918 research outputs found
Elastic and magnetic effects on the infrared phonon spectra of MnF2
We measured the temperature dependent infrared reflectivity spectra of MnF2
between 4 K and room temperature. We show that the phonon spectrum undergoes a
strong renormalization at TN. The ab-initio calculation we performed on this
compound accurately predict the magnitude and the direction of the phonon
parameters changes across the antiferromagnetic transition, showing that they
are mainly induced by the magnetic order. In this material, we found that the
dielectric constant is mostly from phonon origin. The large change in the
lattice parameters with temperature seen by X-ray diffraction as well as the
A2u phonon softening below TN indicate that magnetic order induced distortions
in MnF2 are compatible with the ferroelectric instabilities observed in TiO2,
FeF2 and other rutile-type fluorides. This study also shows the anomalous
temperature evolution of the lower energy Eu mode in the paramagnetic phase,
which can be compared to that of the B1g one seen by Raman spectroscopy in many
isostructural materials. This was interpreted as being a precursor of a phase
transition from rutile to CaCl2 structure which was observed under pressure in
ZnF2.Comment: 8 pages, 8 figures, updated version accepted in PR
Giant electrocaloric response in the prototypical Pb(Mg,Nb)O relaxor ferroelectric from atomistic simulations
An atomistic effective Hamiltonian is used to investigate electrocaloric (EC)
effects of Pb(MgNb)O (PMN) relaxor ferroelectrics in its
ergodic regime, and subject to electric fields applied along the pseudocubic
[111] direction. Such Hamiltonian qualitatively reproduces (i) the electric
field-versus-temperature phase diagram, including the existence of a critical
point where first-order and second-order transitions meet each other; and (ii)
a giant EC response near such critical point. It also reveals that such giant
response around this critical point is microscopically induced by field-induced
percolation of polar nanoregions. Moreover, it is also found that, for any
temperature above the critical point, the EC coefficient-versus-electric field
curve adopts a maximum (and thus larger electrocaloric response too), that can
be well described by the general Landau-like model proposed in [Jiang et al,
Phys. Rev. B 96, 014114 (2017)] and that is further correlated with specific
microscopic features related to dipoles lying along different rhombohedral
directions. Furthermore, for temperatures being at least 40 K higher than the
critical temperature, the (electric field, temperature) line associated with
this maximal EC coefficient is below both the Widom line and the line
representing percolation of polar nanoregions.Comment: 6 pages, 5 figure
Geoclimatic, demographic and socioeconomic characteristics related to dengue outbreaks in Southeastern Brazil: an annual spatial and spatiotemporal risk model over a 12-year period
Dengue fever is re-emerging worldwide, however the reasons of this new emergence are not fully understood. Our goal was to report the incidence of dengue in one of the most populous States of Brazil, and to assess the high-risk areas using a spatial and spatio-temporal annual models including geoclimatic, demographic and socioeconomic characteristics. An ecological study with both, a spatial and a temporal component was carried out in Sao Paulo State, Southeastern Brazil, between January 1st, 2007 and December 31st, 2019. Crude and Bayesian empirical rates of dengue cases following by Standardized Incidence Ratios (SIR) were calculated considering the municipalities as the analytical units and using the Integrated Nested Laplace Approximation in a Bayesian context. A total of 2,027,142 cases of dengue were reported during the studied period. The spatial model allocated the municipalities in four groups according to the SIR values: (I) SIR<0.8; (II) SIR 0.8<1.2; (III) SIR 1.2<2.0 and SIR>2.0 identified the municipalities with higher risk for dengue outbreaks. “Hot spots” are shown in the thematic maps. Significant correlations between SIR and two climate variables, two demographic variables and one socioeconomical variable were found. No significant correlations were found in the spatio-temporal model. The incidence of dengue exhibited an inconstant and unpredictable variation every year. The highest rates of dengue are concentrated in geographical clusters with lower surface pressure, rainfall and altitude, but also in municipalities with higher degree of urbanization and better socioeconomic conditions. Nevertheless, annual consolidated variations in climatic features do not influence in the epidemic yearly pattern of dengue in southeastern Brazil
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