1,320 research outputs found
Effective interactions in the colloidal suspensions from HNC theory
The HNC Ornstein-Zernike integral equations are used to determine the
properties of simple models of colloidal solutions where the colloids and ions
are immersed in a solvent considered as a dielectric continuum and have a size
ratio equal to 80 and a charge ratio varying between 1 and 4000. At an infinite
dilution of colloids, the effective interactions between colloids and ions are
determined for ionic concentrations ranging from 0.001 to 0.1 mol/l and
compared to those derived from the Poisson-Boltzmann theory. At finite
concentrations, we discuss on the basis of the HNC results the possibility of
an unambiguous definition of the effective interactions between the colloidal
molecules.Comment: 26 pages, 15 figure
Can neutral and ionized PAHs be carriers of the UV extinction bump and the diffuse interstellar bands?
Up to now, no laboratory-based study has investigated polycyclic aromatic
hydrocarbon (PAH) species as potential carriers of both the diffuse
interstellar bands (DIBs) and the 2175 A UV bump. We examined the proposed
correlation between these two features by applying experimental and theoretical
techniques on two specific medium-sized/large PAHs (dibenzorubicene C30H14 and
hexabenzocoronene C42H18) in their neutral and cationic states. It was already
shown that mixtures of sufficiently large, neutral PAHs can partly or even
completely account for the UV bump. We investigated how the absorption bands
are altered upon ionization of these molecules by interstellar UV photons. The
experimental studies presented here were realized by performing matrix
isolation spectroscopy with subsequent far-UV irradiation. The main effects
were found to be a broadening of the absorption bands in the UV combined with
slight red shifts. The position of the complete pi - pi* absorption structure
around 217.5 nm, however, remains more or less unchanged which could explain
the observed position invariance of the interstellar bump for different lines
of sight. This favors the assignment of this feature to the interstellar PAH
population. As far as the DIBs are concerned, neither our investigations nor
the laboratory studies carried out by other research groups support a possible
connection with this class of molecules. Instead, there are reasonable
arguments that neutral and singly ionized cationic PAHs cannot be made
responsible for the DIBs.Comment: 11 pages, 7 figures, 1 tabl
Prewetting transition on a weakly disordered substrate : evidence for a creeping film dynamics
We present the first microscopic images of the prewetting transition of a
liquid film on a solid surface. Pictures of the local coverage map of a helium
film on a cesium metal surface are taken while the temperature is raised
through the transition. The film edge is found to advance at constant
temperature by successive avalanches in a creep motion with a macroscopic
correlation length. The creep velocity varies strongly in a narrow temperature
range. The retreat motion is obtained only at much lower temperature,
conforming to the strong hysteresis observed for prewetting transition on a
disordered surface. Prewetting transition on such disordered surfaces appears
to give rise to dynamical phenomena similar to what is observed for domain wall
motions in 2D magnets.Comment: 7 pages, 3 figures, to be published in Euro.Phys.Let
A mean-field kinetic lattice gas model of electrochemical cells
We develop Electrochemical Mean-Field Kinetic Equations (EMFKE) to simulate
electrochemical cells. We start from a microscopic lattice-gas model with
charged particles, and build mean-field kinetic equations following the lines
of earlier work for neutral particles. We include the Poisson equation to
account for the influence of the electric field on ion migration, and
oxido-reduction processes on the electrode surfaces to allow for growth and
dissolution. We confirm the viability of our approach by simulating (i) the
electrochemical equilibrium at flat electrodes, which displays the correct
charged double-layer, (ii) the growth kinetics of one-dimensional
electrochemical cells during growth and dissolution, and (iii) electrochemical
dendrites in two dimensions.Comment: 14 pages twocolumn, 17 figure
ACME Stellar Spectra. I. Absolutely Calibrated, Mostly Empirical Flux Densities of 55 Cancri and its Transiting Planet 55 Cancri e
The ACME Spectra project provides absolutely calibrated, mostly empirical
spectra of exoplanet host stars for use in analysis of the stars and their
planets. Spectra are obtained from ground-based telescopes and are tied
directly to calibrated ground- and space-based photometry. The spectra remain
only "mostly" empirical because of telluric absorption, but interpolation of
stellar models over the gaps in wavelength coverage provides continuous stellar
spectra. Among other uses, the spectra are suitable for precisely converting
observed secondary eclipses (occultations) into absolute flux units with
minimal recourse to models. In this letter I introduce ACME's methods and
present a calibrated spectrum of the nearby, super-Earth hosting star 55 Cancri
that spans the range from 0.81-5.05 micron. This spectrum is well-suited for
interpreting near- and thermal-infrared eclipse observations. With this
spectrum I show that the brightness temperature of the small, low-mass
transiting planet 55 Cnc e is 1950 +260/-190 K at 4.5 micron (cooler than
previously reported), which corresponds to a planetary flux of 0.44 +0.12/-0.08
mJy. This result suggests the planet has some combination of a nonzero albedo,
a moderately efficient redistribution of absorbed stellar irradiation, and/or
an optically thick atmosphere, but more precise eclipse measurements are
required to distinguish between these scenarii.Comment: Accepted to A&A. 6 pages, 1 figure, 1 electronic table. See
http://irtfweb.ifa.hawaii.edu/~spex/IRTF_Spectral_Library/ for an alternative
spectru
Electrowetting of liquid marbles
Electrowetting of water drops on structured superhydrophobic surfaces are known to cause an irreversible change from a slippy (Cassie-Baxter) to a sticky (Wenzel) regime. An alternative approach to using a water drop on a superhydrophobic surface to obtain a non-wetting system is to use a liquid marble on a smooth solid substrate. A liquid marble is a droplet coated in hydrophobic grains, which therefore carries its own solid surface structure as a conformal coating. Such droplets can be considered as perfect non-wetting systems having contact angles to smooth solid substrates of close to 180 degrees. In this work we report the electrowetting of liquid marbles made of water coated with hydrophobic lycopodium grains and show that the electrowetting is completely reversible. Marbles are shown to return to their initial contact angle for both ac and dc electrowetting and without requiring a threshold voltage to be exceeded. Furthermore, we provide a proof-of-principle demonstration that controlled motion of marbles on a finger electrode structure is possible
Dynamic surface decoupling in a sheared polymer melt
We propose that several mechanisms contribute to friction in a polymer melt
adsorbed at a structured surface. The first one is the well known
disentanglement of bulk polymer chains from the surface layer. However, if the
surface is ideal at the atomic scale, the adsorbed parts of polymer chains can
move along the equipotential lines of the surface potential. This gives rise to
a strong slippage of the melt. For high shear rates chains partially desorb.
However, the friction force on adsorbed chains increases, resulting in
quasi-stick boundary conditions. We propose that the adsorbed layers can be
efficiently used to adjust the friction force between the polymer melt and the
surface
Ethanol electrooxidation on Pt-Sn and Pt-Sn-W bulk alloys
Ethanol oxidation has been studied on Pt-Sn and Pt-Sn-W electrodes prepared in an arc-melting furnace. Different electrochemical techniques like cyclic voltammetry and chronoamperometry were used to evaluate the catalytic activity of these materials. The electro-oxidation process was also investigated by in situ infrared reflectance spectroscopy in order to determine adsorbed intermediates and reaction products. Experimental results indicated that Pt-Sn and Pt-Sn-W alloys are able to oxidize ethanol mainly to acetaldehyde and acetic acid. Adsorbed CO was also detected, demonstrating the viability of splitting the C-C bond in the ethanol molecule during the oxidation process. The adsorbed CO was further oxidized to CO2.This reaction product was clearly detected by SNIFTIRS. Pt-Sn-W catalyst showed a better electrochemical performance than Pt-Sn that, in it turn, is better than Pt-alone.A oxidação de etanol foi estudada sobre eletrodos Pt-Sn e Pt-Sn-W preparados em forno a arco elétrico. Diferentes técnicas eletroquímicas, tais como voltametria cíclica e cronoamperometria foram utilizadas para avaliar a atividade catalítica desses materiais. O processo de eletro-oxidação também foi investigado in situ por espectroscopia de reflectância na região do infravermelho para determinar intermediários adsorvidos e produtos da reação. Os resultados experimentais indicaram que as ligas Pt-Sn e Pt-Sn-W são capaz de oxidar etanol principalmente para acetaldeído e ácido acético. CO adsorvido também foi detectado, demonstrando a viabilidade do rompimento da ligação C-C na molécula de etanol durante o processo de oxidação. Adicionalmente, o CO adsorvido foi oxidado a CO2. Esse produto de reação foi claramente detectado por SNIFTIRS. O catalisador Pt-Sn-W mostrou um melhor desempenho eletroquímico em relação ao Pt-Sn e este, por sua vez, é melhor do que Pt pura.CAPES - COFECUBCNP
Spreading of Latex Particles on a Substrate
We have investigated both experimentally and theoretically the spreading
behavior of latex particles deposited on solid substrates. These particles,
which are composed of cross-linked polymer chains, have an intrinsic elastic
modulus. We show that the elasticity must be considered to account for the
observed contact angle between the particle and the solid substrate, as
measured through atomic force microscopy techniques. In particular, the work of
adhesion computed within our model can be significantly larger than that from
the classical Dupr\'{e} formula.Comment: 7 pages, 7 figures, to appear in Europhys. Let
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