20 research outputs found

    O PROCESSO DE TRABALHO EM UMA IMOBILI?RIA : SOBRECARGA DE ATIVIDADE NO ?MBITO DA DIRE??O GERAL

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    O presente Trabalho de Conclus?o de Curso (TCC) tem a finalidade de analisar as poss?veis causas de sobrecarga de atividades no ?mbito da Dire??o Geral no contexto de uma imobili?ria. Para isso realizou-se uma pesquisa bibliogr?fica e descritiva sobre o processo de trabalho de uma imobili?ria, as fun??es administrativas empregadas, sobretudo a fun??o de organiza??o, que aborda sobre a distribui??o do trabalho. Como instrumento de coleta de dados foi aplicado um question?rio com 13 quest?es aos gestores imobili?rios com a finalidade de filtrar informa??es referentes ? sua forma??o, qual o estilo de trabalho adotado em sua pr?tica, al?m da postura do gestor frente ? dire??o geral da imobili?ria, a natureza dos dados coletados ? de pesquisa quantitativa. Onde foram comparados os dados coletados da pesquisa de campo com os modelos te?ricos descrito no trabalho acad?mico, a partir de uma investiga??o bibliogr?fica sobre o tema em quest?o. A experi?ncia direta do estagi?rio na empresa colaborou com a compreens?o das an?lises feitas sobre o problema estudado chegando, portanto, aos resultados obtidos

    Alternative Biodefensive based on the Essential Oil from Allium sativum Encapsulated in PCL/Gelatin Nanoparticles

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    The goal of this paper was to develop a biodegradable system containing the essential oil from Allium sativum bulbs encapsulated in PCL/gelatin-based nanoparticles, as well as evaluate its efficiency to control Aedes aegypti Linn. larvae and Cerataphis lataniae Bois. aphids. The essential oil was analyzed by GC-FID and GC-MS, and six compounds were identified, representing 93.1% of the total oil. The major compounds were diallyl trisulfide (51.8%), diallyl disulfide (23.2%) and allyl methyl trisulfide (13.6%). The PCL/gelatin-based nanoparticles containing this essential oil exhibited encapsulation efficiency higher than 94%, average particle diameter around 200 nm and zeta potential values about -36 mV. The essential oil presented no antioxidant nor enzymatic activities, so its effectiveness might be explained by the presence of sulfur compounds. The release kinetics of the encapsulated essential oil confirmed the release mechanism by the Fick's Law. About 50% of the encapsulated essential oil was released after 1 h, and about 90% was released after 50 h. This behavior is interesting from the technological point of view since the nanoparticles released as much oil as possible in a short period of time and then the lethal dosages were maintained along the time. Nanoparticles containing the encapsulated essential oil was submitted to in vitro bioassays against A. aegypti and C. lataniae and showed 100% of mortality against larvae and aphids up to 24 h. In conclusion, the essential oil from A. sativum presented effectiveness to be applied in sustainable management of pests in greenhouses, as well as for larvicidal control

    Comparing laser induced breakdown spectroscopy, near infrared spectroscopy, and their integration for simultaneous multi-elemental determination of micro- and macronutrients in vegetable samples

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    Laser-induced breakdown spectroscopy (LIBS) is an appealing analytical technique for simultaneous multi-elemental analysis. Near-infrared spectroscopy (NIRS) has also been suggested for the same purpose, mainly for vegetable samples. However, LIBS has failed to provide adequate results in many cases due to sample matrix complexity, and NIRS performance is harmed because of its lack of sensitivity and indirect correlation with inorganic elemental species. In this work, the performance of these two techniques are compared for the determination of micro- and macroelements in vegetable samples (Brachiaria forages) using multivariate regression. In addition, a data fusion scheme, in which spectral data sourced by NIRS is integrated with LIBS, is proposed to improve elemental content determination in those samples. The information of the molecular composition detected by NIR vibrational spectroscopy was consistently selected by recursive partial least squares to yield quantitative multivariate models for K, Ca, Mg, Mn and Fe in forage plants that are superior to models based on the use of individual NIRS and LIBS spectral information. While all data fusion models showed better predictive accuracy than any of the two individual techniques, best results were observed for Ca. This suggests that matrix composition affects each element determination by LIBS distinctively and supports the idea that a successful quantitative data fusion strategy for LIBS requires a technique such as NIRS which is sensitive to this variability10622836465768/2014-8; 134662/2015–6; 165274/2015–82014/50951-4This work was supported by the National Institute of Advanced Analytical Science and Technology (INCTAA, CNPq proc. 465768/2014-8, FAPESP 2014/50951-4). Authors are thankful to the GEAtom group from the Chemistry Institute at UNICAMP for helping with the ICP OES analyses, and to Dr. Gilberto Batista de Souza from EMBRAPA Sudeste for supplying the forage samples. DMO and LMF thank CNPq for the master's graduate research (proc. no. 134662/2015–6) and post-doctoral fellowships (proc. no. 165274/2015–8), respectivel

    A Simple Device For Lens-to-sample Distance Adjustment In Laser-induced Breakdown Spectroscopy (libs)

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    Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)A simple device based on two commercial laser pointers is described to assist in the analysis of samples that present uneven surfaces and/or irregular shapes using laser-induced breakdown spectroscopy (LIBS). The device allows for easy positioning of the sample surface at a reproducible distance from the focusing lens that conveys the laser pulse to generate the micro-plasma in a LIBS system, with reproducibility better than +/- 0.2 mm. In this way, fluctuations in the fluence (J cm(-2)) are minimized and the LIBS analytical signals can be obtained with a better precision even when samples with irregular surfaces are probed.714634639National Institute for Advanced Analytical Science and Technology (INCTAA) [FAPESP 2008/57808-1, CNPq 573894/2008-6]Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

    EXPERIÊNCIAS NO ENSINO SUPERIOR: OFICINA LÚDICA OU REVISÃO DE CONTEÚDO?

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    Trata-se de um relato de experiência vivenciado na semana de extensão do Campus Ceilândia da Universidade de Brasília desenvolvido na “Oficina: uso do Lúdico no ensino superior em enfermagem - uma práxis criativa e inovadora”. O objetivo foi aproximar os estudantes das atividades lúdicas na enfermagem, e também aplicar de forma prática e divertida os assuntos ministrados em sala de aula. Participaram da oficina 27 estudantes dentre estes alunos de enfermagem e farmácia com idade entre 18 e 25 anos. Foram-lhes apresentados três jogos, o jogo de computador “Imunização”, e os jogo de tabuleiro “Hipo/Hipertensão” e “ImunizAção”. Observou-se que durante as atividades, os alunos relembram e puderam desenvolver suas habilidades através do jogo, com temas diversos os jogos de tabuleiro despertaram curiosidade e entusiasmo. Atividades lúdicas contribuem para o aprendizado e tornam as aulas mais divertidas, despertam a curiosidade nos alunos, e apresentam uma forma inovadora para ministrar conteúdos

    Bioactivity of Licaria puchury-major Essential Oil Against Aedes aegypti , Tetranychus urticae and Cerataphis lataniae

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    The present study was carried out to evaluate an alternative controlling agent for greenhouse pests and the yellow fever mosquito larvae. The potential bioactivity of Licaria puchury-major (Mart.) Kosterm. (“puxuri”) was evaluated here against three most common pests in tropical and subtropical countries: Aedes aegypti Linn. Larvae, Tetranychus urticae Koch. mites and Cerataphis lataniae Boisd. aphids. The essential oil from seeds was analyzed by GC-FID and GC-MS. The major compounds were safrole (38.8%) and eucalyptol (21.7%). Phenylpropanes (51.7%) was the main group of compounds and oxygenated monoterpenes represented 28.8% of the total oil. The essential oil has shown no inhibition of acetylcholinesterase (AChE) in the tested concentrations. However, potential antioxidant activities were evaluated by different methods [DPPH: LD 50 = (27.8 ± 1.0) µg/.mL; ABTS: (977.3 ± 25.2) µM TEs/g (Trolox Equivalents); FRAP: (548.2 ± 29.0) µM Fe(II)/g]. A significant larvicidal potential for 24 h of exposure was observed with LD 50 = 98.9 µg/mL, being an indicative that the larval mortality may occur by ingestion or contact due to the no inhibition against AChE. Volatile phase effects were evaluated against T. urticae Koch. and C. lataniae Boisd. and LD 50 were found about 30.8 and 13.5 µg/mL , respectively. These results are consistent with an octopaminergic effect , since some phenylpropanoids (such as Safrole, identified as the major compound in this work) can block octopamine, a multi-functional, naturally occurring biogenic amine. Then, this study clearly illustrated the efficacy of the investigated seeds, which encourages the development of a new potential natural controlling agent against these common pests due to the abundance of these seeds in the Amazon region and to the high essential oil yield

    The genetic architecture of phosphorus efficiency in sorghum involves pleiotropic QTL for root morphology and grain yield under low phosphorus availability in the soil

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    Abstract Background Phosphorus (P) fixation on aluminum (Al) and iron (Fe) oxides in soil clays restricts P availability for crops cultivated on highly weathered tropical soils, which are common in developing countries. Hence, P deficiency becomes a major obstacle for global food security. We used multi-trait quantitative trait loci (QTL) mapping to study the genetic architecture of P efficiency and to explore the importance of root traits on sorghum grain yield on a tropical low-P soil. Results P acquisition efficiency was the most important component of P efficiency, and both traits were highly correlated with grain yield under low P availability. Root surface area was positively associated with grain yield. The guinea parent, SC283, contributed 58% of all favorable alleles detected by single-trait mapping. Multi-trait mapping detected 14 grain yield and/or root morphology QTLs. Tightly linked or pleiotropic QTL underlying the surface area of fine roots (1–2 mm in diameter) and grain yield were detected at positions 1–7 megabase pairs (Mb) and 71 Mb on chromosome 3, respectively, and a root diameter/grain yield QTL was detected at 7 Mb on chromosome 7. All these QTLs were near sorghum homologs of the rice serine/threonine kinase, OsPSTOL1. The SbPSTOL1 genes on chromosome 3, Sb03g006765 at 7 Mb and Sb03g031690 at 60 Mb were more highly expressed in SC283, which donated the favorable alleles at all QTLs found nearby SbPSTOL1 genes. The Al tolerance gene, SbMATE, may also influence a grain yield QTL on chromosome 3. Another PSTOL1-like gene, Sb07g02840, appears to enhance grain yield via small increases in root diameter. Co-localization analyses suggested a role for other genes, such as a sorghum homolog of the Arabidopsis ubiquitin-conjugating E2 enzyme, phosphate 2 (PHO2), on grain yield advantage conferred by the elite parent, BR007 allele. Conclusions Genetic determinants conferring higher root surface area and slight increases in fine root diameter may favor P uptake, thereby enhancing grain yield under low-P availability in the soil. Molecular markers for SbPSTOL1 genes and for QTL increasing grain yield by non-root morphology-based mechanisms hold promise in breeding strategies aimed at developing sorghum cultivars adapted to low-P soils
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