3D microstructure of magnesium potassium phosphate ceramics from X-ray tomography: new insights into the reaction mechanisms

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3D microstructure of magnesium potassium phosphate ceramics from X-ray tomography: new insights into the reaction mechanisms

Magnesium potassium phosphate ceramics are chemically bonded ceramics employed as biomaterials, in nuclear waste encapsulation and for concrete repair. The microstructure dictates material performance and depends on the raw mix composition. Synchrotron X-ray computed microtomography was employed to describe the 3D microstructure and its time evolution during hardening and gain insights into the reaction mechanisms. Any excess water with respect to the stoichiometry of the reaction brought about an increase in porosity, but, notably, a reduction in the average pore size. Crystals filled the water ‘pockets’ in the ceramic volume by growing larger, although less densely packed, increasing the complexity of the pore shape. Platelet over elongated crystal habit was favoured. Such a change in shape is likely related to a change in reaction mechanism, as crystallization from a gel-like amorphous precursor is hindered and progressively substituted by a through-solution mechanism. It is proposed that the time evolution of the microstructure is dictated by the balance between crystallization from amorphous precursor, prevailing in relatively ‘dense’ systems (with stoichiometric water or in low excess), and water segregation, prevailing at higher water contents. The former mechanism was shown to produce an increase in porosity with time, because of the density mismatch between the amorphous and the crystalline phase

Multidisciplinary study of the Tindari Fault (Sicily, Italy) separating ongoing contractional and extensional compartments along the active Africa–Eurasia convergent boundary

The Africa–Eurasia convergence in Sicily and southern Calabria is currently expressed by two different tectonic and geodynamic domains: thewestern region, governed by a roughlyN–S compression generated by a continental collision; the eastern one, controlled by a NW–SE extension related to the south-east-directed expansion of the Calabro–Peloritan Arc. The different deformation pattern of these two domains is accommodated by a right-lateral shear zone (Aeolian–Tindari–Letojanni fault system) which, from the Ionian Sea, north of Mt. Etna, extends across the Peloritani chain to the Aeolian Islands. In this work, we study the evidence of active tectonics characterizing this shear zone, through the analysis of seismic and geodetic data acquired by the INGV networks in the last 15 years. The study is completed by structural and morphological surveys carried out between Capo Tindari and the watershed of the chain. The results allowed defining a clear structural picture depicting the tectonic interferences between the two different geodynamic domains. The results indicate that, besides the regional ~N130°E horizontal extensional stress field, another one, NE–SW-oriented, is active in the investigated area. Both tension axes are mutually independent and have been active up to the present at different times. The coexistence of these different active horizontal extensions is the result of complex interactions between several induced stresses: 1) the regional extension (NW–SE) related to the slab rollback and back-arc extension; 2) the strong uplift of the chain; 3) the accommodation between compressional and extensional tectonic regimes along the Aeolian– Tindari–Letojanni faults, through a SSE–NNW right-lateral transtensional displacement. In these conditions, the greater and recurring uplift activity is not able to induce a radial extensional dynamics, but, under the “directing” action of the shear system, it can only act on the regional extension (NW–SE) and produce the second system of extension (NE–SW)

The Gaia-ESO Survey: dynamics of ionized and neutral gas in the Lagoon nebula (M8)

We present a spectroscopic study of the dynamics of the ionized and neutral gas throughout the Lagoon nebula (M8), using VLT/FLAMES data from the Gaia-ESO Survey. We explore the connections between the nebular gas and the stellar population of the associated star cluster NGC6530. We characterize through spectral fitting emission lines of H-alpha, [N II] and [S II] doublets, [O III], and absorption lines of sodium D doublet, using data from the FLAMES/Giraffe and UVES spectrographs, on more than 1000 sightlines towards the entire face of the Lagoon nebula. Gas temperatures are derived from line-width comparisons, densities from the [S II] doublet ratio, and ionization parameter from H-alpha/[N II] ratio. Although doubly-peaked emission profiles are rarely found, line asymmetries often imply multiple velocity components along the line of sight. This is especially true for the sodium absorption, and for the [O III] lines. Spatial maps for density and ionization are derived, and compared to other known properties of the nebula and of its massive stars 9 Sgr, Herschel 36 and HD 165052 which are confirmed to provide most of the ionizing flux. The detailed velocity fields across the nebula show several expanding shells, related to the cluster NGC6530, the O stars 9 Sgr and Herschel 36, and the massive protostar M8East-IR. The origins of kinematical expansion and ionization of the NGC6530 shell appear to be different. We are able to put constrains on the line-of-sight (relative or absolute) distances between some of these objects and the molecular cloud. The large obscuring band running through the middle of the nebula is being compressed by both sides, which might explain its enhanced density. We also find an unexplained large-scale velocity gradient across the entire nebula. At larger distances, the transition from ionized to neutral gas is studied using the sodium lines.Comment: 26 pages, 31 figures, accepted on Astronomy and Astrophysics journa

Synthetic calcium carbonate improves the effectiveness of treatments with nanolime to contrast decay in highly porous limestone

Three synthetized polymorphs of calcium carbonate have been tested in combination with the suspension of nanolime particles as potential consolidating agents for contrasting stone decay and overcome some of the limitations of nanolime agents when applied to substrates with large porosity. The modifications induced in the pore network of the Maastricht limestone were analyzed with microscopy and in a non-invasive fashion with small angle neutron scattering and synchrotron radiation micro-computed tomography. A reduction in porosity and pore accessibility at the micrometric scale was detected with the latter technique, and ascribed to the improved pore-filling capacity of the consolidation agent containing CaCO3 particles. These were found to be effectively bound to the carbonated nanolime, strengthening the pore-matrix microstructure. Penetration depth and positive effect on porosity were found to depend on the particle size and shape. Absence of significant changes in the fractal nature of the pore surface at the nanoscale, was interpreted as indication of the negligible contribution of nanolime-based materials in the consolidation of stones with large porosity. However, the results indicate that in such cases, their effectiveness may be enhanced when used in combination with CaCO3 particles, owing to the synergic effect of chemical/structural compatibility and particle size distribution

PyPore3D: An Open Source Software Tool for Imaging Data Processing and Analysis of Porous and Multiphase Media

n this work, we propose the software library PyPore3D, an open source solution for data processing of large 3D/4D tomographic data sets. PyPore3D is based on the Pore3D core library, developed thanks to the collaboration between Elettra Sincrotrone (Trieste) and the University of Trieste (Italy). The Pore3D core library is built with a distinction between the User Interface and the backend filtering, segmentation, morphological processing, skeletonisation and analysis functions. The current Pore3D version relies on the closed source IDL framework to call the backend functions and enables simple scripting procedures for streamlined data processing. PyPore3D addresses this limitation by proposing a full open source solution which provides Python wrappers to the the Pore3D C library functions. The PyPore3D library allows the users to fully use the Pore3D Core Library as an open source solution under Python and Jupyter Notebooks PyPore3D is both getting rid of all the intrinsic limitations of licensed platforms (e.g., closed source and export restrictions) and adding, when needed, the flexibility of being able to integrate scientific libraries available for Python (SciPy, TensorFlow, etc.)

Quantitative and Qualitative Assessments of Retinal Structure with Variable A-Scan Rate Spectralis OCT: Insights into IPL Multilaminarity

The aim of this study was to evaluate the qualitative and quantitative differences between 20 and 85 kHz A-scan rate optical coherence tomography (OCT) images acquired by spectral domain OCT. The study included 60 healthy subjects analyzed with horizontal linear scans with a variable A-scan rate (SHIFT technology, Heidelberg Engineering, Heidelberg, Germany). The retinal thickness measurement of each retinal layer was performed in three different positions (subfoveal, nasal, and temporal). The qualitative assessment was performed by two independent observers who rated every image with a score ranging from 1 ("sufficient") to 3 ("excellent") on the basis of three parameters: visualization of the vitreo-retinal interface, characterization of the retinal layers, and visualization of the sclero-choroidal interface. No statistically significant differences in terms of retinal layer thickness between the two A-scan rate scans were observed (p > 0.05). The coefficient of variation of the retinal thickness values was lower in the 20 kHz group (25.8% versus 30.1% with the 85 kHz). The 20 kHz images showed a higher quality index for both observers. An inner plexiform layer (IPL) multilaminarity was detected in 78.3% of patients from the 20 kHz group and in 40% of patients from the 85 kHz group (p < 0.05)

The Gaia-ESO Survey: the selection function of the Milky Way field stars

The Gaia-ESO Survey was designed to target all major Galactic components (i.e., bulge, thin and thick discs, halo and clusters), with the goal of constraining the chemical and dynamical evolution of the Milky Way. This paper presents the methodology and considerations that drive the selection of the targeted, allocated and successfully observed Milky Way field stars. The detailed understanding of the survey construction, specifically the influence of target selection criteria on observed Milky Way field stars is required in order to analyse and interpret the survey data correctly. We present the target selection process for the Milky Way field stars observed with VLT/FLAMES and provide the weights that characterise the survey target selection. The weights can be used to account for the selection effects in the Gaia-ESO Survey data for scientific studies. We provide a couple of simple examples to highlight the necessity of including such information in studies of the stellar populations in the Milky Way.Comment: 18 pages, 19 figures, Accepted for publication in MNRAS (April 25, 2016

The Gaia-ESO Survey: membership and Initial Mass Function of the Gamma Velorum cluster

Understanding the properties of young open clusters, such as the Initial Mass Function (IMF), star formation history and dynamic evolution, is crucial to obtain reliable theoretical predictions of the mechanisms involved in the star formation process. We want to obtain a list, as complete as possible, of confirmed members of the young open cluster Gamma Velorum, with the aim of deriving general cluster properties such as the IMF. We used all available spectroscopic membership indicators within the Gaia-ESO public archive together with literature photometry and X-ray data and, for each method, we derived the most complete list of candidate cluster members. Then, we considered photometry, gravity and radial velocities as necessary conditions to select a subsample of candidates whose membership was confirmed by using the lithium and H$\alpha$ lines and X-rays as youth indicators. We found 242 confirmed and 4 possible cluster members for which we derived masses using very recent stellar evolutionary models. The cluster IMF in the mass range investigated in this study shows a slope of $\alpha=2.6\pm0.5$ for $0.5<M/M_\odot <1.3$ and $\alpha=1.1\pm0.4$ for $0.16<M/M_\odot <0.5$ and is consistent with a standard IMF. The similarity of the IMF of the young population around $\gamma^2$Vel to that in other star forming regions and the field suggests it may have formed through very similar processes.Comment: Accepted for publication in A&A; 18 pages, 11 figures, 5 table