1,211 research outputs found
A spaceborne optical interferometer: The JPL CSI mission focus
The JPL Control Structure Interaction (CSI) program is part of the larger NASA-wide CSI program. Within this larger context, the JPL CSI program will emphasize technology for systems that demand micron or sub-micron level control, so-called Micro-Precision Controlled Structures (u-PCS). The development of such technology will make it practical to fly missions with large optical or large precision antenna systems. In keeping with the focused nature of the desired technology, the JPL approach is to identify a focus mission, develop the focus mission CSI system design to a preliminary level, and then use this design to drive out requirements for CSI technology development in the design and analysis, ground test bed, and flight experiment areas
Molecular composition of particulate matter emissions from dung and brushwood burning household cookstoves in Haryana, India
Emissions of airborne particles from biomass burning are a significant source of black carbon (BC) and brown carbon (BrC) in rural areas of developing countries where biomass is the predominant energy source for cooking and heating. This study explores the molecular composition of organic aerosols from household cooking emissions with a focus on identifying fuel-specific compounds and BrC chromophores. Traditional meals were prepared by a local cook with dung and brushwood-fueled cookstoves in a village in Palwal district, Haryana, India. Cooking was done in a village kitchen while controlling for variables including stove type, fuel moisture, and meal. Fine particulate matter (PM2.5) emissions were collected on filters, and then analyzed via nanospray desorption electrospray ionization-high-resolution mass spectrometry (nano-DESI-HRMS) and high-performance liquid chromatography-photodiode array-high-resolution mass spectrometry (HPLC-PDA-HRMS) techniques. The nano-DESI-HRMS analysis provided an inventory of numerous compounds present in the particle phase. Although several compounds observed in this study have been previously characterized using gas chromatography methods a majority of the species in the nano-DESI spectra were newly observed biomass burning compounds. Both the stove (chulha or angithi) and the fuel (brushwood or dung) affected the composition of organic aerosols. The geometric mean of the PM2.5 emission factor and the observed molecular complexity increased in the following order: brushwood-chulha (7.3±1.8 g kg-1 dry fuel, 93 compounds), dung-chulha (21.1±4.2 g kg-1 dry fuel, 212 compounds), and dung-angithi (29.8±11.5 g kg-1 dry fuel, 262 compounds). The mass-normalized absorption coefficient (MACbulk) for the organic-solvent extractable material for brushwood PM2.5 was 3.7±1.5 and 1.9±0.8m2 g-1 at 360 and 405 nm, respectively, which was approximately a factor of two higher than that for dung PM2.5. The HPLC-PDA-HRMS analysis showed that, regardless of fuel type, the main chromophores were CxHyOz lignin fragments. The main chromophores accounting for the higher MACbulk values of brushwood PM2.5 were C8H10O3 (tentatively assigned to syringol), nitrophenols C8H9NO4, and C10H10O3 (tentatively assigned to methoxycinnamic acid)
Fractional Quantum Mechanics
A path integral approach to quantum physics has been developed. Fractional
path integrals over the paths of the L\'evy flights are defined. It is shown
that if the fractality of the Brownian trajectories leads to standard quantum
and statistical mechanics, then the fractality of the L\'evy paths leads to
fractional quantum mechanics and fractional statistical mechanics. The
fractional quantum and statistical mechanics have been developed via our
fractional path integral approach. A fractional generalization of the
Schr\"odinger equation has been found. A relationship between the energy and
the momentum of the nonrelativistic quantum-mechanical particle has been
established. The equation for the fractional plane wave function has been
obtained. We have derived a free particle quantum-mechanical kernel using Fox's
H function. A fractional generalization of the Heisenberg uncertainty relation
has been established. Fractional statistical mechanics has been developed via
the path integral approach. A fractional generalization of the motion equation
for the density matrix has been found. The density matrix of a free particle
has been expressed in terms of the Fox's H function. We also discuss the
relationships between fractional and the well-known Feynman path integral
approaches to quantum and statistical mechanics.Comment: 27 page
Path Integral Approach to the Non-Relativistic Electron Charge Transfer
A path integral approach has been generalized for the non-relativistic
electron charge transfer processes. The charge transfer - the capture of an
electron by an ion passing another atom or more generally the problem of
rearrangement collisions is formulated in terms of influence functionals. It
has been shown that the electron charge transfer process can be treated either
as electron transition problem or as elastic scattering of ion and atom in the
some effective potential field. The first-order Born approximation for the
electron charge transfer cross section has been reproduced to prove the
adequacy of the path integral approach for this problem.Comment: 19 pages, 1 figure, to appear in Journal of Physics B: Atomic,
Molecular & Optical, vol.34, 200
Spectro-microscopic measurements of carbonaceous aerosol aging in Central California
Carbonaceous aerosols are responsible for large uncertainties in climate models, degraded visibility, and adverse health effects. The Carbonaceous Aerosols and Radiative Effects Study (CARES) was designed to study carbonaceous aerosols in the natural environment of the Central Valley, California, and learn more about their atmospheric formation and aging. This paper presents results from spectro-microscopic measurements of carbonaceous particles collected during CARES at the time of a pollution accumulation event (27–29 June 2010), when in situ measurements indicated an increase in the organic carbon content of aerosols as the Sacramento urban plume aged. Computer-controlled scanning electron microscopy coupled with an energy dispersive X-ray detector (CCSEM/EDX) and scanning transmission X-ray microscopy coupled with near-edge X-ray absorption spectroscopy (STXM/NEXAFS) were used to probe the chemical composition and morphology of individual particles. It was found that the mass of organic carbon on individual particles increased through condensation of secondary organic aerosol. STXM/NEXAFS indicated that the number fraction of homogenous organic particles lacking inorganic inclusions (greater than ~50 nm equivalent circular diameter) increased with plume age, as did the organic mass per particle. Comparison of the CARES spectro-microscopic dataset with a similar dataset obtained in Mexico City during the MILAGRO campaign showed that fresh particles in Mexico City contained three times as much carbon as those sampled during CARES. The number fraction of soot particles at the Mexico City urban site (ranging from 16.6 to 47.3%) was larger than at the CARES urban site (13.4–15.7%), and the most aged samples from CARES contained fewer carbon–carbon double bonds. Differences between carbonaceous particles in Mexico City and California result from different sources, photochemical conditions, gas phase reactants, and secondary organic aerosol precursors. The detailed results provided by these spectro-microscopic measurements will allow for a comprehensive evaluation of aerosol process models used in climate research
Applications of Lagrangian dispersion modeling to the analysis of changes in the specific absorption of elemental carbon
International audienceWe use a Lagrangian dispersion model driven by a mesoscale model with four-dimensional data assimilation to simulate the dispersion of elemental carbon (EC) over a region encompassing Mexico City and its surroundings, the study domain for the 2006 MAX-MEX experiment, which was a component of the MILAGRO campaign. The results are used to identify periods when biomass burning was likely to have had a significant impact on the concentrations of elemental carbon at two sites, T1 and T2, downwind of the city, and when emissions from the Mexico City Metropolitan Area (MCMA) were likely to have been more important. They are also used to estimate the median ages of EC affecting the specific absorption of light, ?ABS, at 870 nm as well as to identify periods when the urban plume from the MCMA was likely to have been advected over T1 and T2. Median EC ages at T1 and T2 are substantially larger during the day than at night. Values of ?ABS at T1, the nearer of the two sites to Mexico City, were smaller at night and increased rapidly after mid-morning, peaking in the mid-afternoon. The behavior is attributed to the coating of aerosols with substances such as sulfate or organic carbon during daylight hours, but such coating appears to be limited or absent at night. Evidence for this is provided by scanning electron microscopy images of aerosols collected at the sampling sites. During daylight hours the values of ?ABS did not increase with aerosol age for median ages in the range of 1?4 h. There is some evidence for absorption increasing as aerosols were advected from T1 to T2 but the statistical significance of that result is not strong
On distributions of functionals of anomalous diffusion paths
Functionals of Brownian motion have diverse applications in physics,
mathematics, and other fields. The probability density function (PDF) of
Brownian functionals satisfies the Feynman-Kac formula, which is a Schrodinger
equation in imaginary time. In recent years there is a growing interest in
particular functionals of non-Brownian motion, or anomalous diffusion, but no
equation existed for their PDF. Here, we derive a fractional generalization of
the Feynman-Kac equation for functionals of anomalous paths based on
sub-diffusive continuous-time random walk. We also derive a backward equation
and a generalization to Levy flights. Solutions are presented for a wide number
of applications including the occupation time in half space and in an interval,
the first passage time, the maximal displacement, and the hitting probability.
We briefly discuss other fractional Schrodinger equations that recently
appeared in the literature.Comment: 25 pages, 4 figure
Psi-Series Solution of Fractional Ginzburg-Landau Equation
One-dimensional Ginzburg-Landau equations with derivatives of noninteger
order are considered. Using psi-series with fractional powers, the solution of
the fractional Ginzburg-Landau (FGL) equation is derived. The leading-order
behaviours of solutions about an arbitrary singularity, as well as their
resonance structures, have been obtained. It was proved that fractional
equations of order with polynomial nonlinearity of order have the
noninteger power-like behavior of order near the singularity.Comment: LaTeX, 19 pages, 2 figure
On bulk singularities in the random normal matrix model
We extend the method of rescaled Ward identities of Ameur-Kang-Makarov to
study the distribution of eigenvalues close to a bulk singularity, i.e. a point
in the interior of the droplet where the density of the classical equilibrium
measure vanishes. We prove results to the effect that a certain "dominant part"
of the Taylor expansion determines the microscopic properties near a bulk
singularity. A description of the distribution is given in terms of a special
entire function, which depends on the nature of the singularity (a
Mittag-Leffler function in the case of a rotationally symmetric singularity).Comment: This version clarifies on the proof of Theorem
The Calcium Carbonate Geological Samples Study by <sup>3</sup>He NMR
© 2017 Springer-Verlag WienGeological samples of calcium carbonates (CaCO3) were investigated by 3He NMR, nitrogen porosimetry, X-ray diffraction and electron microscopy methods. The integral porosity of the samples was obtained by 3He nuclear magnetic resonance method and compared with nitrogen adsorption isotherms data. The advantages of 3He porometry method are discussed
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