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Ozone production in four major cities of China: sensitivity to ozone precursors and heterogeneous processes
Abstract. Despite a large volume of research over a number of years, our understandings of the key precursors that control tropospheric ozone production and the impacts of heterogeneous processes remain incomplete. In this study, we analyze measurements of ozone and its precursors made at rural/suburban sites downwind of four large Chinese cities â Beijing, Shanghai, Guangzhou and Lanzhou. At each site the same measurement techniques were utilized and a photochemical box model based on the Master Chemical Mechanism (v3.2) was applied, to minimize uncertainties in comparison of the results due to differences in methodology. All four cities suffered from severe ozone pollution. At the rural site of Beijing, export of the well-processed urban plumes contributed to the extremely high ozone levels (up to an hourly value of 286 ppbv), while the pollution observed at the suburban sites of Shanghai, Guangzhou and Lanzhou was characterized by intense in-situ ozone production. The major anthropogenic hydrocarbons were alkenes and aromatics in Beijing and Shanghai, aromatics in Guangzhou, and alkenes in Lanzhou. The ozone production was found to be in a VOCs-limited regime in both Shanghai and Guangzhou, and a mixed regime in Lanzhou. In Shanghai, the ozone formation was most sensitive to aromatics and alkenes, while in Guangzhou aromatics were the predominant ozone precursors. In Lanzhou, either controlling NOx or reducing emissions of olefins from the petrochemical industry would mitigate the local ozone production. The potential impacts of several heterogeneous processes on the ozone formation were assessed. The hydrolysis of dinitrogen pentoxide (N2O5), uptake of the hydroperoxyl radical (HO2) on particles, and surface reactions of NO2 forming nitrous acid (HONO) present considerable sources of uncertainty in the current studies of ozone chemistry. Further efforts are urgently required to better understand these processes and refine atmospheric models
A study of the Relationship Between the Microwave and Meter-Wavelength Emissions from the Solar Flare on June 3, 2021
We present the preliminary results of the flare analysis. The event took place on 3rd June 2021, at 01:36 UT. It was observed in microwaves by Siberian Radioheliograph (SRH) within the 3-6 GHz, Broadband Microwave Spectropolarimeter (BBMS) and in meter radio range by e-Callisto spectrograph network. We found several of the type III bursts and the type-J burst in the meter radio range. At the same time, only the one burst was detected in the averaged time profiles of microwaves emission. This one corresponds to the strongest type III radio burst. Using the images by SRH, we defined the two sources and analysis of the time profiles of them separately. This approach allowed us finding the microwave bursts associated with the radio bursts, which were not distinguished in averaged time profiles. The delays between microwave and meter radio emission obtained from observations were compared with the results of preliminary analysis of dynamic spectra in radio meter range
Microfluidic droplet grating for reconfigurable optical diffraction
Author name used in this publication: X. M. Zhang2009-2010 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Visualizing dimensionality reduction of systems biology data
One of the challenges in analyzing high-dimensional expression data is the
detection of important biological signals. A common approach is to apply a
dimension reduction method, such as principal component analysis. Typically,
after application of such a method the data is projected and visualized in the
new coordinate system, using scatter plots or profile plots. These methods
provide good results if the data have certain properties which become visible
in the new coordinate system and which were hard to detect in the original
coordinate system. Often however, the application of only one method does not
suffice to capture all important signals. Therefore several methods addressing
different aspects of the data need to be applied. We have developed a framework
for linear and non-linear dimension reduction methods within our visual
analytics pipeline SpRay. This includes measures that assist the interpretation
of the factorization result. Different visualizations of these measures can be
combined with functional annotations that support the interpretation of the
results. We show an application to high-resolution time series microarray data
in the antibiotic-producing organism Streptomyces coelicolor as well as to
microarray data measuring expression of cells with normal karyotype and cells
with trisomies of human chromosomes 13 and 21
Hydrostatic pressure does not cause detectable changes to survival of human retinal ganglion
Purpose: Elevated intraocular pressure (IOP) is a major risk factor for glaucoma. One consequence of raised IOP is that ocular tissues are subjected to increased hydrostatic pressure (HP). The effect of raised HP on stress pathway signaling and retinal ganglion cell (RGC) survival in the human retina was investigated. Methods: A chamber was designed to expose cells to increased HP (constant and fluctuating). Accurate pressure control (10-100mmHg) was achieved using mass flow controllers. Human organotypic retinal cultures (HORCs) from donor eyes (<24h post mortem) were cultured in serum-free DMEM/HamF12. Increased HP was compared to simulated ischemia (oxygen glucose deprivation, OGD). Cell death and apoptosis were measured by LDH and TUNEL assays, RGC marker expression by qRT-PCR (THY-1) and RGC number by immunohistochemistry (NeuN). Activated p38 and JNK were detected by Western blot. Results: Exposure of HORCs to constant (60mmHg) or fluctuating (10-100mmHg; 1 cycle/min) pressure for 24 or 48h caused no loss of structural integrity, LDH release, decrease in RGC marker expression (THY-1) or loss of RGCs compared with controls. In addition, there was no increase in TUNEL-positive NeuN-labelled cells at either time-point indicating no increase in apoptosis of RGCs. OGD increased apoptosis, reduced RGC marker expression and RGC number and caused elevated LDH release at 24h. p38 and JNK phosphorylation remained unchanged in HORCs exposed to fluctuating pressure (10-100mmHg; 1 cycle/min) for 15, 30, 60 and 90min durations, whereas OGD (3h) increased activation of p38 and JNK, remaining elevated for 90min post-OGD. Conclusions: Directly applied HP had no detectable impact on RGC survival and stress-signalling in HORCs. Simulated ischemia, however, activated stress pathways and caused RGC death. These results show that direct HP does not cause degeneration of RGCs in the ex vivo human retina
A quantum crystallographic approach to short hydrogen bonds
In this work we use high-resolution synchrotron X-ray diffraction for electron density mapping, in conjunction with ab initio modelling, to study short OâHâŻO and O+âHâŻOâ hydrogen bonds whose behaviour is known to be tuneable by temperature. The short hydrogen bonds have donorâacceptor distances in the region of 2.45 Ă
and are formed in substituted urea and organic acid molecular complexes of N,Nâ˛-dimethylurea oxalic acid 2â:â1 (1), N,N-dimethylurea 2,4-dinitrobenzoate 1â:â1 (2) and N,N-dimethylurea 3,5-dinitrobenzoic acid 2â:â2 (3). From the combined analyses, these complexes are found to fall within the salt-cocrystal continuum and exhibit short hydrogen bonds that can be characterised as both strong and electrostatic (1, 3) or very strong with a significant covalent contribution (2). An additional charge assisted component is found to be important in distinguishing the relatively uncommon OâHâŻO pseudo-covalent interaction from a typical strong hydrogen bond. The electron density is found to be sensitive to the extent of static proton transfer, presenting it as a useful parameter in the study of the saltâcocrystal continuum. From complementary calculated hydrogen atom potentials, we attribute changes in proton position to the molecular environment. Calculated potentials also show zero barrier to proton migration, forming an âenergy slideâ between the donor and acceptor atoms. The better fundamental understanding of the short hydrogen bond in the âzone of fluctuationâ presented in a salt-cocrystal continuum, enabled by studies like this, provide greater insight into their related properties and can have implications in the regulation of pharmaceutical materials
Self-IQ-Demodulation Based Compensation Scheme of Frequency-Dependent IQ Imbalance for Wideband Direct-Conversion Transmitters
A low cost frequency-dependent (FD) I/Q imbalance self-compensation scheme is investigated in this paper. The direct conversion transmitters are widely used in wireless systems. However, the unwanted image-frequencies and distortions are inevitably introduced into the direct conversion system. This problem is even severer in wideband systems. Therefore, the accurate estimation and compensation of I/Q imbalance is crucial. The current compensation method is based on external instruments or internal feedback path which introduces additional impairments and is expensive. This paper proposes a low cost FD I/Q imbalance self-IQ-demodulation based compensation scheme without using external calibration instruments. First, the impairments of baseband and RF components are investigated. Further, I/Q imbalance model is developed. Then, the proposed two-step self-IQ-demodulation based compensation scheme is investigated. In the first step of the scheme, the local oscillator (LO) related I/Q impairments parameters are estimated. Then in the second step, the overall FD I/Q imbalance parameters are estimated by utilizing the transmitter LO. To realize this self-IQ-demodulation algorithm, this paper introduces minor modifications to the current power detector circuit. Afterwards, the estimated parameters are applied to the baseband equivalent compensator. This sophisticated algorithm guarantees low computation complexity and low cost. The compensation performance is evaluated in laboratory measurement
Satellite mapping in cities and below cities: how good is it now?
Global navigation satellite systems (GNSS) have existed since the launch of the US global positioning system constellation in 1978. There is an increasing need for better maps in the digital age, particularly for buried utilities. One of the most convenient methods for creating accurate maps is the use of navigation satellites for positioning. However, built-up urban areas are not ideal for the use of this positioning technology. This paper provides an update on the situation regarding GNSS and assesses how new satellites and signals are contributing to better positioning availability by carrying out a test in a controlled environment. The results show that using combined satellite systems improves availability in urban canyons in some cases, but not in all scenarios. In addition, pipeline mapping technology has been tested and been shown to be an effective means of mapping pipes deep under the ground over short distances
Observation of a ppb mass threshoud enhancement in \psi^\prime\to\pi^+\pi^-J/\psi(J/\psi\to\gamma p\bar{p}) decay
The decay channel
is studied using a sample of events collected
by the BESIII experiment at BEPCII. A strong enhancement at threshold is
observed in the invariant mass spectrum. The enhancement can be fit
with an -wave Breit-Wigner resonance function with a resulting peak mass of
and a
narrow width that is at the 90% confidence level.
These results are consistent with published BESII results. These mass and width
values do not match with those of any known meson resonance.Comment: 5 pages, 3 figures, submitted to Chinese Physics
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