319 research outputs found
Optimizing the Stark-decelerator beamline for the trapping of cold molecules using evolutionary strategies
We demonstrate feedback control optimization for the Stark deceleration and
trapping of neutral polar molecules using evolutionary strategies. In a
Stark-decelerator beamline pulsed electric fields are used to decelerate OH
radicals and subsequently store them in an electrostatic trap. The efficiency
of the deceleration and trapping process is determined by the exact timings of
the applied electric field pulses. Automated optimization of these timings
yields an increase of 40 % of the number of trapped OH radicals.Comment: 7 pages, 4 figures (RevTeX) (v2) minor corrections (v3) no changes to
manuscript, but fix author list in arXiv abstrac
Epitaxy and magnetotransport of Sr_2FeMoO_6 thin films
By pulsed-laser deposition epitaxial thin films of Sr_2FeMoO_6 have been pre-
pared on (100) SrTiO_3 substrates. Already for a deposition temperature of 320
C epitaxial growth is achieved. Depending on deposition parameters the films
show metallic or semiconducting behavior. At high (low) deposition temperature
the Fe,Mo sublattice has a rock-salt (random) structure. The metallic samples
have a large negative magnetoresistance which peaks at the Curie temperature.
The magnetic moment was determined to 4 mu_B per formula unit (f.u.), in
agreement with the expected value for an ideal ferrimagnetic arrangement. We
found an ordinary Hall coefficient of -6.01x10^{-10} m^3/As at 300 K,
corresponding to an electronlike charge-carrier density of 1.3 per Fe,Mo-pair.
In the semiconducting films the magnetic moment is reduced to 1 mu_B/f.u. due
to disorder in the Fe,Mo sublattice. In low fields an anomalous holelike
contribution dominates the Hall voltage, which vanishes at low temperatures for
the metallic films only.Comment: Institute of Physics, University of Mainz, Germany, 4 pages,
including 5 pictures and 1 Table, submitted to Phys. Rev.
Fermi surface induced lattice distortion in NbTe
The origin of the monoclinic distortion and domain formation in the quasi
two-dimensional layer compound NbTe is investigated. Angle-resolved
photoemission shows that the Fermi surface is pseudogapped over large portions
of the Brillouin zone. Ab initio calculation of the electron and phonon
bandstructure as well as the static RPA susceptibility lead us to conclude that
Fermi surface nesting and electron-phonon coupling play a key role in the
lowering of the crystal symmetry and in the formation of the charge density
wave phase
Two-Dimensional Spectroscopy of Extended Molecular Systems: Applications to Energy Transport and Relaxation in an α-Helix
A simulation study of the coupled dynamics of amide I and amide II vibrations in an α-helix dissolved in water shows that two-dimensional (2D) infrared spectroscopy may be used to disentangle the energy transport along the helix through each of these modes from the energy relaxation between them. Time scales for both types of processes are obtained. Using polarization-dependent 2D spectroscopy is an important ingredient in the method we propose. The method may also be applied to other two-band systems, both in the infrared (collective vibrations) and the visible (excitons) parts of the spectrum.
Encoding a qubit into multilevel subspaces
We present a formalism for encoding the logical basis of a qubit into
subspaces of multiple physical levels. The need for this multilevel encoding
arises naturally in situations where the speed of quantum operations exceeds
the limits imposed by the addressability of individual energy levels of the
qubit physical system. A basic feature of the multilevel encoding formalism is
the logical equivalence of different physical states and correspondingly, of
different physical transformations. This logical equivalence is a source of a
significant flexibility in designing logical operations, while the multilevel
structure inherently accommodates fast and intense broadband controls thereby
facilitating faster quantum operations. Another important practical advantage
of multilevel encoding is the ability to maintain full quantum-computational
fidelity in the presence of mixing and decoherence within encoding subspaces.
The formalism is developed in detail for single-qubit operations and
generalized for multiple qubits. As an illustrative example, we perform a
simulation of closed-loop optimal control of single-qubit operations for a
model multilevel system, and subsequently apply these operations at finite
temperatures to investigate the effect of decoherence on operational fidelity.Comment: IOPart LaTeX, 2 figures, 31 pages; addition of a numerical simulatio
Photon echo studies of photosynthetic light harvesting
The broad linewidths in absorption spectra of photosynthetic complexes obscure information related to their structure and function. Photon echo techniques represent a powerful class of time-resolved electronic spectroscopy that allow researchers to probe the interactions normally hidden under broad linewidths with sufficient time resolution to follow the fastest energy transfer events in light harvesting. Here, we outline the technical approach and applications of two types of photon echo experiments: the photon echo peak shift and two-dimensional (2D) Fourier transform photon echo spectroscopy. We review several extensions of these techniques to photosynthetic complexes. Photon echo peak shift spectroscopy can be used to determine the strength of coupling between a pigment and its surrounding environment including neighboring pigments and to quantify timescales of energy transfer. Two-dimensional spectroscopy yields a frequency-resolved map of absorption and emission processes, allowing coupling interactions and energy transfer pathways to be viewed directly. Furthermore, 2D spectroscopy reveals structural information such as the relative orientations of coupled transitions. Both classes of experiments can be used to probe the quantum mechanical nature of photosynthetic light-harvesting: peak shift experiments allow quantification of correlated energetic fluctuations between pigments, while 2D techniques measure quantum beating directly, both of which indicate the extent of quantum coherence over multiple pigment sites in the protein complex. The mechanistic and structural information obtained by these techniques reveals valuable insights into the design principles of photosynthetic light-harvesting complexes, and a multitude of variations on the methods outlined here
Suppression of quantum oscillations and the dependence on site energies in electronic excitation transfer in the Fenna-Matthews-Olson trimer
Energy transfer in the photosynthetic complex of the Green Sulfur Bacteria
known as the Fenna-Matthews-Olson (FMO) complex is studied theoretically taking
all three subunits (monomers) of the FMO trimer and the recently found eighth
bacteriochlorophyll (BChl) molecule into account. We find that in all
considered cases there is very little transfer between the monomers. Since it
is believed that the eighth BChl is located near the main light harvesting
antenna we look at the differences in transfer between the situation when BChl
8 is initially excited and the usually considered case when BChl 1 or 6 is
initially excited. We find strong differences in the transfer dynamics, both
qualitatively and quantitatively. When the excited state dynamics is
initialized at site eight of the FMO complex, we see a slow exponential-like
decay of the excitation. This is in contrast to the oscillations and a
relatively fast transfer that occurs when only seven sites or initialization at
sites 1 and 6 is considered. Additionally we show that differences in the
values of the electronic transition energies found in the literature lead to a
large difference in the transfer dynamics
Quantum entanglement in photosynthetic light harvesting complexes
Light harvesting components of photosynthetic organisms are complex, coupled,
many-body quantum systems, in which electronic coherence has recently been
shown to survive for relatively long time scales despite the decohering effects
of their environments. Within this context, we analyze entanglement in
multi-chromophoric light harvesting complexes, and establish methods for
quantification of entanglement by presenting necessary and sufficient
conditions for entanglement and by deriving a measure of global entanglement.
These methods are then applied to the Fenna-Matthews-Olson (FMO) protein to
extract the initial state and temperature dependencies of entanglement. We show
that while FMO in natural conditions largely contains bipartite entanglement
between dimerized chromophores, a small amount of long-range and multipartite
entanglement exists even at physiological temperatures. This constitutes the
first rigorous quantification of entanglement in a biological system. Finally,
we discuss the practical utilization of entanglement in densely packed
molecular aggregates such as light harvesting complexes.Comment: 14 pages, 7 figures. Improved presentation, published versio
Experimental and theoretical study of α–Eu2(MoO4)3 under compression
The compression process in the α-phase of europium trimolybdate was revised employing
several experimental techniques. X-ray diffraction (using synchrotron and laboratory radiation
sources), Raman scattering and photoluminescence experiments were performed up to a
maximum pressure of 21 GPa. In addition, the crystal structure and Raman mode frequencies
have been studied by means of first-principles density functional based methods. Results
suggest that the compression process of α-Eu2(MoO4)3 can be described by three stages.
Below 8 GPa, the α-phase suffers an isotropic contraction of the crystal structure. Between
8 and 12 GPa, the compound undergoes an anisotropic compression due to distortion and
rotation of the MoO4 tetrahedra. At pressures above 12 GPa, the amorphization process starts
without any previous occurrence of a crystalline-crystalline phase transition in the whole range
of pressure. This behavior clearly differs from the process of compression and amorphization
in trimolybdates with β′-phase and tritungstates with α-phase.We thank Diamond Light Source for access to beamline I15 (EE1746) that contributed to the results presented here. Part of the diffraction measurements were performed at the 'Servicio Integrado de Difraccion de Rayos X (SIDIX)' of University of La Laguna. This work has been supported by Ministerio de Economia y Competitividad of Spain (MINECO) for the research projects through the National Program of Materials (MAT2010-21270-C04-01/02/03/04, MAT2013-46649-C41/2/3/4-P and MAT2013-43319-P), the Consolider-Ingenio 2010 MALTA (CSD2007-00045), the project of Generalitat Valenciana (GVA-ACOMP/2014/243) and by the European Union FEDER funds. C Guzman-Afonso wishes to thank ACIISI and FSE for a fellowship. J A Sans thanks the FPI and 'Juan de la Cierva' programs for fellowships.Guzmán-Afonso, C.; León-Luis, S.; Sans-Tresserras, JÁ.; González -Silgo, C.; Rodríguez-Hernández, P.; Radescu, S.; muñoz, A.... (2015). Experimental and theoretical study of α–Eu2(MoO4)3 under compression. Journal of Physics: Condensed Matter. 27(46):465401-1-465401-11. https://doi.org/10.1088/0953-8984/27/46/465401S465401-1465401-11274
Effect of Dopants on Zirconia Stabilization—An X-ray Absorption Study: I, Trivalent Dopants
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/65562/1/j.1151-2916.1994.tb06964.x.pd
- …