranging mainly from 4 to 16 m s−1. The mean wind increase is about 15 %, which corresponds to 1.8 m s−1. A wind speed increase of 4 to 7 m s−1 above warm eddies is not uncommon. Cases where the wind did not increase above the eddies or did not decrease downstream had higher wind speeds and occurred during a cold front associated with intense cyclonic low-pressure systems, suggesting certain synoptic conditions need to be met to allow for the development of wind speed anomalies over warm-core ocean eddies. In many cases, change in wind speed above eddies was masked by a large-scale synoptic wind speed deceleration/acceleration affecting parts of the eddies

Southern African summer-rainfall variability, and its teleconnections, on interannual to interdecadal timescales in CMIP5 models

23 pagesInternational audienceThis study provides the first assessment of CMIP5 model performances in simulating southern Africa (SA) rainfall variability in austral summer (Nov–Feb), and its teleconnections with large-scale climate variability at different timescales. Observed SA rainfall varies at three major timescales: interannual (2–8 years), quasi-decadal (8–13 years; QDV) and interdecadal (15–28 years; IDV). These rainfall fluctuations are, respectively, associated with El Niño Southern Oscillation (ENSO), the Interdecadal Pacific Oscillation (IPO) and the Pacific Decadal Oscillation (PDO), interacting with climate anomalies in the South Atlantic and South Indian Ocean. CMIP5 models produce their own variability, but perform better in simulating interannual rainfall variability, while QDV and IDV are largely underestimated. These limitations can be partly explained by spatial shifts in core regions of SA rainfall variability in the models. Most models reproduce the impact of La Niña on rainfall at the interannual scale in SA, in spite of limitations in the representation of ENSO. Realistic links between negative IPO are found in some models at the QDV scale, but very poor performances are found at the IDV scale. Strong limitations, i.e. loss or reversal of these teleconnections, are also noted in some simulations. Such model errors, however, do not systematically impact the skill of simulated rainfall variability. This is because biased SST variability in the South Atlantic and South Indian Oceans strongly impact model skills by modulating the impact of Pacific modes of variability. Using probabilistic multi-scale clustering, model uncertainties in SST variability are primarily driven by differences from one model to another, or comparable models (sharing similar physics), at the global scale. At the regional scale, i.e. SA rainfall variability and associated teleconnections, while differences in model physics remain a large source of uncertainty, the contribution of internal climate variability is increasing. This is particularly true at the QDV and IDV scales, where the individual simulations from the same model tend to differentiate, and the sampling error increase

How Local and Global Metacognition Shape Mental Health

Metacognition is the ability to reflect on our own cognition and mental states. It is a critical aspect of human subjective experience and operates across many hierarchical levels of abstraction—encompassing “local” confidence in isolated decisions and “global” self-beliefs about our abilities and skills. Alterations in metacognition are considered foundational to neurological and psychiatric disorders, but research has mostly focused on local metacognitive computations, missing out on the role of global aspects of metacognition. Here, we first review current behavioral and neural metrics of local metacognition that lay the foundation for this research. We then address the neurocognitive underpinnings of global metacognition uncovered by recent studies. Finally, we outline a theoretical framework in which higher hierarchical levels of metacognition may help identify the role of maladaptive metacognitive evaluation in mental health conditions, particularly when combined with transdiagnostic methods

Sea-surface temperatures at the sub-Antarctic islands Marion and Gough during the past 50 years

Sea-surface temperatures (SSTs) have been measured at Marion and Gough islands for nearly 50 years. These are some of the longest records of their kind in the sub-Antarctic. We present the trend, the seasonal cycle, and the time-frequency characteristics of the SST for both islands, which rose by 1.4°C at Marion Island and by 0.5°C at Gough Island over the 50-year period. Intermittent temperature oscillations, with periods of between 1 and 5 years, were observed throughout the record. A 5-year periodicity, compatible with an Antarctic CircumpolarWave signature, dominated after 1990 in both records. We also observed a strong low-frequency component with a period varying from 9.3 to 11.4 years at Marion Island, and a much weaker component with a period varying from 9.9 to 11.8 years at Gough Island