Boradiazaindacene (Bodipy)-based building blocks for the construction of energy transfer cassettes

Cataloged from PDF version of article.Energy transfer cassettes composed entirely of boradiazaindacene (Bodipy) units were designed and synthesized to capture photonic energy and convert it to longer wavelength fluorescence emission. The new energy transfer systems obtained by simple condensation reactions are capable of elaborating efficient energy transfer from donor Bodipy units to the distyryl-Bodipy acceptor. (C) 2009 Elsevier Ltd. All rights reserved

A new surgical technique to facilitate osteochondral autograft transfer in osteochondral defects of the capitellum: A case report

A 17-year-old boy who was engaged in amateur weightlifting and body building presented with complaints of right elbow pain and limitation in elbow range of motion. Plain x-rays and magnetic resonance imaging showed an osteochondral defect in the medial third of the capitellum. At surgery, as a new technique, the lateral collateral ligament was detached from the humeral attachment to provide access to the capitellum with a clear and perpendicular exposure. Following removal of loose fragments within the joint, an osteochondral graft harvested from the lateral femoral condyle was implanted to the defect area of the capitellum. Postoperative radiologic controls showed that the defect was entirely filled by the graft with appropriate graft height. On follow-up examination at 12 months, the patient did not have any complaint about his elbow, and had no limitation of movement compared to the left elbow. Magnetic resonance imaging showed that the graft was successfully adapted to the recipient site without any sign of loosening. At final follow-up 40 months after surgery, the surface of the articular cartilage appeared normal. The range of elbow motion was preserved and the patient had no restriction in daily and sports activities. Considering technical difficulties posed by the narrow and complex structure of the elbow joint, this new technique involving detachment of the lateral collateral ligament facilitates perpendicular implantation of the graft. In our opinion, utilization of this new technique will improve functional and radiological results of osteochondral autograft transfer. © 2010 Turkish Association of Orthopaedics and Traumatology

Chromogenic and Fluorogenic Sensing of Biological Thiols in Auqeous Solutions Using BODIPY-Based Reagents

Cataloged from PDF version of article.udicious design of BODIPY dyes carrying nitroethenyl substituents in conjugation with the BODIPY core yields dyes that respond to biological thiols by both absorbance and emission changes. Incorporation of solubilizing ethyleneglycol units ensures water solubility. The result is bright signaling of biologically relevant thiols in the longer wavelength region of the visible spectrum and in aqueous solutions

Effect of corn particle size and inclusion of organic acid in the diet on growth performance and gastrointestinal structure in young chicks.

The effect of 3 corn particle sizes (dgw: 375, 1117, and 2402 μm) combined with or without organic acids (0.3 g/kg of Galliacid S®) was investigated on broilers from day 1 to day 21; 540 1-day old Ross 708 males were raised in 36 pens (3x2 factorial design, 6 blocks each). We measured: body weight, feed intake, feed conversion ratio, liver weight, pH weight and height of empty gizzard, pH and length of intestine and caeca, height and width of ileal villi, crypt depth/gland diameter, total bacteria count. Different corn particle sizes and organic acid supplements only affected feed intake (days 14 and 21), feed conversion ratio (day 14), villus height, and crypt depth. On day 21, fine milling had negative effects on body weights compared with larger feed particle size (816 vs 848 and 844 g); acidic additive had a positive effect on broiler growth (859 vs 813g). Length of small intestinal villi and crypt depth were affected by both particle size and organic acids (fine to coarse small intestinal villi: 1869a, 1401c, and 1039d μm in non-acidified; 1708b, 1535c, and 942e μm in acidified. Fine to coarse crypt depth: 102ab, 98b; 65c μm in non-acidified; 106a, 70c, and 66c μm in acidified). No difference was observed in total bacteria counts of the gut in relation to the different treatments. Use of organic acids during starter phase is useful, especially when the milling process is inappropriate

Optimal Placement of Multiple Interconnected Gateways in Heterogeneous Wireless Sensor Networks

Data c ollec ted b y sensors of ten h av e to b e rem otely d eliv ered th rou g h m u lti- h op w ireless path s to d ata sink s c onnec ted to applic ation ser v ers for inform ation proc essing . T h e position of th ese sink s h as a h u g e im pac t on th e q u ality of th e spec i c W ireless S ensor N etw or k ( W S N ) . Ind eed , it m ay c reate ar ti c ial traf c b ottlenec k s w h ic h affec t th e energ y ef c ienc y and th e W S N lifetim e. T h is paper c onsid ers a h eterog eneou s netw or k sc enar io w h ere w ireless sensors d eliv er d ata to inter m ed iate g atew ay s g eared w ith a d iv erse w ireless tec h nolog y and inter c onnec ted tog eth er and to th e sink . An optim iz ation f ram ew or k b ased on Integ er L inear P rog ram m ing (IL P ) is d ev eloped to loc ate w ireless g atew ay s m inim iz ing th e ov erall installation c ost and th e energ y c onsu m ption in th e W S N , w h ile ac c ou nting for m u lti- h op c ov erag e b etw een sensors and g atew ay s, and c onnec tiv ity am ong w ireless g atew ay s. T h e proposed IL P for m u lations are solv ed to optim ality for m ed iu m -siz e instanc es to analy z e th e q u ality of th e d esig ned netw or k s, and h eu r istic alg or ith m s are also proposed to tac k le larg e-sc ale h eterog eneou s sc enar ios

Mechanical and Tribological Properties of TiN Coatings Produced by PIII&D Technique

The structure, mechanical and tribological properties TiN coatings рroduced with PIII&D by using rectilinear filtered vacuum arc plasma system are present. The results of scratch testing and wear reciprocating testing clearly revealed the positive effect of pulse bias (0.5÷2.5 kV) application on tribological behavior of the TiN coatings in comparison the coatings deposited with DC bias (150 V). Application of pulsed bias potential leads to a significant reduction in the friction coefficient and increasing of coatings wear resistance due to a change in their structure. The orientation of crystal planes parallel to the surface changes from (111) to (220) with the application of pulse bias, which is accompanied by a transition from fibrous grains structure to denser columnar grains. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3518

First records of anomalously white harbour porpoises (Phocoena phocoena) in the Turkish seas with a global review

Dede, Ayhan/0000-0002-7712-615X; YESILCICEK, TUNCAY/0000-0002-3236-8227; Tonay, Arda M./0000-0003-2718-9328; Kose, Ozay/0000-0002-3565-160XWOS: 000320413100012Three anomalously white harbour porpoises (Phocoena phocoena) were reported in Turkish Seas. One of them was bycaught on 19 June 2011 in bottom gill nets off the eastern coast of the Turkish Black Sea. the second one was observed four times in May and early June 2012 in the Istanbul Strait. the last one was stranded alive on 7 July 2012 in the Istanbul Strait. Records (published and unpublished) of anomalously white harbour porpoises in the world were reviewed. in total, 34 records were found from the world seas: the Black Sea, North Sea, Baltic Sea, North Atlantic Ocean and North Eastern Pacific Ocean. According to these records, three patterns of pigmentation were suggested.Recep Tayym Erdogan UniversityRecep Tayyip Erdogan University [BAP 2010.103 03 2]; Istanbul UniversityIstanbul University [BAP 184761, BAP 27942]The authors thank S. Berrow, O K. Didockson, K. Flannery, PG H Evans, A. Gob, Z. Gunelidze, I Hasselmeier, L Hutchings, W Keener, C.C. Kinze, L Morison, S. Pezeril, D. Quigley, K Robinson, D. Schulte, R Sears, A. U for observation data and old photos, A. Beird for photos, A.E. Kutukcu for video in Istanbul Strait, E. Danyer and I Aytemiz for necropsy report, H Bayar for necropsy assistance, 13 Topaloglu for photos of case 3 and logistic, S. Akmermer, K Akmermer and U. Akmermer for help in Size, L Eadie, T de Haas, N. Tonay and Kirecburnu's fishermen in Istanbul, Coast Guard for cooperation in IU/TUDAV Cetacean Stranding Network; V. Onar and P.S C. Turetken for help in fixation case 3, P Korkmazel, K. Guzey/ANIMA for colour grading and video time warping, B. Ozturk, P Gol'din and D Fertl for their valuable advises; A A Ozturk, R. Bilgin, C. Torso for their contributions during editing Case I study was supported by Recep Tayym Erdogan University, Scientific Research Project (BAP 2010.103 03 2). Case 2 study was supported by Istanbul University, Scientific Research Pealed (BAP 184761 Case 3 preserving and exhibit was provided by Istanbul University, Scientific Research Project (BAP 27942

Performance Evaluation of Gradient Routing Strategies for Wireless Sensor Networks

International audienceWe consider Wireless Sensor Networks (WSN) applications in which sensors have to send data to a unique sink in a multi-hop fashion. Gradient routing protocol is a scalable way to route data in these applications. Many gradient routing protocols exist, they mainly differ in their performances (delay, delivery ratio, etc.). In this paper, we propose an extensive performance evaluation study of some gradient routing protocols in order to give guidelines for WSN developers

Design and synthesis of soluble dibenzosuberane-substituted fullerene derivatives for bulk-heterojunction polymer solar cells

Cataloged from PDF version of article.Two new dibenzosuberane-substituted fullerene derivatives, dibenzosuberane-C60 monoadduct (DBSCMA) and bis-adduct (DBSCBA) were synthesized using a classical cyclopropanation reaction via a tosylhydrazone route for application as acceptor materials in polymer solar cells (PSCs). DBSCBA shows good solubility in common organic solvents and both derivatives were characterized by 1HNMR, 13C NMR, MALD-TOF, elemental analysis and UV-vis absorption measurements. The shift of fullerene energy levels induced by the dibenzosuberane substitution was investigated by using theoretical simulations and ultraviolet photoelectron spectroscopy. Bulk-heterojunction PSCs based on poly (3-hexylthiophene) (P3HT) and dibenzosuberane-C60 derivatives were fabricated and optimized by adjusting the donor/acceptor ratio and using thermal annealing and solvent additive. The morphologies of the active layers processed under different conditions were also examined by atomic force microscopy. When tested under an illumination of AM 1.5 G at 100 mW/ cm2, the highest power conversion efficiency of the devices using DBSCBA is 3.70% which is superior to that of conventional P3HT:PCBM devices. © 2013 Elsevier B.V

Mechanical and Tribological Properties of TiN Coatings Produced by PIII&D Technique

The structure, mechanical and tribological properties TiN coatings рroduced with PIII&D by using rectilinear filtered vacuum arc plasma system are present. The results of scratch testing and wear reciprocating testing clearly revealed the positive effect of pulse bias (0.5÷2.5 kV) application on tribological behavior of the TiN coatings in comparison the coatings deposited with DC bias (150 V). Application of pulsed bias potential leads to a significant reduction in the friction coefficient and increasing of coatings wear resistance due to a change in their structure. The orientation of crystal planes parallel to the surface changes from (111) to (220) with the application of pulse bias, which is accompanied by a transition from fibrous grains structure to denser columnar grains. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3518