European climate response to tropical volcanic eruptions over the last half millennium

We analyse the winter and summer climatic signal following 15 major tropical volcanic eruptions over the last half millennium based on multi-proxy reconstructions for Europe. During the first and second post-eruption years we find significant continental scale summer cooling and somewhat drier conditions over Central Europe. In the Northern Hemispheric winter the volcanic forcing induces an atmospheric circulation response that significantly follows a positive NAO state connected with a significant overall warm anomaly and wetter conditions over Northern Europe. Our findings compare well with GCM studies as well as observational studies, which mainly cover the substantially shorter instrumental period and thus include a limited set of major eruptions

Summer heat waves over western Europe 1880-2003, their relationship to large-scale forcings and predictability

We investigate the large-scale forcing and teleconnections between atmospheric circulation (sea level pressure, SLP), sea surface temperatures (SSTs), precipitation and heat wave events over western Europe using a new dataset of 54 daily maximum temperature time series. Forty four of these time series have been homogenised at the daily timescale to ensure that the presence of inhomogeneities has been minimised. The daily data have been used to create a seasonal index of the number of heat waves. Using canonical correlation analysis (CCA), heat waves over western Europe are shown to be related to anomalous high pressure over Scandinavia and central western Europe. Other forcing factors such as Atlantic SSTs and European precipitation, the later as a proxy for soil moisture, a known factor in strengthening land-atmosphere feedback processes, are also important. The strength of the relationship between summer SLP anomalies and heat waves is improved (from 35%) to account for around 46% of its variability when summer Atlantic and Mediterranean SSTs and summer European precipitation anomalies are included as predictors. This indicates that these predictors are not completely collinear rather that they each have some contribution to accounting for summer heat wave variability. However, the simplicity and scale of the statistical analysis masks this complex interaction between variables. There is some useful predictive skill of summer heat waves using multiple lagged predictors. A CCA using preceding winter North Atlantic SSTs and preceding January to May Mediterranean total precipitation results in significant hindcast (1972-2003) Spearman rank correlation skill scores up to 0.55 with an average skill score over the domain equal to 0.28±0.28. In agreement with previous studies focused on mean summer temperature, there appears to be some predictability of heat wave events on the decadal scale from the Atlantic Multidecadal Oscillation (AMO), although the long-term global mean temperature is also well related to western European heat waves. Combining these results with the observed positive trends in summer continental European SLP, North Atlantic SSTs and indications of a decline in European summer precipitation then possibly these long-term changes are also related to increased heat wave occurrence and it is important that the physical processes controlling these changes be more fully understoo

The importance of ship log data: reconstructing North Atlantic, European and Mediterranean sea level pressure fields back to 1750

Local to regional climate anomalies are to a large extent determined by the state of the atmospheric circulation. The knowledge of large-scale sea level pressure (SLP) variations in former times is therefore crucial when addressing past climate changes across Europe and the Mediterranean. However, currently available SLP reconstructions lack data from the ocean, particularly in the pre-1850 period. Here we present a new statistically-derived 5°×5° resolved gridded seasonal SLP dataset covering the eastern North Atlantic, Europe and the Mediterranean area (40°W-50°E; 20°N-70°N) back to 1750 using terrestrial instrumental pressure series and marine wind information from ship logbooks. For the period 1750-1850, the new SLP reconstruction provides a more accurate representation of the strength of the winter westerlies as well as the location and variability of the Azores High than currently available multiproxy pressure field reconstructions. These findings strongly support the potential of ship logbooks as an important source to determine past circulation variations especially for the pre-1850 period. This new dataset can be further used for dynamical studies relating large-scale atmospheric circulation to temperature and precipitation variability over the Mediterranean and Eurasia, for the comparison with outputs from GCMs as well as for detection and attribution studie

The origin of the "European Medieval Warm Period"

Proxy records and results of a three dimensional climate model show that European summer temperatures roughly a millennium ago were comparable to those of the last 25 years of the 20th century, supporting the existence of a summer "Medieval Warm Period" in Europe. Those two relatively mild periods were separated by a rather cold era, often referred to as the "Little Ice Age". Our modelling results suggest that the warm summer conditions during the early second millennium compared to the climate background state of the 13th–18th century are due to a large extent to the long term cooling induced by changes in land-use in Europe. During the last 200 years, the effect of increasing greenhouse gas concentrations, which was partly levelled off by that of sulphate aerosols, has dominated the climate history over Europe in summer. This induces a clear warming during the last 200 years, allowing summer temperature during the last 25 years to reach back the values simulated for the early second millennium. Volcanic and solar forcing plays a weaker role in this comparison between the last 25 years of the 20th century and the early second millennium. Our hypothesis appears consistent with proxy records but modelling results have to be weighted against the existing uncertainties in the external forcing factors, in particular related to land-use changes, and against the uncertainty of the regional climate sensitivity. Evidence for winter is more equivocal than for summer. The forced response in the model displays a clear temperature maximum at the end of the 20th century. However, the uncertainties are too large to state that this period is the warmest of the past millennium in Europe during winter

A mild biomass pretreatment using gamma-valerolactone for concentrated sugar production

Here we report that gamma-valerolactone (GVL), a biomass-derived solvent, can be used to facilitate the mild pretreatment of lignocellulosic biomass. An 80% GVL, 20% water solvent system was used to pretreat hardwood at the mild temperature of 120 degrees C with an acid loading of 75 mM H2SO4. Up to 80% of original lignin was removed with 96-99% of original cellulose retained in the pretreated substrates. The use of a mild temperature and low acid concentrations caused negligible degradation of sugars. Up to 99% of the original glucan and 96% of the original xylan could be recovered after pretreatment. The pretreated substrate was quantitatively converted to sugars (99% and 100% total glucose and xylose yield) with an enzyme loading of 15 FPU g(-1) glucan. These digestibilities were three times higher than those obtained when using other organic solvents such as tetrahydrofuran or ethanol, and 20 times higher than when pure water was used during pretreatment. Over 99.5% of GVL could be recovered by liquid-CO2 extraction of the pretreated slurries while removing less than 1% of the sugars. This approach produced pretreatment slurries that could easily undergo high-solids (30% w/v) enzymatic hydrolysis without any substrate washing or drying. We obtained glucose and xylose yields of up to 90% and 97%, respectively, and generated sugar streams with sugar concentrations up to 182 g L-1

Projections of global changes in precipitation extremes from CMIP5 models

Precipitation extremes are expected to increase in a warming climate, thus it is essential to characterise their potential future changes. Here we evalu- ate eight high-resolution Global Climate Model simulations in the twenti- eth century and provide new evidence on projected global precipitation ex- tremes for the 21st century. A significant intensification of daily extremes for all seasons is projected for the mid and high latitudes of both hemispheres at the end of the present century. For the subtropics and tropics, the lack of reliable and consistent estimations found for both the historical and fu- ture simulations might be connected with model deficiencies in the repre- sentation of organised convective systems. Low inter-model variability and good agreement with high-resolution regional observations are found for the twentieth century winter over the Northern Hemisphere mid and high lat- itudes

Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production

Protection groups were introduced during biomass pretreatment to stabilize lignin's α,γ-diol group during its extraction and prevent its condensation. Acetaldehyde and propionaldehyde stabilized the α,γ-diol without any aromatic ring alkylation, which significantly increased final product selectivity. The subsequent hydrogenolysis catalyzed by Pd/C generated lignin monomers at near-theoretical yields based on Klason lignin (48 % from birch, 20 % from spruce, 70 % from high-syringyl transgenic poplar), and with high selectivity to a single 4-n-propanolsyringol product (80 %) in the case of the poplar. Unlike direct hydrogenation of native wood, hydrogenolysis of protected lignin with Ni/C also led to high selectivity to this single product (78 %), paving the way to high-selectivity lignin upgrading with base metal catalysts. The use of extracted lignin facilitated valorization of polysaccharides, leading to high yields of all three major biomass polymers to a single major product

Prominent role of mesopore surface area and external acid sites for the synthesis of polyoxymethylene dimethyl ethers (OME) on a hierarchical H-ZSM-5 zeolite

H-ZSM-5 zeolite has been shown to be an active catalyst for the synthesis of polyoxymethylene dimethyl ethers (OME). However, we demonstrated – by passivation of the zeolite's external surface – that the reaction rate is limited due to severe internal diffusion limitations of the reactants and products. External acid sites thus played a more prominent role in the observed overall reaction rate compared to the acid sites in the zeolite's micropores. Through controlled introduction of an intercrystalline network of mesopores the zeolite's activity was significantly enhanced by allowing a more significant part of the reaction to take place within the zeolite's micropores. By optimising alkaline treatment and consequent acid wash of H-ZSM-5, we achieved a two-fold increase in the initial reaction rate and a 10% increase in selectivity towards OME with 3 to 5 oxymethylene units (OME3–5), which are the more desirable products

Selective synthesis of dimethyl ether on eco-friendly K10 montmorillonite clay

The methanol dehydration reaction was studied over environmentally benign, easily accessible and inexpensive K10 montmorillonite clay used as the catalyst at a temperature range between 200–700 °C. Nearly 100% selectivity towards dimethyl ether (DME) at 80% methanol conversion was observed at 300 °C. However, upon heating, the selectivity shifted and the catalyst produced formaldehyde as well as an almost 1:1 M ratio of methane and carbon monoxide at 700 °C. Calcination at 300 °C increased the catalyst acidity due to desorption of chemisorbed water, thereby enhancing the methanol conversion to form DME. Higher calcination temperatures negatively affected the catalyst structure and, therefore, its activity. Catalyst characterization by means of X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), and solid-state Nuclear Magnetic Resonance (MAS NMR) spectroscopy, revealed that the calcination temperature affected the near surface Si/Al ratio as well as the surface hydroxyl groups. It was concluded that the density of the surface Brønsted acid sites is directly proportional to methanol conversion to DME