Universal phase transitions of B1 structured stoichiometric transition-metal carbides

The high-pressure phase transitions of B1-structured stoichiometric transition metal carbides (TMCs, TM=Ti, Zr, Hf, V, Nb, and Ta) were systematically investigated using ab initio calculations. These carbides underwent universal phase transitions along two novel phase-transition routes, namely, B1\rightarrowdistorted TlI (TlI')\rightarrowTlI and/or B1\rightarrowdistorted TiB (TiB')\rightarrowTiB, when subjected to pressures. The two routes can coexist possibly because of the tiny enthalpy differences between the new phases under corresponding pressures. Four new phases result from atomic slips of the B1-structured parent phases under pressure. After completely releasing the pressure, taking TiC as a representative of TMCs, only its new TlI'-type phase is mechanically and dynamically stable, and may be recovered.Comment: [email protected]

Hydrogen storage systems from waste Mg alloys

The production cost of materials for hydrogen storage is one of the major issues to be addressed in order to consider them suitable for large scale applications. In the last decades several authors reported on the hydrogen sorption properties of Mg and Mg-based systems. In this work magnesium industrial wastes of AZ91 alloy and Mg-10 wt.% Gd alloy are used for the production of hydrogen storage materials. The hydrogen sorption properties of the alloys were investigated by means of volumetric technique, in situ synchrotron radiation powder X-ray diffraction (SR-PXD) and calorimetric methods. The measured reversible hydrogen storage capacity for the alloys AZ91 and Mg-10 wt.% Gd are 4.2 and 5.8 wt.%, respectively. For the Mg-10 wt.% Gd alloy, the hydrogenated product was also successfully used as starting reactant for the synthesis of Mg(NH2)2 and as MgH2 substitute in the Reactive Hydride Composite (RHC) 2LiBH4 + MgH 2. The results of this work demonstrate the concrete possibility to use Mg alloy wastes for hydrogen storage purposes

Phase transition kinetics of superionic H 2 O ice phases revealed by Megahertz X-ray free-electron laser-heating experiments

H2O transforms to two forms of superionic (SI) ice at high pressures and temperatures, which contain highly mobile protons within a solid oxygen sublattice. Yet the stability field of both phases remains debated. Here, we present the results of an ultrafast X-ray heating study utilizing MHz pulse trains produced by the European X-ray Free Electron Laser to create high temperature states of H2O, which were probed using X-ray diffraction during dynamic cooling. We confirm an isostructural transition during heating in the 26-69 GPa range, consistent with the formation of SI-bcc. In contrast to prior work, SI-fcc was observed exclusively above ~50 GPa, despite evidence of melting at lower pressures. The absence of SI-fcc in lower pressure runs is attributed to short heating timescales and the pressure-temperature path induced by the pump-probe heating scheme in which H2O was heated above its melting temperature before the observation of quenched crystalline states, based on the earlier theoretical prediction that SI-bcc nucleates more readily from the fluid than SI-fcc. Our results may have implications for the stability of SI phases in ice-rich planets, for example during dynamic freezing, where the preferential crystallization of SI-bcc may result in distinct physical properties across mantle ice layers

Stellar Populations in the Galactic Center

We discuss the stellar content of the Galactic Center, and in particular, recent estimates of the star formation rate (SFR). We discuss pros and cons of the different stellar tracers and focus our attention on the SFR based on the three classical Cepheids recently discovered in the Galactic Center. We also discuss stellar populations in field and cluster stars and present some preliminary results based on near-infrared photometry of a field centered on the young massive cluster Arches. We also provide a new estimate of the true distance modulus to the Galactic Center and we found 14.49$\pm$0.02(standard)$\pm$0.10(systematic) mag (7.91$\pm0.08\pm0.40$ kpc). Current estimate agrees quite well with similar photometric and kinematic distance determinations available in the literature. We also discuss the metallicity gradient of the thin disk and the sharp change in the slope when moving across the edge of the inner disk, the Galactic Bar and the Galactic Center. The difference becomes even more compelling if we take into account that metal abundances are based on young stellar tracers (classical Cepheids, Red Supergiants, Luminous Blue Variables). Finally, we briefly outline the possible mechanisms that might account for current empirical evidence.Comment: To be published in the Astrophysics and Space Science Proceeding

Trends in liver transplantation for primary biliary cirrhosis in the Netherlands 1988-2008

Background: A decrease in the need for liver transplantations (LTX) in Primary Biliary Cirrhosis (PBC), possibly related to treatment with ursodeoxycholic acid (UDCA), has been reported in the USA and UK. The aim of this study was to assess LTX require

X-ray free electron laser heating of water and gold at high static pressure

The study of water at high pressure and temperature is essential for understanding planetary interiors but is hampered by the high reactivity of water at extreme conditions. Here, indirect X-ray laser heating of water in a diamond anvil cell is realized via a gold absorber, showing no evidence of reactivity

HST Paschen-alpha Survey of the Galactic Center: Data Reduction and Products

Our HST/NICMOS Pa survey of the Galactic center (GC) provides a uniform, panoramic, high-resolution map of stars and ionized diffuse gas in the central 416 arcmin^2 of the Galaxy. This survey was carried out with 144 HST orbits using two narrow-band filters at 1.87 and 1.90 micron in NICMOS Camera 3. In this paper, we describe in detail the data reduction and mosaicking procedures followed, including background level matching and astrometric corrections. We have detected ~570,000 near-IR sources and are able to quantify photometric uncertainties of the detections. The source detection limit varies across the survey field but the typical 50% completion limit is ~17th mag (Vega System) in the 1.90 micron band. A comparison with the expected stellar magnitude distribution shows that these sources are primarily Main-Sequence massive stars (>7M) and evolved lower mass stars at the distance of the GC. In particular, the observed source magnitude distribution exhibits a prominent peak, which could represent the Red Clump stars within the GC. The observed magnitude and color of these RC stars support a steep extinction curve in the near-IR toward the GC. The flux ratios of our detected sources in the two bands also allow for an adaptive and statistical estimate of extinction across the field. With the subtraction of the extinction-corrected continuum, we construct a net Pa emission map and identify a set of Pa-emitting sources, which should mostly be evolved massive stars with strong stellar winds. The majority of the identified Pa point sources are located within the three known massive GC stellar clusters. However, a significant fraction of our Pa-emitting sources are located outside the clusters and may represent a new class of `field' massive stars, many of which may have formed in isolation and/or in small groups. The maps and source catalogues presented here are available electronically.Comment: Accepted for publication in MNRA

Considerations for management strategy evaluation for small pelagic fishes

Management strategy evaluation (MSE) is the state-of-the-art approach for testing and comparing management strategies in a way that accounts for multiple sources of uncertainty (e.g. monitoring, estimation, and implementation). Management strategy evaluation can help identify management strategies that are robust to uncertainty about the life history of the target species and its relationship to other species in the food web. Small pelagic fish (e.g. anchovy, herring and sardine) fulfil an important ecological role in marine food webs and present challenges to the use of MSE and other simulation-based evaluation approaches. This is due to considerable stochastic variation in their ecology and life history, which leads to substantial observation and process uncertainty. Here, we summarize the current state of MSE for small pelagic fishes worldwide. We leverage expert input from ecologists and modellers to draw attention to sources of process and observation uncertainty for small pelagic species, providing examples from geographical regions where these species are ecologically, economically and culturally important. Temporal variation in recruitment and other life-history rates, spatial structure and movement, and species interactions are key considerations for small pelagic fishes. We discuss tools for building these into the MSE process, with examples from existing fisheries. We argue that model complexity should be informed by management priorities and whether ecosystem information will be used to generate dynamics or to inform reference points. We recommend that our list of considerations be used in the initial phases of the MSE process for small pelagic fishes or to build complexity on existing single-species models.publishedVersio

Novel experimental setup for megahertz X-ray diffraction in a diamond anvil cell at the High Energy Density (HED) instrument of the European X-ray Free-Electron Laser (EuXFEL)

The high-precision X-ray diffraction setup for work with diamond anvil cells (DACs) in interaction chamber 2 (IC2) of the High Energy Density instrument of the European X-ray Free-Electron Laser is described. This includes beamline optics, sample positioning and detector systems located in the multipurpose vacuum chamber. Concepts for pump-probe X-ray diffraction experiments in the DAC are described and their implementation demonstrated during the First User Community Assisted Commissioning experiment. X-ray heating and diffraction of Bi under pressure, obtained using 20 fs X-ray pulses at 17.8 keV and 2.2 MHz repetition, is illustrated through splitting of diffraction peaks, and interpreted employing finite element modeling of the sample chamber in the DAC