Chelate-modified polymers for atmospheric gas chromatography

Chromatographic materials were developed to serve as the stationary phase of columns used in the separation of atmospheric gases. These materials consist of a crosslinked porous polymer matrix, e.g., a divinylbenzene polymer, into which has been embedded an inorganic complexed ion such as N,N'-ethylene-bis-(acetylacetoniminato)-cobalt (2). Organic nitrogenous bases, such as pyridine, may be incorporated into the chelate polymer complexes to increase their chromatographic utility. With such materials, the process of gas chromatography is greatly simplified, especially in terms of time and quantity of material needed for a gas separation

Advanced space system concepts and their orbital support needs (1980 - 2000). Volume 1: Executive summary

The likely system concepts which might be representative of NASA and DoD space programs in the 1980-2000 time period were studied along with the programs' likely needs for major space transportation vehicles, orbital support vehicles, and technology developments which could be shared by the military and civilian space establishments in that time period. Such needs could then be used by NASA as an input in determining the nature of its long-range development plan. The approach used was to develop a list of possible space system concepts (initiatives) in parallel with a list of needs based on consideration of the likely environments and goals of the future. The two lists thus obtained represented what could be done, regardless of need; and what should be done, regardless of capability, respectively. A set of development program plans for space application concepts was then assembled, matching needs against capabilities, and the requirements of the space concepts for support vehicles, transportation, and technology were extracted. The process was pursued in parallel for likely military and civilian programs, and the common support needs thus identified

Advanced space system concepts and their orbital support needs (1980 - 2000). Volume 2: Final report

The results are presented of a study which identifies over 100 new and highly capable space systems for the 1980-2000 time period: civilian systems which could bring benefits to large numbers of average citizens in everyday life, much enhance the kinds and levels of public services, increase the economic motivation for industrial investment in space, expand scientific horizons; and, in the military area, systems which could materially alter current concepts of tactical and strategic engagements. The requirements for space transportation, orbital support, and technology for these systems are derived, and those requirements likely to be shared between NASA and the DoD in the time period identified. The high leverage technologies for the time period are identified as very large microwave antennas and optics, high energy power subsystems, high precision and high power lasers, microelectronic circuit complexes and data processors, mosaic solid state sensing devices, and long-life cryogenic refrigerators

Advanced space system concepts and their orbital support needs (1980 - 2000). Volume 3: Detailed data. Part 1: Catalog of initiatives, functional options, and future environments and goals

The following areas were discussed in relation to a study of the commonality of space vehicle applications to future national needs: (1) index of initiatives (civilian observation, communication, support), brief illustrated description of each initiative, time periods (from 1980 to 2000+) for implementation of these initiatives; (2) data bank of functional system options, presented in the form of data sheets, one for each of the major functions, with the system option for near-term, midterm, and far-term space projects applicable to each subcategory of functions to be fulfilled; (3) table relating initiatives and desired goals (public service and humanistic, materialistic, scientific and intellectual); and (4) data on size, weight and cost estimations

Seismic modelling and paleoceanography at DSDP Site 574

The analysis of high-resolution watergun seismic profiles collected in support of DSDP Leg 85 drilling reveals sev eral major, regionally traceable reflectors that can be correlated over more than 360,000 km2 in the central equatorial Pacific. Synthetic seismograms generated from shipboard physical property measurements (carefully corrected to in situ values) for DSDP Site 574 show excellent agreement with the field records; the agreement suggests that the traveltime to-depth conversion is accurate and permits the precise (± 5 m) location of reflectors in the cored section. The reflectors can be dated (±0.5 Ma) as follows: Orange, 21.5 to 22.5 Ma; Yellow, 20.5 to 21.5 Ma; Lavender, 16 to 17 Ma; Red, 13.5 to 14.5 Ma; Purple, 11 to 12 Ma; Brown, 7 to 8 Ma; and Green, 3 to 4 Ma. Similar analyses at the other Leg 85 sites result in identical ages. The reflectors are thus time surfaces; this chapter relates them to major paleoceanographic events and changes in the relative sea-level curve. The Orange and Yellow reflectors are associated with a marked increase in δ 1 3C, a major change in planktonic foraminiferal assemblages, the development of the deep Circum-Antarctic Current, and the establishment of steep thermal gradients between tropical and polar regions. This reorganization of the oceanic circulation system was probably a response to the opening of the Drake Passage, and it resulted in changes in the chemistry of tropical Pacific waters that caused the induration (and thus impedance contrasts) associated with these reflectors. The Lavender reflector is associated with a large carbonate minimum, the Chron 16 carbon shift, a widespread hiatus (NH2), major eustatic sea-level fluctuations, and a significant increase in silica deposition in the Pacific. It is not associated with 18O enrichment or climatic cooling. We conclude that this event represents an intensification in Antarc tic Bottom Water (AABW) circulation and the partitioning of silica between the Atlantic and the Pacific, caused by the introduction of North Atlantic Deep Water (NADW) in response to paleobathymetric and tectonic events. The Red re flector is associated with a subdued carbonate minimum, a widespread hiatus (NH3), a sea-level drop, significant changes in microfossil assemblages, and a major increase in δ 1 8 that has been linked with the buildup of Antarctic ice. Detailed isotopic analyses reveal that this isotopic shift occurred within an interval of 30,000 yr. and precisely at the depth of the Red reflector. The Purple reflector is associated with an extremely large carbonate minimum, a change in the style of carbonate deposition in the Pacific, a major lithologic boundary, a widespread hiatus (NH4), an increase in the provincialism be tween low and high latitudes in all planktonic microfossil assemblages, an apparent fall in eustatic sea level, an enrich ment in δ 1 8 , and a major North Atlantic reflector interpreted as representing an intensification of North Atlantic bot tom-water circulation. The Brown reflector is roughly associated with a small carbonate minimum, an enrichment in δ 1 8 , the late Miocene 1 3C depletion, a drop in the relative sea-level curve, and major faunal changes. The Green reflector is associated with a large carbonate minimum, an enrichment in δ 1 8 , a major western North Atlantic erosional event, and a widespread eastern Atlantic seismic reflector. The bulk of evidence supports correlation with the onset of Northern Hemisphere glaciation, but detailed isotopic analyses indicate that this isotopic event may be linked to the establishment of colder bottom waters without major ice-sheet development. Several types of reflectors have been identified. The reflectors in the older section result from diagenetic effects; the regionally correctable reflectors are associated with global events. In the younger (post-18 Ma) section, local reflectors are characterized by velocity contrasts, whereas regional reflectors are associated with density contrasts caused by car bonate minima. Two modes of generation of carbonate minima (and thus of reflectors) spanning the equatorial Pacific are (1) the intensification of AABW without the concurrent intensification of NADW and so without fractionation of silica between the Atlantic and the Pacific; this mode results in the less extreme carbonate minima; and (2) the intensifi cation of AABW in response to the intensification of NADW; this mode results in extreme carbonate minima and a cor relation of equatorial Pacific reflectors with North Atlantic events

Swarms: Optimum aggregations of spacecraft

Swarms are aggregations of spacecraft or elements of a space system which are cooperative in function, but physically isolated or only loosely connected. For some missions the swarm configuration may be optimum compared to a group of completely independent spacecraft or a complex rigidly integrated spacecraft or space platform. General features of swarms are induced by considering an ensemble of 26 swarms, examples ranging from Earth centered swarms for commercial application to swarms for exploring minor planets. A concept for a low altitude swarm as a substitute for a space platform is proposed and a preliminary design studied. The salient design feature is the web of tethers holding the 30 km swarm in a rigid two dimensional array in the orbital plane. A mathematical discussion and tutorial in tether technology and in some aspects of the distribution of services (mass, energy, and information to swarm elements) are included

Parametric instability in a free-evolving warped protoplanetary disc

Warped accretion discs of low viscosity are prone to hydrodynamic instability due to parametric resonance of inertial waves as confirmed by local simulations. Global simulations of warped discs, using either smoothed particle hydrodynamics (SPH) or grid-based codes, are ubiquitous but no such instability has been seen. Here we utilize a hybrid Godunov-type Lagrangian method to study parametric instability in global simulations of warped Keplerian discs at unprecedentedly high resolution (up to 120 million particles). In the global simulations, the propagation of the warp is well described by the linear bending-wave equations before the instability sets in. The ensuing turbulence, captured for the first time in a global simulation, damps relative orbital inclinations and leads to a decrease in the angular momentum deficit. As a result, the warp undergoes significant damping within one bending-wave crossing time. Observed protoplanetary disc warps are likely maintained by companions or aftermath of disc breaking

On the spectrum of Farey and Gauss maps

In this paper we introduce Hilbert spaces of holomorphic functions given by generalized Borel and Laplace transforms which are left invariant by the transfer operators of the Farey map and its induced version, the Gauss map, respectively. By means of a suitable operator-valued power series we are able to study simultaneously the spectrum of both these operators along with the analytic properties of the associated dynamical zeta functions.Comment: 23 page