Fiber-Fed Laser-Heated Process for Printing Transparent Glass

This paper presents the Additive Manufacturing (AM) of glass using a fiber-fed process. Glass fiber with a diameter of 100 μm is fed into a laser generated melt pool. A CO2 laser beam is focused on the intersection between the fiber and the work piece which is positioned on a four-axis computer controlled stage. The laser energy at λ=10.6 μm is directly absorbed by the silica and locally heats the glass above the working point. By carefully controlling the laser power, scan speed, and feed rate, bubble free shapes can be deposited including trusses and basic lenses. Issues unique to the process are discussed, including the thermal breakdown of the glass, buckling of the fiber against an inadequately heated stiff molten region, and dimensional control when depositing viscous material

Four Months of Kettlebell Training Improves Muscle Strength and Functional Outcomes in Older Adults

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Bubble Formation in Additive Manufacturing of Borosilicate Glass

Entrapped bubbles are an important problem in conventional glass manufacturing. It is also a significant factor determining the quality of glass products produced using additive manufacturing (AM). This paper reports on the bubble formation and entrapment in filament-fed AM printing of borosilicate glass. This process involves maintaining a local molten region using a CO2 laser. A 2 mm filament is fed continuously into the molten region while CNC stages position the workpiece relative to the laser and filament feed. Two different bubble regimes are identified in experiments with borosilicate glass. These regimes can be related to different physical phenomena, specifically, bubble entrapment at defects in the filaments and bubble formation due to reboil. These can be overcome by selecting defect free filaments and by minimizing the temperature inside the molten region to prevent breaking down the glass. Understanding these mechanisms allows bubble-free glass to be printed. Finally, residual stress in the deposited glass pieces is removed using post-deposition annealing and validated using a polariscope

Bond-rearrangement and ionization mechanisms in the photo-double-ionization of simple hydrocarbons (C2H4, C2H3F, and 1,1-C2H2F2) near and above threshold

Citation: Gaire, B., Gatton, A., Wiegandt, F., Neff, J., Janke, C., Zeller, S., . . . Weber, T. (2016). Bond-rearrangement and ionization mechanisms in the photo-double-ionization of simple hydrocarbons (C2H4, C2H3F, and 1,1-C2H2F2) near and above threshold. Physical Review A, 94(3), 8. doi:10.1103/PhysRevA.94.033412We investigate bond-rearrangement driven by photo-double-ionization (PDI) near and above the double-ionization threshold in a sequence of carbon-carbon double-bonded hydrocarbon molecules: ethylene, fluoroethylene, and 1,1-difluoroethylene. We employ the kinematically complete cold target recoil ion momentum spectroscopy method to resolve all photo-double-ionization events leading to two-ion fragments. We observe changes in the branching ratios of different dissociative ionization channels depending on the presence of no, one, or two fluorine atoms. The role of the fluorine atom in the bond-rearrangement channels is intriguing, as evident by the reordering of the threshold energies of the PDI in the fluorinated molecules. These effects offer a compelling argument that the electronegativity of the fluorine (or the polarity of the molecule) strongly influences the potential energy surfaces of the molecules and drives bond rearrangement during the dissociation process. The energy sharing and the relative angle between the three-dimensional momentum vectors of the two electrons enable us to distinguish between knockout and other ionization mechanisms of the PDI processes

Additive Manufacturing of Transparent Fused Quartz

This paper investigates a filament-fed process for additive manufacturing (AM) of fused quartz. Glasses such as fused quartz have significant scientific and engineering applications, which include optics, communications, electronics, and hermetic seals. AM has several attractive benefits such as increased design freedom, faster prototyping, and lower processing costs for small production volumes. However, current research into glass AM has focused primarily on nonoptical applications. Fused quartz is studied here because of its desirability for use in high-quality optics due to its high transmissivity and thermal stability. Fused quartz filaments are fed into a CO2 laser-generated molten region, smoothly depositing material onto the workpiece. Spectroscopy and pyrometry are used to measure the thermal radiation incandescently emitted from the molten region. The effects of the laser power and scan speed are determined by measuring the morphology of single tracks. Thin walls are printed to study the effects of layer-to-layer height. This information is used to deposit solid pieces including a cylindrical-convex shape capable of focusing visible light. The transmittance and index homogeneity of the printed fused quartz are measured. These results show that the filament-fed process has the potential to print transmissive optics

Ultrafast temporal evolution of interatomic Coulombic decay in NeKr dimers

We investigate interatomic Coulombic decay in NeKr dimers after neon inner-valence photoionization [Ne+(2s-1)] using a synchrotron light source. We measure with high energy resolution the two singly charged ions of the Coulomb-exploding dimer dication and the photoelectron in coincidence. By carefully tracing the post-collision interaction between the photoelectron and the emitted ICD electron we are able to probe the temporal evolution of the state as it decays. Although the ionizing light pulses are 80 picoseconds long, we determine the lifetime of the intermediate dimer cation state and visualize the contraction of the nuclear structure on the femtosecond time scale

A case of natural recovery after the removal of invasive predators – community assemblage changes in the avifauna of Burgess Island

Opportunities to monitor natural island ecosystem recovery following the eradication of introduced predators are rare, and provide a useful comparison for recovery programmes aided by active habitat restoration and species translocations. We present an assessment of the current avifauna on Burgess Island, Mokohinau Group, 2 decades after kiore (Pacific rat; Rattus exulans) removal. The 4 most abundant land bird species we recorded are red-crowned parakeet (Cyanorhamphus novaezelandiae), bellbird (Anthornis melanura), tui (Prosthemadera novaeseelandiae) and silvereye (Zosterops lateralis), all New Zealand native taxa. Our records confirm that 46 species now utilize the island’s habitats, compared with 24 species reported from the literature during the last decades of rat infestation. We also confirm breeding of 9 seabird species by 2011, only 4 of which maintained breeding populations on Burgess Island prior to rat eradication. More than 20 years after predator removal, Burgess Island hosts a rich avifauna, and provides a valuable example of natural recovery following predator eradication without any further active restoration measure