270 research outputs found
Al<sub>5+α</sub>Si<sub>5+δ</sub>N<sub>12</sub>, a new Nitride compound
The family of III-Nitride semiconductors has been under intensive research for almost 30 years and has revolutionized lighting applications at the dawn of the 21st century. However, besides the developments and applications achieved, nitride alloys continue to fuel the quest for novel materials and applications. We report on the synthesis of a new nitride-based compound by using annealing of AlN heteroepitaxial layers under a Si-atmosphere at temperatures between 1350 °C and 1550 °C. The structure and stoichiometry of this compound are investigated by high resolution transmission electron microscopy (TEM) techniques and energy dispersive X-Ray (EDX) spectroscopy. Results are supported by density functional theory (DFT) calculations. The identified structure is a derivative of the parent wurtzite AlN crystal where the anion sublattice is fully occupied by N atoms and the cation sublattice is the stacking of 2 different planes along lt;0001gt;: The first one exhibits a ×3 periodicity along lt;11–20gt; with 1/3 of the sites being vacant. The rest of the sites in the cation sublattice are occupied by an equal number of Si and Al atoms. Assuming a semiconducting alloy, a range of stoichiometries is proposed, Al5+αSi5+δN12 with α being between −2/3 and 1/4 and δ between 0 and 3/4. © 2019, The Author(s)
Back-translation for discovering distant protein homologies
Frameshift mutations in protein-coding DNA sequences produce a drastic change
in the resulting protein sequence, which prevents classic protein alignment
methods from revealing the proteins' common origin. Moreover, when a large
number of substitutions are additionally involved in the divergence, the
homology detection becomes difficult even at the DNA level. To cope with this
situation, we propose a novel method to infer distant homology relations of two
proteins, that accounts for frameshift and point mutations that may have
affected the coding sequences. We design a dynamic programming alignment
algorithm over memory-efficient graph representations of the complete set of
putative DNA sequences of each protein, with the goal of determining the two
putative DNA sequences which have the best scoring alignment under a powerful
scoring system designed to reflect the most probable evolutionary process. This
allows us to uncover evolutionary information that is not captured by
traditional alignment methods, which is confirmed by biologically significant
examples.Comment: The 9th International Workshop in Algorithms in Bioinformatics
(WABI), Philadelphia : \'Etats-Unis d'Am\'erique (2009
Biochar a partir de biomassa de Miscanthus e Quebracho, produzido em forno tubular em sistema aberto e sob fluxo de nitrogênio.
bitstream/item/141831/1/Comunicado-Tecnico-375-2015.pd
The importance of major mergers in the build up of stellar mass in brightest cluster galaxies at z=1
Recent independent results from numerical simulations and observations have
shown that brightest cluster galaxies (BCGs) have increased their stellar mass
by a factor of almost two between z~0.9 and z~0.2. The numerical simulations
further suggest that more than half this mass is accreted through major
mergers. Using a sample of 18 distant galaxy clusters with over 600
spectroscopically confirmed cluster members between them, we search for
observational evidence that major mergers do play a significant role. We find a
major merger rate of 0.38 +/- 0.14 mergers per Gyr at z~1. While the
uncertainties, which stem from the small size of our sample, are relatively
large, our rate is consistent with the results that are derived from numerical
simulations. If we assume that this rate continues to the present day and that
half of the mass of the companion is accreted onto the BCG during these
mergers, then we find that this rate can explain the growth in the stellar mass
of the BCGs that is observed and predicted by simulations. Major mergers
therefore appear to be playing an important role, perhaps even the dominant
one, in the build up of stellar mass in these extraordinary galaxies.Comment: 15 pages, 6 figures, accepted for publication in MNRAS. Reduced data
will be made available through the ESO archiv
Self-healing capacity of nuclear glass observed by NMR spectroscopy
Safe management of high level nuclear waste is a worldwide significant issue for which vitrification has been selected by many countries. There exists a crucial need for improving our understanding of the ageing of the glass under irradiation. While external irradiation by ions provides a rapid simulation of damage induced by alpha decays, short lived actinide doping is more representative of the reality. Here, we report radiological NMR experiments to compare the damage in International Simplified Glass (ISG) when irradiated by these two methods. In the 0.1 mole percent 244Cm doped glass, accumulation of high alpha decay only shows small modifications of the local structure, in sharp contrast to heavy ion irradiation. These results reveal the ability of the alpha particle to partially repair the damage generated by the heavy recoil nuclei highlighting the radiation resistance of nuclear glass and the difficulty to accurately simulate its behaviour by single ion beam irradiations
Shear induced instabilities in layered liquids
Motivated by the experimentally observed shear-induced destabilization and
reorientation of smectic A like systems, we consider an extended formulation of
smectic A hydrodynamics. We include both, the smectic layering (via the layer
displacement u and the layer normal p) and the director n of the underlying
nematic order in our macroscopic hydrodynamic description and allow both
directions to differ in non equilibrium situations. In an homeotropically
aligned sample the nematic director does couple to an applied simple shear,
whereas the smectic layering stays unchanged. This difference leads to a finite
(but usually small) angle between n and p, which we find to be equivalent to an
effective dilatation of the layers. This effective dilatation leads, above a
certain threshold, to an undulation instability of the layers. We generalize
our earlier approach [Rheol. Acta, vol.39(3), 15] and include the cross
couplings with the velocity field and the order parameters for orientational
and positional order and show how the order parameters interact with the
undulation instability. We explore the influence of various material parameters
on the instability. Comparing our results to recent experiments and molecular
dynamic simulations, we find a good qualitative agreement.Comment: 15 pages, 12 figures, accepted for publication in PR
Shear instabilities of freely standing thermotropic smectic-A films
In this Letter we discuss theoretically the instabilities of thermotropic
freely standing smectic-A films under shear flow\cite{re:wu}. We show that, in
Couette geometry, the centrifugal force pushes the liquid crystal toward the
outer boundary and induces smectic layer dilation close to the outer boundary.
Under strong shear, this effect induces a layer buckling instability. The
critical shear rate is proportional to , where is the thickness
of the film.Comment: 12 pages, 2 figure
- …