Multiple-clause constituent questions: intonation and variation in Hungarian

When a question phrase bears a grammatical function in a subordinate clause but the interrogativity it introduces extends over a higher clause, there are two main possibilities in Hungarian: (i) the question phrase appears preverbally in the clause over which it takes scope, or (ii) the question phrase appears in the subordinate clause while the scope of interrogativity is indicated by the presence of another question phrase in the higher clause (the scope-marking construction). In order to understand the features shared by these two types of question and the ways in which they differ, this article explores the intonation of these types of multiple-clause constituent questions in Hungarian. The results of experimental investigation are reported and discussed, and the significance of these findings is evaluated in the context of wider typological variation in the formation of multiple-clause constituent questions

Synthesis and Electronic Structure Determination of Uranium(VI) Ligand Radical Complexes

   Pentagonal bipyramidal uranyl complexes of salen ligands, N,N’-bis(3-tert-butyl-(5R)-salicylidene)-1,2-phenylenediamine, in which R = tBu (1a), OMe (1b), and NMe2 (1c), were prepared and the electronic structure of the one-electron oxidized species [1a-c]+ were investigated in solution. The solid-state structures of 1a and 1b were solved by X-ray crystallography, and in the case of 1b an asymmetric UO22+ unit was found due to an intermolecular hydrogen bonding interaction. Electrochemical investigation of 1a-c by cyclic voltammetry showed that each complex exhibited at least one quasi-reversible redox process assigned to the oxidation of the phenolate moieties to phenoxyl radicals. The trend in redox potentials matches the electron-donating ability of the para-phenolate substituents. The electron paramagnetic resonance spectra of cations [1a-c]+ exhibited gav values of 1.997, 1.999, and 1.995, respectively, reflecting the ligand radical character of the oxidized forms, and in addition, spin-orbit coupling to the uranium centre. Chemical oxidation as monitored by ultraviolet-visible-near-infrared (UV-vis-NIR) spectroscopy afforded the one-electron oxidized species. Weak low energy intra-ligand charge transfer (CT) transitions were observed for [1a-c]+ indicating localization of the ligand radical to form a phenolate / phenoxyl radical species. Further analysis using density functional theory (DFT) calculations predicted a localized phenoxyl radical for [1a-c]+ with a small but significant contribution of the phenylenediamine unit to the spin density. Time-dependent DFT (TD-DFT) calculations provided further insight into the nature of the low energy transitions, predicting both phenolate to phenoxyl intervalence charge transfer (IVCT) and phenylenediamine to phenoxyl CT character. Overall, [1a-c]+ are determined to be relatively localized ligand radical complexes, in which localization is enhanced as the electron donating ability of the para-phenolate substituents is increased (NMe2 > OMe > tBu)

Identification and Quantification of the Main Electrolyte Decomposition By-product in Na-Ion Batteries through FEC: Towards an Improvement of Safety and Lifetime

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Influence of optical excitation on the electric field assisted assembly of CdSe nanorods

International audienc

Transparent multilevel aligned electrode microfluidic chip for dielectrophoretic colloidal handling

International audienc

Colloidal optical waveguides with integrated local light sources built by capillary force assembly

International audienc