Growth and optical properties of GaN/AlN quantum wells

We demonstrate the growth of GaN/AlN quantum well structures by plasma-assisted molecular-beam epitaxy by taking advantage of the surfactant effect of Ga. The GaN/AlN quantum wells show photoluminescence emission with photon energies in the range between 4.2 and 2.3 eV for well widths between 0.7 and 2.6 nm, respectively. An internal electric field strength of $9.2\pm 1.0$ MV/cm is deduced from the dependence of the emission energy on the well width.Comment: Submitted to AP

Comércio Justo como Estratégia de Internacionalização de Pequenos Negócios: Empoderamento para as Rendeiras da Arte Renascença no Semi-Árido Pernambucano

A pesquisa foi realizada com o fito de avaliar as reais possibilidades das mulheres que produzem rendas no agreste pernambucano virem a internacionalizar sua produção se beneficiando do comércio justo como forma de adquirir maior autonomia frente aos atravessadores que exploram naquela região a mão-de-obra local. A metodologia utilizada consistiu em repertoriar as principais dificuldades da comunidade rendeira nos municípios de Pesqueira, Poção e adjacências que respondem por mais de 80% da renda renascença produzida no Brasil e em contra-ponto, compreender, mediante pesquisa de campo, os mecanismos que regem o comércio justo na Europa, em particular na França, onde foram contactados no período de maio de 2008 à julho de 2009 inúmeros agentes atuando na comercialização de produtos do comércio alternativo. Em conclusão, descobriu-se que dentre os atores da filière équitable os principais influenciadores eram os importadores europeus que mantinham relações estreitas com as comunidades produtoras nos paises do Sul. Para as rendeiras do agreste, ficou claro que suas melhores chances em participar do movimento encontram-se na moda ética (peças confeccionadas com algodão orgânico) em plena expansão na Europa.Comércio justo, internacionalização, intermediários, renda renascença

Step by step capping and strain state of GaN/AlN quantum dots studied by grazing incidence diffraction anomalous fine structure

The investigation of small size embedded nanostructures, by a combination of complementary anomalous diffraction techniques, is reported. GaN Quantum Dots (QDs), grown by molecular beam epitaxy in a modified Stranski-Krastanow mode, are studied in terms of strain and local environment, as a function of the AlN cap layer thickness, by means of grazing incidence anomalous diffraction. That is, the X-ray photons energy is tuned across the Ga absorption K-edge which makes diffraction chemically selective. Measurement of \textit{hkl}-scans, close to the AlN (30-30) Bragg reflection, at several energies across the Ga K-edge, allows the extraction of the Ga partial structure factor, from which the in-plane strain of GaN QDs is deduced. From the fixed-Q energy-dependent diffracted intensity spectra, measured for diffraction-selected iso-strain regions corresponding to the average in-plane strain state of the QDs, quantitative information regarding composition and the out-of-plane strain has been obtained. We recover the in-plane and out-of-plane strains in the dots. The comparison to the biaxial elastic strain in a pseudomorphic layer indicates a tendency to an over-strained regime.Comment: submitted to PR

First results obtained using the CENBG nanobeam line: performances and applications

A high resolution focused beam line has been recently installed on the AIFIRA (“Applications Interdisciplinaires des Faisceaux d’Ions en Région Aquitaine”) facility at CENBG. This nanobeam line, based on a doublet–triplet configuration of Oxford Microbeam Ltd. OM-50™ quadrupoles, offers the opportunity to focus protons, deuterons and alpha particles in the MeV energy range to a sub-micrometer beam spot. The beam optics design has been studied in detail and optimized using detailed ray-tracing simulations and the full mechanical design of the beam line was reported in the Debrecen ICNMTA conference in 2008. During the last two years, the lenses have been carefully aligned and the target chamber has been fully equipped with particle and X-ray detectors, microscopes and precise positioning stages. The beam line is now operational and has been used for its firstapplications to ion beam analysis. Interestingly, this set-up turned out to be a very versatile tool for a wide range of applications. Indeed, even if it was not intended during the design phase, the ion optics configuration offers the opportunity to work either with a high current microbeam (using the triplet only) or with a lower current beam presenting a sub-micrometer resolution (using the doublet–triplet configuration). The performances of the CENBGnanobeam line are presented for both configurations. Quantitative data concerning the beam lateral resolutions at different beam currents are provided. Finally, the firstresults obtained for different types of application are shown, including nuclear reaction analysis at the micrometer scale and the firstresults on biological sample

Chr21 protein–protein interactions: enrichment in proteins involved in intellectual disability, autism, and late-onset Alzheimer’s disease

Down syndrome (DS) is caused by human chromosome 21 (HSA21) trisomy. It is characterized by a poorly understood intellectual disability (ID). We studied two mouse models of DS, one with an extra copy of the Dyrk1A gene (189N3) and the other with an extra copy of the mouse Chr16 syntenic region (Dp(16)1Yey). RNA-seq analysis of the transcripts deregulated in the embryonic hippocampus revealed an enrichment in genes associated with chromatin for the 189N3 model, and synapses for the Dp(16)1Yey model. A large-scale yeast two-hybrid screen (82 different screens, including 72 HSA21 baits and 10 rebounds) of a human brain library containing at least 107 independent fragments identified 1,949 novel protein–protein interactions. The direct interactors of HSA21 baits and rebounds were significantly enriched in ID-related genes (P-value < 2.29 × 10−8). Proximity ligation assays showed that some of the proteins encoded by HSA21 were located at the dendritic spine postsynaptic density, in a protein network at the dendritic spine postsynapse. We located HSA21 DYRK1A and DSCAM, mutations of which increase the risk of autism spectrum disorder (ASD) 20-fold, in this postsynaptic network. We found that an intracellular domain of DSCAM bound either DLGs, which are multimeric scaffolds comprising receptors, ion channels and associated signaling proteins, or DYRK1A. The DYRK1A-DSCAM interaction domain is conserved in Drosophila and humans. The postsynaptic network was found to be enriched in proteins associated with ARC-related synaptic plasticity, ASD, and late-onset Alzheimer’s disease. These results highlight links between DS and brain diseases with a complex genetic basis

Technical developments for computed tomography on the CENBG nanobeam line

The use of ion microbeams as probes for computedtomography has proven to be a powerful tool for the three-dimensional characterization of specimens a few tens of micrometers in size. Compared to other types of probes, the main advantage is that quantitative information about mass density and composition can be obtained directly, using specific reconstruction codes. At the Centre d’Etudes Nucléaires de Bordeaux Gradignan (CENBG), this technique was initially developed for applications in cellular biology. However, the observation of the cell ultrastructure requires a sub-micron resolution. The construction of the nanobeamline at the Applications Interdisciplinaires des Faisceaux d’Ions en Region Aquitaine (AIFIRA) irradiation facility has opened new perspectives for such applications. The implementation of computedtomography on the nanobeamline of CENBG has required a careful design of the analysis chamber, especially microscopes for precise sample visualization, and detectors for scanning transmission ion microscopy (STIM) and for particle induced X-ray emission (PIXE). The sample can be precisely positioned in the three directions X, Y, Z and a stepper motor coupled to a goniometer ensures the rotational motion. First images of 3D tomography were obtained on a reference sample containing microspheres of certified diameter, showing the good stability of the beam and the sample stage, and the precision of the motion

Particle-induced morphological modification of Al alloy equiaxed dendrites revealed by sub-second in situ microtomography

The study of dendritic growth is a challenging topic at the heart of intense research in material science. Understanding such processes is of prime importance as it helps predicting the final microstructure governing material properties. In the specific case of the design of metal-matrix nanocomposites (MMNCs), the addition of nano-sized particles inside the metallic melt increases the complexity as their influence on the growth morphology of dendrites is not yet fully understood. In the present experimental study, we use in situ X-ray tomography imaging with very high temporal resolution (0.35 s per 3D image) coupled with in situ ultrasonic melt homogenisation to record, in 3D and real time, the free growth at high cooling rates (~2 K.s-1) of equiaxed dendrites in an AA6082 alloy containing Y2O3 nanoparticles. The careful 3D analysis of the dendrite morphologies as well as their solidification dynamics reveals that in the case of well-dispersed particles, dendrite equiaxed growth occurs through complex hyper-branched morphologies. Such behaviour is believed to arise from particle-induced modification of the solidification processes at the origin of multiple splitting, branching and curving mechanisms of the dendrite arms. These results shed light on long-standing empirical and modelling statements and open new ways for direct investigation of equiaxed growth in metallic alloys and composites.European Commission in the 7th Framework Program (contract FP7-NMP3-LA-2012-280421) ExoMet Project by the European Space Agency and by the individual partner organizations; ESRF-MA1876 long term project