Uticaj meteoroloških parametara na koncentraciju SO2 u Obrenovcu, Srbija

In this paper, the impacts of some meteorological parameters on the SO2 concentrations in the City of Obrenovac are presented. The City of Obrenovac is located in the north-west part of Serbia on the banks of the River Sava. The observed source emission, the power plants TENT A and B are situated on the bank of the Sava River in the vicinity of Obrenovac. During the period from January to November 2006, the concentrations of sulfur dioxide in the air at 4 monitoring sites in Obrenovac were measured. It was noticed that the maximal measured daily concentrations of sulfur dioxide ranged from 1 μg m-3 (16th November, 2006) to 98 μg m-3 (29th January 2006) and lie under the maximal allowed concentration value according to the Serbian Law on Environmental Protection. The measured sulfur dioxide concentrations mostly showed characteristics usual for a daily acidification sulfur dioxide cycle, excluding the specificities influenced by the measuring site itself. Sulfur dioxide transport was recorded at increased wind speeds, primarily from the southeast direction. Based on the impact of meteorological parameters on the sulfur dioxide concentration, a validation of the monitoring sites was also performed from the aspect of their representivity.U radu su predstavljeni rezultati monitoringa koncentracije SO2 u vazduhu u Obrenovcu koji se nalazi na severozapadu Srbije na obalama reke Save. Posmatran je uticaj meteoroloških parametara na koncentraciju SO2 emitovanog iz termoelektrana TENT A i B koji se smatraju najvećim izvorima emisije. U periodu od januara do novembra 2006. godine praćene su koncentracije sumpor-dioksida u vazduhu na 4 merna mesta lokalizovana na različitim udaljenostima od izvora emisije. Maksimalne izmerene dnevne koncentracije sumpor-dioksida su se kretale od 1 μg m-3 (16. novembra, 2006) do 24 μg m-3 (29. januara, 2006). Izmerene promene koncentracija sumpor-dioksida uglavnom pokazuju uobičajene karakteristike dnevne acidifikacije ciklusa uz razlike koje potiču od osobenosti mernih mesta. Transport sumpor-dioksida zabeležen je pri pojačanom vetru prvenstveno iz jugoistočnog pravca. Na osnovu korelacionih odnosa između koncentracije sumpor-dioksida i odgovarajućih meteroloških parametara izvršena je karakterizacija mernih mesta u pogledu njihove reprezentativnosti za merenje sumpor-dioksida

Uticaj meteoroloških parametara na koncentraciju SO2 u Obrenovcu, Srbija

In this paper, the impacts of some meteorological parameters on the SO2 concentrations in the City of Obrenovac are presented. The City of Obrenovac is located in the north-west part of Serbia on the banks of the River Sava. The observed source emission, the power plants TENT A and B are situated on the bank of the Sava River in the vicinity of Obrenovac. During the period from January to November 2006, the concentrations of sulfur dioxide in the air at 4 monitoring sites in Obrenovac were measured. It was noticed that the maximal measured daily concentrations of sulfur dioxide ranged from 1 μg m-3 (16th November, 2006) to 98 μg m-3 (29th January 2006) and lie under the maximal allowed concentration value according to the Serbian Law on Environmental Protection. The measured sulfur dioxide concentrations mostly showed characteristics usual for a daily acidification sulfur dioxide cycle, excluding the specificities influenced by the measuring site itself. Sulfur dioxide transport was recorded at increased wind speeds, primarily from the southeast direction. Based on the impact of meteorological parameters on the sulfur dioxide concentration, a validation of the monitoring sites was also performed from the aspect of their representivity.U radu su predstavljeni rezultati monitoringa koncentracije SO2 u vazduhu u Obrenovcu koji se nalazi na severozapadu Srbije na obalama reke Save. Posmatran je uticaj meteoroloških parametara na koncentraciju SO2 emitovanog iz termoelektrana TENT A i B koji se smatraju najvećim izvorima emisije. U periodu od januara do novembra 2006. godine praćene su koncentracije sumpor-dioksida u vazduhu na 4 merna mesta lokalizovana na različitim udaljenostima od izvora emisije. Maksimalne izmerene dnevne koncentracije sumpor-dioksida su se kretale od 1 μg m-3 (16. novembra, 2006) do 24 μg m-3 (29. januara, 2006). Izmerene promene koncentracija sumpor-dioksida uglavnom pokazuju uobičajene karakteristike dnevne acidifikacije ciklusa uz razlike koje potiču od osobenosti mernih mesta. Transport sumpor-dioksida zabeležen je pri pojačanom vetru prvenstveno iz jugoistočnog pravca. Na osnovu korelacionih odnosa između koncentracije sumpor-dioksida i odgovarajućih meteroloških parametara izvršena je karakterizacija mernih mesta u pogledu njihove reprezentativnosti za merenje sumpor-dioksida

Safe trapping of Cs radionuclides in sintered matrix of zeolites

Cesium aluminosilicate phases are of the great interest as possible host for Cs immobilization in radioactive waste management. The possibility to use zeolite as a host material for radioactive Cs immobilization was investigated. Cs-exchanged forms of clinoptilolite and 13X which were prepared by ion-exchange treatment were compacted. The powders compacts of exchanged zeolites were thermally treated at 1200 °C. The XRD analysis showed that Cs was successfully immobilized after heat treatment by formation of stable cesium-aluminosilicate ceramic forms. Thermal and mechanical properties of the sintered samples were investigated. From the perspective of these characteristics, Cs-exchanged zeolite (clinoptilolite and 13 X) can be considered as a potential material for safe waste disposal

Changes of structural and hydrogen desorption properties of MgH2 indused by ion irradiation

Changes in structural and hydrogen desorption properties of MgH2 induced by ion irradiation have been investigated. MgH2 powder samples have been irradiated with 45 keV B3+ and 120 keV Ar8+ions, with ion fluence of 1015 ions/cm2. The effects of ion irradiation are estimated by numerical calculations using SRIM package. The induced material modifications and their consequences on hydrogen dynamics in the system are investigated by XRD, particle size distribution and TPD techniques. Changes of TPD spectra with irradiation conditions suggest that there are several mechanisms involved in desorption process which depend on defect concentration and their interaction and ordering. The results confirmed that the near-surface area of MgH2 and formation of a substoichiometric MgHx (x<2) play a crucial role in hydrogen kinetics and that various concentrations of induced defects substantially influence H diffusion and desorption kinetics in MgH2. The results also confirm that there is possibility to control the thermodynamic parameters by controlling vacancies concentration in the system

Mechanochemically improved surface properties of activated carbon cloth for the removal of As(V) from aqueous solutions

Modified activated carbon cloth is prepared by mechanochemical modification of viscose rayon carbon cloth. The effects of different milling atmospheres, in the air and inert conditions, were investigated. Changes in kind and number of acidic and basic surface groups on the surface of activated carbon cloth, upon modification, as well as before and after the sorption of arsenic were determined. Higher number of basic groups responsible for the removal of arsenic ions was achieved by modification under inert conditions. Breakage and collapse of cylindrical fibers, decrease of particle sizes, change in the shape and consistency of the particles, as well as increase of microstructural disorder i.e. the loss of turbostratic structure occurred upon milling. pHPZC values increased from 4.46 to 5.04 and 5.77 after the air and inert milling, respectively. Adsorption followed pseudo second order kinetics with chemisorption as rate-controlling step. Langmuir isotherm best fit the equilibrium data and maximum adsorption capacity is 5.5 mg g−1 at a pH value close to 7.0, typical for groundwater. The mechanism of arsenic adsorption onto activated carbon cloth milled in inert atmosphere involved electrostatic and dispersive interactions between arsenic ions and carbon particles in wide pH range (from 2 to 10)