Effect of shape anisotropy on the phase diagram of the Gay-Berne fluid

We have used the density functional theory to study the effect of molecular elongation on the isotropic-nematic, isotropic-smectic A and nematic-smectic A phase transitions of a fluid of molecules interacting via the Gay-Berne intermolecular potential. We have considered a range of length-to-width parameter $3.0\leq x_0\leq 4.0$ in steps of 0.2 at different densities and temperatures. Pair correlation functions needed as input information in density functional theory are calculated using the Percus-Yevick integral equation theory. Within the small range of elongation, the phase diagram shows significant changes. The fluid at low temperature is found to freeze directly from isotropic to smectic A phase for all the values of $x_0$ considered by us on increasing the density while nematic phase stabilizes in between isotropic and smectic A phases only at high temperatures and densities. Both isotropic-nematic and nematic-smectic A transition density and pressure are found to decrease as we increase $x_0$. The phase diagram obtained is compared with computer simulation result of the same model potential and is found to be in good qualitative agreement.Comment: 15 pages, 6 figure

Wolf-Rayet Stars in Starburst Galaxies

Wolf-Rayet stars have been detected in a large number of galaxies experiencing intense bursts of star formation. All stars initially more massive than a certain, metallicity-dependent, value are believed to experience the Wolf-Rayet phase at the end of their evolution, just before collapsing in supernova explosion. The detection of Wolf-Rayet stars puts therefore important constraints on the evolutionary status of starbursts, the properties of their Initial Mass Functions and their star formation regime. In this contribution we review the properties of galaxies hosting Wolf-Rayet stars, with special emphasis on the factors that determine their presence and evolution, as well as their impact on the surrounding medium.Comment: Contribution to the Proceedings of the JENAM 99 conference "The interplay between massive stars and the ISM", held in Toulouse in September 7-11, 1999. 10 pages, 5 figures. Requires elsart.cls latex macr