Emission FTIR analyses of thin microscopic patches of jet fuel residues deposited on heated metal surfaces

The relationship of fuel stability to fuel composition and the development of mechanisms for deposit formation were investigated. Fuel deposits reduce heat transfer efficiency and increase resistance to fuel flow and are highly detrimental to aircraft performance. Infrared emission Fourier transform spectroscopy was chosen as the primary method of analysis because it was sensitive enough to be used in-situ on tiny patches of monolayers or of only a few molecular layers of deposits which generally proved completely insoluble in any nondestructive solvents. Deposits of four base fuels were compared; dodecane, a dodecane/tetralin blend, commercial Jet A fuel, and a broadened-properties jet fuel particularly rich in polynuclear aromatics. Every fuel in turn was provided with and without small additions of such additives as thiophene, furan, pyrrole, and copper and iron naphthenates

Emission FTIR analyses of thin microscopic patches of jet fuel residue deposited on heated metal surface

Deposits laid down in patches on metal strips in a high pressure/high temperature fuel system simulator operated with aerated fuel at varying flow rates were analyzed by emission FTIR in terms of functional groups. Significant differences were found in the spectra and amounts of deposits derived from fuels to which small concentrations of oxygen-, nitrogen-, or sulfur-containing heterocyclics or metal naphthenates were added. The spectra of deposits generated on strips by heating fuels and air in a closed container were very different from those of the flowing fluid deposits. One such closed-container dodecane deposit on silver gave a strong surface-enhanced Raman spectrum

Global Atmospheric Aerosol Modeling

Global aerosol models are used to study the distribution and properties of atmospheric aerosol particles as well as their effects on clouds, atmospheric chemistry, radiation, and climate. The present article provides an overview of the basic concepts of global atmospheric aerosol modeling and shows some examples from a global aerosol simulation. Particular emphasis is placed on the simulation of aerosol particles and their effects within global climate models

Global model simulations of the impact of ocean-going ships on aerosols, clouds, and the radiation budget

International shipping contributes significantly to the fuel consumption of all transport related activities. Specific emissions of pollutants such as sulfur dioxide (SO<sub>2</sub>) per kg of fuel emitted are higher than for road transport or aviation. Besides gaseous pollutants, ships also emit various types of particulate matter. The aerosol impacts the Earth's radiation budget directly by scattering and absorbing the solar and thermal radiation and indirectly by changing cloud properties. Here we use ECHAM5/MESSy1-MADE, a global climate model with detailed aerosol and cloud microphysics to study the climate impacts of international shipping. The simulations show that emissions from ships significantly increase the cloud droplet number concentration of low marine water clouds by up to 5% to 30% depending on the ship emission inventory and the geographic region. Whereas the cloud liquid water content remains nearly unchanged in these simulations, effective radii of cloud droplets decrease, leading to cloud optical thickness increase of up to 5–10%. The sensitivity of the results is estimated by using three different emission inventories for present-day conditions. The sensitivity analysis reveals that shipping contributes to 2.3% to 3.6% of the total sulfate burden and 0.4% to 1.4% to the total black carbon burden in the year 2000 on the global mean. In addition to changes in aerosol chemical composition, shipping increases the aerosol number concentration, e.g. up to 25% in the size range of the accumulation mode (typically >0.1 μm) over the Atlantic. The total aerosol optical thickness over the Indian Ocean, the Gulf of Mexico and the Northeastern Pacific increases by up to 8–10% depending on the emission inventory. Changes in aerosol optical thickness caused by shipping induced modification of aerosol particle number concentration and chemical composition lead to a change in the shortwave radiation budget at the top of the atmosphere (ToA) under clear-sky condition of about −0.014 W/m² to −0.038 W/m² for a global annual average. The corresponding all-sky direct aerosol forcing ranges between −0.011 W/m² and −0.013 W/m². The indirect aerosol effect of ships on climate is found to be far larger than previously estimated. An indirect radiative effect of −0.19 W/m² to −0.60 W/m² (a change in the atmospheric shortwave radiative flux at ToA) is calculated here, contributing 17% to 39% of the total indirect effect of anthropogenic aerosols. This contribution is high because ship emissions are released in regions with frequent low marine clouds in an otherwise clean environment. In addition, the potential impact of particulate matter on the radiation budget is larger over the dark ocean surface than over polluted regions over land

The Luminosity Profiles of Brightest Cluster Galaxies

(Abridged) We have derived detailed R band luminosity profiles and structural parameters for a total of 430 brightest cluster galaxies (BCGs), down to a limiting surface brightness of 24.5 mag/arcsec^2. Light profiles were initially fitted with a Sersic's R^(1/n) model, but we found that 205 (~48) BCGs require a double component model to accurately match their light profiles. The best fit for these 205 galaxies is an inner Sersic model, with indices n~1-7, plus an outer exponential component. Thus, we establish the existence of two categories of the BCGs luminosity profiles: single and double component profiles. We found that double profile BCGs are brighter ~0.2 mag than single profile BCG. In fact, the Kolmogorov-Smirnov test applied to these subsamples indicates that they have different total magnitude distributions, with mean values M_R=-23.8 +/- 0.6 mag for single profile BCGs and M_R=-24.0 +/- 0.5 mag for double profile BCGs. We find that partial luminosities for both subsamples are indistinguishable up to r = 15 kpc, while for r > 20 kpc the luminosities we obtain are on average 0.2 mag brighter for double profile BCGs. This result indicates that extra-light for double profile BCGs does not come from the inner region but from the outer regions of these galaxies. The best fit slope of the Kormendy relation for the whole sample is a = 3.13 +/- 0.04$. However, when fitted separately, single and double profile BCGs show different slopes: a_(single) = 3.29 +/- 0.06 and a_(double)= 2.79 +/- 0.08. On the other hand, we did not find differences between these two BCGs categories when we compared global cluster properties such as the BCG-projected position relative to the cluster X-ray center emission, X-ray luminosity, or BCG orientation with respect to the cluster position angle.Comment: August 2011 issue of ApJS, volume 195, 15 http://iopscience.iop.org/0067-0049/195/2/1

Impaired Chronotropic Response to Exercise Stress Testing in Patients With Diabetes Predicts Future Cardiovascular Events

OBJECTIVES— To assess the association between impaired chronotropic response (CR) and adverse events among patients with diabetes referred for exercise treadmill testing (ETT)

The Galactic Exoplanet Survey Telescope (GEST)

The Galactic Exoplanet Survey Telescope (GEST) will observe a 2 square degree field in the Galactic bulge to search for extra-solar planets using a gravitational lensing technique. This gravitational lensing technique is the only method employing currently available technology that can detect Earth-mass planets at high signal-to-noise, and can measure the frequency of terrestrial planets as a function of Galactic position. GEST's sensitivity extends down to the mass of Mars, and it can detect hundreds of terrestrial planets with semi-major axes ranging from 0.7 AU to infinity. GEST will be the first truly comprehensive survey of the Galaxy for planets like those in our own Solar System.Comment: 17 pages with 13 figures, to be published in Proc. SPIE vol 4854, "Future EUV-UV and Visible Space Astrophysics Missions and Instrumentation

Can Standard Cosmological Models Explain the Observed Abell Cluster Bulk Flow?

Lauer \& Postman (LP) observe that all Abell clusters with redshifts less than 15,000\kms\ appear to be participating in a bulk flow of 689 km s$^{-1}$ with respect to the Cosmic Microwave Background. We find this result difficult to reconcile with all popular models for large-scale structure formation that assume Gaussian initial conditions. This conclusion is based on Monte-Carlo realizations of the LP data, drawn from large Particle-Mesh $N$-body simulations. We have taken special care to treat properly the longest-wavelength components of the power spectra. Bulk flows with amplitude as large as that reported by LP are not uncommon in the Monte-Carlo datasets. However, the $\chi^2$ of the observed bulk flow, taking into account the anisotropy of the error ellipsoid, is much more difficult to match in the simulations. The models examined are ruled out at confidence levels between 94\% and 98\%. Any model that has {\it intrinsic} flows of less than 480\kms\ on the scales probed by LP scales can be ruled out at a similar level.Comment: Submitted to ApJ. 31 pages of uuencoded compressed postscript (810 kbytes); figures included. Also available via anonymous ftp to eku.ias.edu in /pub/strauss/warpfire/warpfire.ps.